A kind of liquid optical transparent glue and preparation method thereof
An optically transparent adhesive, liquid technology, applied in adhesives, non-polymer organic compound adhesives, etc., can solve problems such as poor curing, improve contrast and clarity, avoid reliability problems, and reduce refraction loss.
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Embodiment 1
[0028] Accurately weigh 30g of maleic anhydride graft-modified polybutadiene acrylate resin (reacted by Ricon130MA8 and hydroxyethyl acrylate in a molar ratio of 1:1, the reaction temperature is controlled at 90 degrees, after 4 hours of reaction, the infrared test 1785cm -1 The absorption peak of maleic anhydride at the place disappears, and the polybutadiene acrylate resin grafted with maleic anhydride is obtained), 40g liquid polybutadiene resin (Ricon156), 30g isooctyl acrylate, 2.5g n-dec Dialkyl mercaptan, 4g of photoinitiator 184, 0.2g of light stabilizer 770, add the above components into the mixer in turn, mix well, vacuumize to -0.1MPa and defoam for 0.1h, then let it stand naturally to room temperature, Sealed packaging, that is.
Embodiment 2
[0030] Accurately weigh 28g of maleic anhydride graft-modified polybutadiene acrylate resin (reacted by Ricon130MA13 and hydroxypropyl acrylate in a molar ratio of 1:1, the reaction temperature is controlled at 110 degrees, after 5 hours of reaction, the infrared test 1785cm -1 The absorption peak of maleic anhydride at the place disappears, that is, the polybutadiene acrylate resin grafted with maleic anhydride is obtained), 56g liquid polybutadiene resin (Ricon156), 14g isobornyl acrylate, 0.9g trihydroxy Methylpropane tris(3-mercaptopropionate), 1g photoinitiator TPO, 0.6g light stabilizer 622, add the above components into the mixer in turn, mix evenly, vacuumize to -0.09MPa and defoam for 0.2h , let it stand naturally to room temperature, seal the package, and get ready.
Embodiment 3
[0032] Accurately weigh 16g of maleic anhydride graft-modified polybutadiene acrylate resin (reacted by Ricon131MA5 and hydroxyethyl methacrylate in a molar ratio of 1:1, the reaction temperature is controlled at 100 degrees, after 4 hours of reaction, infrared test 1785cm -1 The absorption peak of maleic anhydride at the place disappears, that is, the polybutadiene acrylate resin grafted with maleic anhydride is obtained), 56g liquid polybutadiene resin (Ricon152), 20g isobornyl methacrylate, 5g three Methylolpropane three (3-mercaptopropionate), 4g photoinitiator 1173, 1g photoinitiator TEPO, 0.2g light stabilizer 292, add the above-mentioned components in the double planetary power mixing mixer in turn, mix evenly, After evacuating to -0.08MPa for 0.3h to defoam, let it stand naturally to room temperature, and seal the package.
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Abstract
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