Method for recycling metal from waste lithium ion battery with Ni-Co lithium manganite positive electrode materials
A technology of nickel cobalt lithium manganate and lithium ion battery, which is applied in battery recycling, waste collector recycling, recycling technology and other directions, can solve the pollution of atmospheric environment and water environment, high recycling cost, and high requirements for anti-corrosion performance of recycling equipment. High problems, to achieve the effect of easy operation, low recovery cost, and low equipment anti-corrosion requirements
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Embodiment 1
[0025] Collect scrap lithium-ion batteries with nickel-cobalt-lithium manganese oxide cathode materials, place them in 1.0mol / L sodium hydroxide aqueous solution at room temperature for 2h discharge treatment; after discharge treatment, disassemble the scrap lithium-ion batteries, Obtain the positive electrode sheet; the ratio (g / mL) of the mass of the positive electrode sheet to the volume of the ceramic crucible is 1:15, the positive electrode sheet is packed into the ceramic crucible, and then placed in a box-type resistance furnace from room temperature to 5 ° C. Raise the furnace temperature to 550°C at a heating rate of / min and keep it warm for 20 minutes. Put the positive electrode sheet into a container filled with water according to the ratio of the mass of the positive electrode sheet to the volume of water (g / mL) of 1:50 and stir it electrically The mixer was stirred at a stirring speed of 50r / min for 20 minutes, and the temperature of the water during the stirring ...
Embodiment 2
[0027] Collect scrap lithium-ion batteries with nickel-cobalt-lithium manganese oxide cathode materials, place them in 1.0mol / L sodium hydroxide aqueous solution at room temperature for 2h discharge treatment; after discharge treatment, disassemble the scrap lithium-ion batteries, Obtain the positive electrode sheet; the ratio (g / mL) of the mass of the positive electrode sheet to the volume of the ceramic crucible is 1:15, the positive electrode sheet is packed into the ceramic crucible, and then placed in a box-type resistance furnace from room temperature to 5 ° C. Raise the furnace temperature to 550°C at a heating rate of / min and keep it warm for 20 minutes. Put the positive electrode sheet into a container filled with water according to the ratio of the mass of the positive electrode sheet to the volume of water (g / mL) of 1:50 and stir it electrically The mixer was stirred at a stirring speed of 50r / min for 20 minutes, and the temperature of the water during the stirring ...
Embodiment 3
[0029]Collect scrap lithium-ion batteries with nickel-cobalt-lithium manganese oxide cathode materials, place them in 1.0mol / L sodium hydroxide aqueous solution at room temperature for 2h discharge treatment; after discharge treatment, disassemble the scrap lithium-ion batteries, Obtain the positive electrode sheet; the ratio (g / mL) of the mass of the positive electrode sheet to the volume of the ceramic crucible is 1:15, the positive electrode sheet is packed into the ceramic crucible, and then placed in a box-type resistance furnace from room temperature to 5 ° C. Raise the furnace temperature to 550°C at a heating rate of / min and keep it warm for 20 minutes. Put the positive electrode sheet into a container filled with water according to the ratio of the mass of the positive electrode sheet to the volume of water (g / mL) of 1:50 and stir it electrically The mixer was stirred at a stirring speed of 50r / min for 20 minutes, and the temperature of the water during the stirring p...
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