Cover film and copper clad laminate using same
A technology of copper-clad laminate and cover film, which is applied in the direction of film/sheet release coating, film/sheet adhesive, coating, etc., can solve the problems that are difficult to meet, and achieve the suppression of white turbidity and excellent transparency The effect of resistance and heat resistance
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[0103] Hereinafter, although an Example and a comparative example demonstrate this invention further concretely, this invention is not limited to these Examples.
[0104] In Examples and Comparative Examples, measurement and evaluation of various physical properties were performed by the following methods.
[0105] (1) Thickness
[0106] Measurement was performed with a micrometer prescribed in JIS B 7502.
[0107] (2) Glass transition temperature
[0108] The kinetic viscosity when the temperature was raised at a rate of 10° C. / min was measured using a dynamic viscosity measuring device RSA II manufactured by American Rheology Co., Ltd., and Tg was obtained from the maximum value of tan δ.
[0109] (3) Melt viscosity
[0110] Using Rheosol-G3000 manufactured by Japan UBM Co., Ltd., the temperature of the sample was raised at a rate of 10° C. / min, and the dynamic viscosity in the range of 100° C. to 160° C. was measured. Here, the dynamic viscosity means the viscosity when...
manufacture example 1
[0129] Add 100 parts by mass of methyl ethyl ketone, 5 parts by mass of UV initiator (manufactured by Ciba Specialty Chemicals Co., Ltd., DarocureTPO) and 100 parts by mass of acrylic acid ester (manufactured by Daicel-Cytec Co., Ltd., PETA-K). Stirring was carried out at room temperature to obtain a resin composition 1 for a hard coat layer.
manufacture example 2
[0131] Add 100 parts by mass of methyl ethyl ketone, 5 parts by mass of UV initiator (manufactured by Ciba Specialty Chemicals Co., Ltd., DarocureTPO), 50 parts by mass of acrylic acrylate (manufactured by Daicel-Cytec Co., Ltd., PETA-K) and different 50 parts by mass of a type of acrylic acrylate (manufactured by Daicel Cytec Corporation, PEG400DA) was stirred at room temperature to obtain a resin composition 2 for a hard coat layer.
[0132] Adhesive resin composition
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