Neutral calcium phosphate bone cement and preparation method thereof
A technology of bone cement and calcium phosphate, applied in medical science, prosthesis, etc., to achieve the effect of simple preparation method, high mechanical strength and good effect
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Embodiment 1
[0026] Weigh 86 g of calcium hydrogen phosphate dihydrate and 25 g of calcium carbonate, add them to 165 mL of water, ball mill and mix well. Then the water was distilled under reduced pressure, and dried in a vacuum drying oven at 80° C. to obtain a mixed powder. The powder was fired in the middle of a furnace at 900°C for 15 hours, and then the bone cement dispersion was obtained by wet ball milling. The dispersion liquid is centrifuged and dried to obtain the main component of the bone cement powder, and the powder size is 300-800 nm.
Embodiment 2
[0028] 96 g of the main component of bone cement powder and 4 g of hydroxyapatite were ground uniformly with a mortar to obtain bone cement powder. The solidification solution composed of 20% citric acid-1% hydroxypropyl methylcellulose was mixed with bone cement powder at a liquid-solid ratio of 0.5 mL / g, and the initial setting time was determined to be 11 min according to the standard ASTM C191. The apparent density of the bone cement after curing is 1.45 g / cm 3 , The collapse coefficient is 1.5%. When it is added to water, the solution is neutral. After standing for a week, the pH of the test solution remains unchanged, such as figure 1 As shown, the pH of the aqueous solution remains neutral over a long time scale.
Embodiment 3
[0030] 91 g of the main component of bone cement powder, 4 g of hydroxyapatite and 5 g of sodium silicate were ground uniformly in a mortar to obtain bone cement powder. The solidification solution composed of 20% citric acid-1% hydroxypropyl methylcellulose was mixed with the bone cement powder at a liquid-solid ratio of 0.5 mL / g, and the initial setting time was determined to be 9 min according to the standard ASTM C191. The apparent density of the bone cement after curing is 1.48 g / cm 3 , Collapse coefficient 2.2%. When it is added to water, the solution is neutral. After standing for a week, the pH of the solution was basically unchanged, and the result was the same as figure 1 Similar to shown.
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