A kind of detection method of orange chrome yellow concentration in heavy metal concentrated acid liquid

A detection method, orange chrome yellow technology, applied in the direction of Raman scattering, material excitation analysis, etc., can solve the problems that other sources of lead and chromium cannot be ruled out, rapid detection cannot be achieved, and the application range is not wide enough to achieve convenient focusing, Speed ​​up processing and avoid distracting effects

Active Publication Date: 2016-10-05
ZHEJIANG UNIV
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Problems solved by technology

Atomic fluorescence spectrometry has the characteristics of high sensitivity, strong selectivity, small sample amount and simple method; but its disadvantage is that the scope of application is not wide enough
[0008] The above methods all identify the presence of heavy metals lead and chromium in the solution, and then infer the residual orange chromium content in the liquid, but in the process of liquid treatment, other sources of lead and chromium cannot be ruled out
Therefore, the detection of heavy metals lead and chromium alone cannot determine that the lead and chromium in the liquid must come from orange chromium yellow.
Moreover, a large amount of reagents are required for pretreatment when using the above method for detection, the process is cumbersome, and rapid detection cannot be achieved
In addition, there are few reports on the monitoring of residual orange chrome yellow in each process during the treatment of orange chrome yellow wastewater.

Method used

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  • A kind of detection method of orange chrome yellow concentration in heavy metal concentrated acid liquid
  • A kind of detection method of orange chrome yellow concentration in heavy metal concentrated acid liquid
  • A kind of detection method of orange chrome yellow concentration in heavy metal concentrated acid liquid

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Embodiment 1

[0050] A method for detecting the concentration of orange chrome yellow in heavy metal concentrated acid liquid, comprising:

[0051] (1) Take heavy metal concentrated acid liquids with different concentrations of orange chrome yellow as test samples, and obtain each test sample at 2717.2cm -1 ~112.3cm -1 Raman spectra with a silicon wafer as a substrate in the wavenumber range.

[0052] In the present embodiment, a 96-well flat-bottomed culture dish (aperture: 6.4mm, bottom area: 0.32cm 2 , with a volume of 0.36ml) as a container, and one hole as a container. Place a circular silicon wafer with a diameter of 5mm and a thickness of 0.5mm at the bottom of each well, pipette 0.4ml of the upper liquid into the well of the petri dish, and use a scraper to scrape the excess liquid along the edge of the petri dish. Remove, and then place the Petri dish on a glass slide for later use.

[0053] The container containing the test samples is placed on the stage of the micro-Raman spe...

Embodiment 2

[0076] Same as embodiment 1, the difference is that after building the calibration model in step (3), it also includes updating the calibration wavenumber and the calibration model, and the update method is as follows:

[0077] Carry out analysis of variance on the first linear regression model to screen the calibration wavenumber, and use the screened calibration wavenumber as the final calibration wavenumber, and according to the orange chrome yellow concentration of all test samples, and each calibration wavenumber after screening in the Raman spectrum The peak intensity at the standard wave number and 520cm -1 The ratio of the peak intensity at the concentration-intensity ratio constructs the second linear regression model of the concentration-intensity ratio as the updated calibration model.

[0078] The variance analysis was carried out on the calibration model, and the results are shown in Table 2

[0079] Table 2

[0080]

[0081] Table 2 shows the wavenumber vari...

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Abstract

The invention discloses a method for detecting the concentration of orange chrome yellow in heavy metal concentrated acid liquid. In the method, heavy metal concentrated acid liquids with different concentrations of orange chrome yellow are used as test samples, and each test sample is obtained within a set wave number range using a silicon chip as the test sample. The Raman spectrum of the substrate, and according to the Raman spectra of all test samples, the continuous projection algorithm and the multiple linear regression analysis method are respectively used to determine the calibration wavenumber, according to the orange chrome yellow concentration of each test sample, and each calibration wavenumber The peak intensity and 520cm ‑1 The first linear regression model of the concentration-intensity ratio is constructed as the calibration model, and the concentration of orange chrome yellow in the sample to be tested is obtained by using the calibration model measurement. The Raman test is used for analysis, which is easy to operate and does not require tedious and time-consuming sample preparation processes. At the same time, interference from other sources is avoided to ensure the accuracy of the test orange chrome yellow, and the comparison with silicon greatly improves the test accuracy. accuracy.

Description

technical field [0001] The invention relates to the technical field of chrome-orange concentration detection, in particular to a method for detecting the chrome-orange concentration in heavy metal concentrated acid liquid. Background technique [0002] Orange chrome yellow is one of lead chrome yellow. It is a pigment used for oily synthetic resin coatings, printing inks, watercolors and oil paints. It is an inorganic coloring pigment for colored paper, rubber and plastic products. Because of its perfect pigment application Performance, relatively low price and complete color range, so it has been widely used. Its main chemical composition is lead chromate, which is very harmful to the human body and can cause anemia, kidney damage, lead poisoning, dermatitis, eczema, chromic nose disease and skin ulcers, etc. The International Cancer Research Center (IARC) has Include "chromium and certain chromium compounds" as chemicals that are carcinogenic to humans. And about 120-150...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N21/65
Inventor 李晓丽孙婵骏何勇
Owner ZHEJIANG UNIV
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