Polymer composition for microelectronic assembly
A technology of polymers and compositions, applied in the direction of electrical solid devices, circuits, electrical components, etc., can solve problems such as adhesive residue
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Embodiment B1
[0115] Example B1: Formulation of polycarbonate from 1,3-cyclohexanediol and endo-endo-2,3-norbornanedimethanol with formic acid in GBL
[0116] Dry polymer (4.54 g), prepared following the procedure in Polymer Example 3, was added to gamma-butyrolactone (GBL) to obtain a polymer solution with a total weight of 12.8 g (35.3 wt% resin content). Mix by roller for a minimum of 12 hours to obtain a clear, viscous, homogeneous polymer solution. The viscous solution was filtered by passing through a 1.0 μm disc filter made of PTFE, and the viscosity was measured at 25° C. with a Brookfield viscometer (Model DV I Prime) to be 17500 cPs. Formic acid (0.67 g, 5 wt% of the total solution) was then added and a homogeneous formulation was obtained after 8 hours of roller mixing.
Embodiment B2
[0117] Example B2: Formulation of polycarbonate from isosorbide and endo-exo-2,3-norbornanedimethanol with formic acid in GBL
[0118] A polycarbonate formulation according to an embodiment of the invention was prepared according to the procedure described in Example B1 using 5.25 g of dry polymer from Polymer Example 9 to obtain 15.0 g (35.0 wt % resin content) of a base polymer solution . The viscosity was determined to be 4600 cPs. Formic acid added was 0.78 g.
Embodiment B3
[0119] Example B3: Formulation of polycarbonate from isosorbide and 1,4-cyclohexanedimethanol with formic acid in GBL
[0120] A polycarbonate formulation according to an embodiment of the present invention was prepared according to the procedure described in Example B1 using 2.00 g of dry polymer from Polymer Example 10 to obtain 10.0 g (20.0 wt% resin content) of a base polymer solution . The viscosity was determined to be 8000 cPs. Formic acid added was 0.52 g.
[0121] C. Evaluation of Solder Fluxing Using Formic Acid in GBL
[0122] The use of the formulations of Examples B1-B3 provided data for evaluations C1-C3 as shown in Table 3, respectively. The method used for these examples was as follows: The formulation was dispensed as distinct spots with a 27-gauge needle onto a copper plate (1.7 cm x 3.4 cm) with a partially oxidized surface. Solder balls (Sn99.3Cu0.7; 600 μm) were carefully transferred on top of each spot on the copper plate. The entire board mounted o...
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