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Efficient and safe preparation method for active carbon material for adsorbing phosphorus in water body

An activated carbon and safe technology, which is applied in the field of activated carbon materials and preparations for efficient and safe adsorption of phosphorus in water bodies, can solve problems such as inability to use phosphorus in drinking water, hidden environmental safety hazards, and environmental pollution, and prevent plant branches and leaves from withering and re-staining water bodies. Secondary pollution and high treatment efficiency

Active Publication Date: 2013-03-27
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The chemical activation method can produce a specific surface area that is more developed than the physical activation, but it needs to be cleaned after activation, which will pollute the environment
Catalytic physical activation method, the addition of a catalyst can effectively increase the physical activation speed, but adding a catalyst will still cause environmental safety hazards
The activated carbon used to adsorb phosphorus on the market mainly improves the adsorption capacity of activated carbon through chemical modification to increase the specific surface area. Chemically modified activated carbon can be used for industrial sewage treatment of phosphorus, but it cannot be used in drinking water bodies, upstream reservoirs, etc. The adsorption of phosphorus in drinking water can easily cause secondary pollution
[0004] Therefore, the physical modification of activated carbon technology is very important, but there is no example of an activated carbon that has a good effect of adsorbing phosphorus after physical modification.

Method used

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  • Efficient and safe preparation method for active carbon material for adsorbing phosphorus in water body

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Dry Zailihua naturally for seven days, chop the raw materials, grind them into powder, pass through a sieve with a sieve aperture of 1mm, and put them in an oven at 105°C for three hours; then put them into a carbonization furnace with nitrogen gas for high-temperature carbonization, and the heating rate is divided into 5°C / min, heat up to 500°C, keep warm for two hours, and cool to room temperature. Introduce carbon dioxide gas for high-temperature activation, the heating rate is 5°C / min, and the temperature is raised to 600°C, kept for two hours, and cooled to room temperature. The specific surface area of ​​the final product reaches 287.95m 2 / g, calcium content 18.10g / kg, magnesium content 3.43g / kg.

[0025] The adsorption effect takes the experiment of activated carbon product adsorption of phosphorus in water as an example.

Embodiment 2

[0027] Weigh 0.2g of activated carbon sample, place it in a 500ml Erlenmeyer flask, add 50ml of 1mg / L KH with different initial concentrations 2 PO4 solution, three replicates for each sample, placed in a constant temperature shaker, shaken at 120r / min, 25°C for 48h, filtered, pipette the supernatant, and use the molybdenum blue colorimetric method to analyze and calculate the phosphorus in the remaining solution After testing, the phosphorus removal rate of activated carbon products reached 70.30%.

Embodiment 3

[0029] Weigh 0.2g of activated carbon sample, place it in a 500ml Erlenmeyer flask, add 50ml of KH with different initial concentrations of 2mg / L 2 PO4 solution, three replicates for each sample, placed in a constant temperature shaker, shaken at 120r / min, 25°C for 48h, filtered, pipette the supernatant, and use the molybdenum blue colorimetric method to analyze and calculate the phosphorus in the remaining solution After testing, the removal rate of phosphorus by activated carbon products reached 79.17%.

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Abstract

The invention relates to preparation for an active carbon material, aiming at providing an efficient and safe preparation method for an active carbon material for adsorbing phosphorus in a water body. The method comprises the following steps of: naturally air-drying thalia dealbata for 7 days, chopping, grinding into a powder, sieving, and then placing in an oven and drying for 3 hours; placing the dried powder in a carbonization furnace, performing high-temperature carbonization while charging nitrogen, heating to 500 DEG C, insulating heat for 2 hours, and then cooling to a room temperature; and performing high-temperature activation while charging carbon dioxide gas in the carbonization furnace, heating to 600 DEG C, insulating heat for 2 hours, and then cooling to a room temperature to obtain the product. Via the preparation method disclosed by the invention, the problem of plant waste treatment in water body purification is solved, the possibility that plant branches and leaves contaminate the water body after being withered is prevented, and waste is turned into wealth; and the prepared biomass active carbon is used for further purifying the water body, thus solving the problem of the possibility of secondary pollution in the water body which is purified by active carbon. The preparation method has the advantages of being high in treatment efficiency, economic and practical, green and environment-friendly, cyclic in purification and the like, as well as achieves the expected effect of efficient decontamination.

Description

technical field [0001] The invention relates to the preparation of activated carbon materials, in particular to an activated carbon material and a preparation method for efficiently and safely adsorbing phosphorus in water bodies. Background technique [0002] As an excellent adsorbent, activated carbon has a unique specific surface area and pore volume and is widely used in various aspects of life, such as decolorization, deodorization, etc. Today, activated carbon is used more and more frequently in the environment. In water treatment, it is widely used to remove colorants, chlorides and other organic substances, as well as heavy metals. At present, the application of activated carbon to the adsorption of phosphorus in water mainly includes the physical adsorption of specific surface area and the precipitation reaction of metal ions and phosphate radicals on the surface of activated carbon. Due to the limited effect of untreated activated carbon adsorption of phosphorus, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/10B01J20/20C02F1/28C02F1/58C01B32/336
Inventor 杨肖娥曾峥韩璇丁哲利赵晶
Owner ZHEJIANG UNIV
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