Electrolyte solution and lithium-ferrous disulfide battery containing same

A ferrous disulfide and electrolyte technology, applied in the field of lithium batteries, can solve problems such as voltage reduction and inability to release 100% capacity, and achieve the effects of improving discharge performance, good discharge performance, and overcoming low discharge capacity.

Active Publication Date: 2013-12-18
EVE ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] U.S. Patent Publication No. US20060046154 discusses improved low-temperature discharge performance using an electrolyte comprising an electrolyte of lithium iodide (LiI) and lithium trifluoromethanesulfonate (PFM-LI), but shows near the start of high-power discharge at low temperatures sharp drop in voltage
[0005] U.S. Patent Publication No. US7722988B2 discloses that 0.5 mol/L LiI is dissolved in 60-70 volume % 1,3-dioxolane (DIOX) and one or more ether mixtures such as ethylene glycol dimethyl ether (DME) The battery in the electrolyte increases the low-temperature discharge capacity without affecting the discharge capacity at room temperature, but d...

Method used

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Embodiment 1

[0028]An embodiment of an electrolyte of the present invention, the electrolyte is used in a lithium-ferrous disulfide battery, the electrolyte includes an electrolyte and an electrolyte solvent; the electrolyte is lithium bisfluorosulfonimide (LiFSI) and lithium iodide (LiI), the molar concentration of the lithium bisfluorosulfonimide (LiFSI) in the electrolyte is 0.6 mol / L, and the molar concentration of the lithium iodide (LiI) in the electrolyte is 0.6mol / L; the electrolyte solvent is 1,3-dioxolane (DIOX) and ethylene glycol dimethyl ether (DME), and in the electrolyte solvent, 1,3-dioxolane (DIOX) The mass percentage of ethylene glycol dimethyl ether (DME) is 25%, and the mass percentage of ethylene glycol dimethyl ether (DME) is 75%.

Embodiment 2

[0030] An embodiment of an electrolyte of the present invention, the electrolyte is used in a lithium-ferrous disulfide battery, the electrolyte includes an electrolyte and an electrolyte solvent; the electrolyte is lithium bisfluorosulfonimide (LiFSI) and lithium bis-trifluoromethanesulfonimide (LiTFSI), the molar concentration of the lithium bis-fluoromethylsulfonimide (LiFSI) in the electrolyte is 0.6 mol / L, and the bis-trifluoromethanesulfonyl The molar concentration of lithium imide (LiTFSI) in the electrolyte is 0.6 mol / L; the electrolyte solvent is 1,3-dioxolane (DIOX) and ethylene glycol dimethyl ether (DME). In the solvent, the mass percentage of 1,3-dioxolane (DIOX) is 25%, and the mass percentage of ethylene glycol dimethyl ether (DME) is 75%.

Embodiment 3

[0032] An embodiment of an electrolyte of the present invention, the electrolyte is used in a lithium-ferrous disulfide battery, the electrolyte includes an electrolyte and an electrolyte solvent; the electrolyte is lithium bisfluorosulfonimide (LiFSI) , the molar concentration of the lithium bisfluorosulfonimide (LiFSI) in the electrolyte is 1.2 mol / L; the electrolyte solvent is 1,3-dioxolane (DIOX) and ethylene glycol dimethyl ether (DME), in the electrolyte solvent, the mass percentage of 1,3-dioxolane (DIOX) is 25%, and the mass percentage of ethylene glycol dimethyl ether (DME) is 75%.

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PUM

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Abstract

The invention discloses electrolyte solution used for a lithium-ferrous disulfide battery. The electrolyte solution comprises electrolyte and an electrolyte solvent, wherein the electrolyte comprises bistrifluoromethanesulfonimide lithium salt, the electrolyte solvent comprises at least one of 1, 3-dioxolame, glycol dimethyl ether and propylene carbonate. The electrolyte solution provided by the invention is formed by the combination of the specific electrolyte and the electrolyte solvent, is mainly used in the lithium-ferrous disulfide battery, is low in cost and can solve the problem that the existing lithium-ferrous disulfide battery cannot discharge electricity or has low discharge capacity at below 40 DEG C, so as to remarkably improve the discharge performance of the lithium-ferrous disulfide battery at below 40 DEG C. Furthermore, the invention also discloses the lithium-ferrous disulfide battery containing the lithium-ferrous disulfide battery, and the lithium-ferrous disulfide battery has good discharge performance.

Description

technical field [0001] The invention relates to an electrolyte and a lithium battery containing the electrolyte, in particular to an electrolyte for a lithium-ferrous disulfide battery and a lithium-ferrous disulfide battery made from the electrolyte. Background technique [0002] Lithium-ferrous disulfide batteries are developing rapidly. The primary batteries have large specific energy, green environmental protection, long storage life and broad market prospects. Especially in the development of high-power electronic appliances such as digital cameras, portable monitoring instruments for medical use, and outdoor product applications. However, all such batteries currently on the market have the problem of poor low temperature performance. [0003] Replacing lithium trifluoromethanesulfonate (PFM-LI) with lithium iodide (LiI) is discussed in U.S. Patent Publication No. US5514491 to improve battery electrical performance and reduce cost, and the electrolyte solvent includes ...

Claims

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Application Information

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IPC IPC(8): H01M6/16
Inventor 余思恩袁中直刘金成
Owner EVE ENERGY CO LTD
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