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High-efficiency flocculant for rapid removal of heavy metals in water

A technology for removing water and heavy metals, applied in the fields of flocculation/sedimentation water/sewage treatment, water/sewage treatment, biological water/sewage treatment, etc. High degree of purification, easy concentration and dehydration, high removal effect

Active Publication Date: 2016-09-14
佑景天(北京)国际水环境研究中心有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditional flocculants mainly include low-molecular flocculants such as aluminum salts and iron salts, which have the disadvantages of slow flocculation and sedimentation, loose and easily broken flocs, and high chemical consumption; high-molecular flocculants such as basic polyaluminum chloride ( PAC), polyaluminum chloride, polyferric sulfate, etc., have high cost, narrow scope of application, and are easily affected by water temperature and pH value; polydimethyldiallylammonium chloride such as polyacrylamide flocculant, etc. It has strong neurotoxicity and certain carcinogenicity. When a large amount of polyacrylamide is used to treat wastewater, it will produce polymer residues, destroy the biological chain of water body, and then affect human health.
At the same time, the sludge produced by traditional flocculants is unstable and easy to dissolve heavy metals. Not only will dioxins be produced during sludge combustion, but it will also cause new pollution to the atmosphere due to the unstable heavy metal fly ash.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Preparation of flocculant

[0032] 1) Take 100kg of Hangjin 2# soil, add 5kg of soil bacteria and 15kg of activated carbon to it, mix evenly, and prepare mixture A;

[0033] 2) Take 10 kg of iron oxide, 10 kg of iron chloride, 20 kg of polyaluminum chloride, 2.5 kg of organic flocculant (polydimethyl diallyl ammonium chloride), 25 kg of cement and 16 kg of sodium thiosulfate, and mix Evenly, prepare mixture B;

[0034] 3) Mix the mixture A and the mixture B uniformly to prepare the flocculant.

[0035] (2) Control experiment of removing hexavalent chromium in water

[0036] The raw water is industrial sewage, and the concentration of hexavalent chromium in the raw water is 2.5mg / L. Under the condition of sufficient stirring, add 5wt% (the mass ratio of the flocculant to the raw water, the same below) of the above-prepared Flocculant and conventional flocculant PAC, after conventional mixing, flocculation, sedimentation and filtration, according to the detection method speci...

Embodiment 2

[0038] (1) Preparation of flocculant

[0039] 1) Take 100kg of Hangjin 2# soil, add 8kg of soil bacteria and 20kg of activated carbon to it, mix evenly, and prepare mixture A;

[0040] 2) Take 15kg of iron oxide, 15kg of iron chloride, 35kg of polyaluminum chloride, 4kg of organic flocculant (polydimethyldiallylammonium chloride), 35kg of cement and 24kg of sodium thiosulfate, and mix them evenly. Into mixture B;

[0041] 3) Mix the mixture A and the mixture B uniformly to prepare the flocculant.

[0042] (2) Control experiment of removing hexavalent chromium in water

[0043] The raw water is industrial sewage, and the concentration of hexavalent chromium in the raw water is 2.5mg / L. Under the condition of sufficient stirring, 4wt% of the flocculant prepared above and the conventional flocculant PAC are added to the above sewage, and after conventional mixing, flocculation, After precipitation and filtration, according to the detection method specified in GB 8978-1996, the concentrat...

Embodiment 3

[0045] (1) Preparation of flocculant

[0046] 1) Take 100kg of Hangjin 2# soil, add 5kg of soil bacteria and 25kg of activated carbon to it, mix evenly, and prepare mixture A;

[0047] 2) Take 10kg of iron oxide, 20kg of iron chloride, 20kg of polyaluminum chloride, 2.5kg of organic flocculant (polydimethyldiallylammonium chloride), 25kg of cement and 16kg of sodium thiosulfate, and mix them evenly. Prepared as mixture B;

[0048] 3) Mix the mixture A and the mixture B uniformly to prepare the flocculant.

[0049] (2) Control experiment of removing lead in water

[0050] The raw water is industrial sewage. The concentration of lead in the raw water is 2.0 mg / L. Under the condition of sufficient stirring, 6wt% of the flocculant prepared above and the conventional flocculant PAC are added to the above sewage respectively, and the mixture is conventionally mixed, flocculated, and precipitated. After filtration, according to the detection method specified in GB 8978-1996, the concentratio...

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Abstract

The invention relates to an efficient flocculating agent for rapidly removing heavy metals in water. The efficient flocculating agent comprises a mixture A and a mixture B, wherein the mixture A comprises the following components in parts by mass: 100 parts of No.2 Hangjin soil, 5-10 parts of soil bacteria and 15-25 parts of activated carbon; and the mixture B comprises the following components in parts by mass: 10-20 parts of iron oxide, 10-20 parts of iron chloride, 20-50 parts of poly-aluminum chloride, 2.5-5 parts of an organic flocculating agent, 25-50 parts of cement and 16-32 parts of sodium thiosulfate. The efficient flocculating agent disclosed by the invention can be used for rapidly and effectively removing a variety of heavy metals such as mercury, lead, chromium, cadmium, arsenic and copper in the water, is short in reaction time, cannot cause secondary pollution, can be directly fed without early dissolution, is simple in use method, and can be widely applied to removal of the heavy metals in various industrial wastewater, polluted underground water, lakes, rivers and reservoirs.

Description

Technical field [0001] The invention relates to a high-efficiency water treatment flocculant used for industrial waste water, polluted groundwater, lakes, rivers and reservoirs. Background technique [0002] The problem of heavy metal pollution in China's water is very prominent, with the pollution rate of rivers, lakes and reservoirs as high as 80.1%. The Yellow River, Huaihe River, Songhua River, Liaohe River and other ten major river basins, the pollution degree of heavy metals exceeding the standard section are all Category V; the total Cu, total Pb, and total Cd content in the sediments of Taihu Lake are all at a light pollution level; the main stream of the Huangpu River In surface sediments, Cd exceeded the background value by 2 times and Pb by 1 time; in Suzhou Creek, all Pb exceeded the standard, Cd exceeded the standard by 75%, and Hg exceeded the standard by 62.5%. In 35.11% of urban rivers, the total Hg exceeded the surface water standard of Class III, 18.46% of the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/52C02F1/62C02F1/72C02F1/70C02F1/28
CPCC02F3/34C02F2103/007C02F2103/06
Inventor 董志刚张伟锋席北斗赵颖刘文芳李晓光郭祎阁彭星
Owner 佑景天(北京)国际水环境研究中心有限公司
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