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A method to characterize the recycling effect of waste thermosetting plastics

A thermosetting and plastic technology, which is applied in the direction of nuclear magnetic resonance analysis, etc., can solve the problems of no accurate and reliable evaluation indicators and undetectable problems, and achieve the effect of strong applicability and practicability, accuracy and stability

Active Publication Date: 2016-05-25
HEFEI UNIV OF TECH
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Problems solved by technology

[0004] Although the physical recovery method has various advantages, there is no accurate and reliable evaluation index for the reactivity or molding ability of the recycled material, and it is even impossible to detect it.

Method used

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  • A method to characterize the recycling effect of waste thermosetting plastics
  • A method to characterize the recycling effect of waste thermosetting plastics
  • A method to characterize the recycling effect of waste thermosetting plastics

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Embodiment Construction

[0044] This embodiment discloses a method for low-field nuclear magnetic resonance to test the crosslinking density of the prepared active recycled materials during the process of recycling thermosetting plastics, and to characterize and evaluate the recycling effect of recycled materials and the molding ability of recycled materials according to numerical changes. Taking commonly used thermosetting plastics as an example, the specific implementation steps are as follows:

[0045] (1) The thermosetting plastic is crushed and regenerated to obtain a chemically reactive recycled material. The raw material of the thermoset plastic and the recycled material of different particle sizes are grouped into powder groups. Each powder group is raw material 1, recycled material 2, and recycled Material 3,..., recycled material M;

[0046] (2) Test the crosslinking density of each powder group as follows:

[0047] a. Use the nuclear magnetic resonance cross-linking density meter to detect and ob...

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Abstract

The invention discloses a method for characterizing a regeneration effect of waste thermosetting plastic. The method is characterized by comprising the following steps: crushing and regenerating thermosetting plastic to obtain regenerated materials; grouping raw materials of the thermosetting plastic and the regenerated materials with different granularities into each powder group; testing the cross-linking density of each powder group; recording the minimum value of the cross-linking density; mixing each group of the regenerated material in each powder group with thermoplastic resin according to a set mass ratio; adding a chemical auxiliary agent for hot press molding to prepare a regenerated plastic product; preparing the regenerated plastic product into a sample and testing the mechanical strength; determining a regeneration coefficient gamma; and determining a quantitative index of the regeneration effect and judging that whether the regenerated powder reaches the index or not. The invention provides the method for quantitatively characterizing the regeneration effect of the regenerated materials in the process of recycling the waste thermosetting plastic by a mechanical physical method; the uncertain factors in the recycling process are overcome.

Description

Technical field [0001] The invention belongs to the field of recycling and reuse of waste polymer materials, and specifically relates to a method for determining the crosslinking density of thermosetting plastics by nuclear magnetic resonance to characterize and evaluate the regeneration effect of regenerated materials obtained during the recycling process of waste thermosetting plastics. Background technique [0002] According to the processing performance of plastics, plastics can be divided into two categories: thermoplastics and thermosetting plastics. Thermoplastics have a linear molecular chain structure, are elastic and plastic, can be dissolved in solvents, can be melted by heat, and can be repeatedly processed into shapes. Thermosetting plastic is a body-shaped network cross-linked molecular chain structure. After solidification and shaping, it cannot be heated and melted, nor can it be dissolved in a solvent, but can only swell. [0003] At present, thermoplastics can be...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N24/08
Inventor 吴仲伟宋守许刘志峰潘绍波
Owner HEFEI UNIV OF TECH
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