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A kind of preparation method of urea-formaldehyde slow-release fertilizer

A technology of urea formaldehyde and slow-release fertilizer, applied in nitrogen fertilizer, fertilization device, fertilizer mixture and other directions, can solve the problems of high moisture content, equipment blockage, easy caking, etc., and achieve the effect of low production cost and simple process

Active Publication Date: 2017-01-25
GUIZHOU RES INST OF CHEM IND +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of this, the purpose of the present invention is to provide a kind of preparation method of urea-formaldehyde slow-release fertilizer, to solve in the urea-formaldehyde slow-release fertilizer preparation process, when adopting rotary flash dryer to dry urea-formaldehyde slow-release fertilizer, due to Urea-formaldehyde has a certain viscosity, and the moisture content is too high. It is easy to agglomerate when it is rotated and flashed, stirred and crushed, and it is easy to cause equipment blockage, which makes the drying process difficult to carry out.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Add 1000kg urea and 1000kg formaldehyde into the urea-formaldehyde preparation tank, and add sodium hydroxide to adjust the pH value in the urea-formaldehyde preparation tank to 8, then heat the tank to 40°C, keep constant temperature and keep stirring to make urea React with formaldehyde for 1 hour, then stop heating and adjust the pH value of the reactant to 6.5 with monoammonium phosphate. After the reactant is polymerized, the crude urea-formaldehyde is obtained; add 600kg of organic fertilizer to the crude urea-formaldehyde and send it to the spin flash dryer , using a temperature of 80 ° C to dry it to a moisture content of 10%, and the urea-formaldehyde slow-release fertilizer can be collected from the outlet of the cyclone separator.

Embodiment 2

[0025] Add 3000kg urea and 1000kg formaldehyde into the urea-formaldehyde preparation tank, and add sodium hydroxide to adjust the pH value in the urea-formaldehyde preparation tank to 8, then heat the tank to 60°C, keep constant temperature and keep stirring to make urea React with formaldehyde for 0.5h, then stop heating and adjust the pH value of the reactant to 7 with monoammonium phosphate. After the reactant is polymerized, the crude urea-formaldehyde is obtained; add 1000kg of organic fertilizer and 1000kg of humic acid to the crude urea-formaldehyde and send it to In the spin flash dryer, use a temperature of 120°C to dry it to a moisture content of 8%, and the urea-formaldehyde slow-release fertilizer can be collected from the outlet of the cyclone separator.

Embodiment 3

[0027] Add 2000kg urea and 1000kg formaldehyde into the urea-formaldehyde preparation tank, and add sodium hydroxide to adjust the pH value in the urea-formaldehyde preparation tank to 8.5, then heat the tank to 50°C, keep constant temperature and keep stirring to make urea React with formaldehyde for 0.7h, then stop heating and adjust the pH value of the reactant to 6.8 with monoammonium phosphate. After the reactant is polymerized, the crude urea-formaldehyde is obtained; add 1200kg of organic fertilizer to the crude urea-formaldehyde and send it to spin flash drying In the machine, it is dried at a temperature of 100°C until the moisture content is 9%, and the urea-formaldehyde slow-release fertilizer can be collected from the outlet of the cyclone separator.

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PUM

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Abstract

The invention discloses a preparation method of a urea-formaldehyde slow release fertilizer. The preparation method comprises the following steps: mixing urea with formaldehyde in a certain mass ratio, adding sodium hydroxide to adjust the pH value and then heating and stirring for full reaction of urea and formaldehyde; and after reaction for a while, stopping heating and adding monoammonium phosphate to adjust the pH value, mixing and drying the obtained material with a mixture of one or two of an organic fertilizer and humic acid in a certain mass ratio, and then granulating to obtain the urea-formaldehyde slow release fertilizer. According to the preparation method disclosed by the invention, during spin flash drying, the mixture of one or two of the organic fertilizer and humic acid is added into a filter cake of urea-formaldehyde, so that the technical problem that the equipment cannot work normally as the urea-formaldehyde is agglomerated during spin flash drying to lead to accumulation of urea-formaldehyde in the equipment to cause equipment blockage is effectively solved. Meanwhile, the preparation method disclosed by the invention is simple in process and relatively low in production cost.

Description

technical field [0001] The invention relates to the technical field of preparation of slow-release fertilizers, in particular to a preparation method of urea-formaldehyde slow-release fertilizers. Background technique [0002] At present, scientists from all over the world believe that the development of the fertilizer industry in the 21st century should develop in the direction of high efficiency, resurrection, special purpose, multi-function, slow release, and controlled release, and a new type of high-efficiency slow-control fertilizer integrating the above advantages. [0003] Urea-formaldehyde slow-release fertilizer is a high-nitrogen slow-release fertilizer with slow nutrient release, long fertilizer effect period, nitrogen utilization rate of more than 80%, and sustainable fertilizer effect for more than 80 days, up to two years. The wetting rate of urea-potassium aldehyde slow-release fertilizer is very low. Generally, the compound fertilizer of urea and ammonium ni...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C05G1/00C05G3/00
CPCC05C9/02
Inventor 田娟马福波陈文兴周昌平虞江
Owner GUIZHOU RES INST OF CHEM IND
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