A method for regenerating and treating organic wastewater using an enzyme-like magnetic catalyst

A magnetic catalyst, organic wastewater technology, applied in chemical instruments and methods, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc. Increase the pretreatment process and other issues to achieve the effect of strong engineering application value, compact structure and small footprint

Inactive Publication Date: 2016-06-29
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Enzyme-like catalytic degradation of organic matter in wastewater is a new technology, such as the "preparation method of an enzyme-like water treatment agent" (CN102350300A) patented technology, which is characterized by the preparation of an enzyme-like water treatment agent with cheap raw materials , but there are deficiencies such as complex preparation process, poor operability, narrow COD range of treated wastewater, and need to increase pretreatment process
Although the study of enzyme-like catalysts has attracted widespread attention, there are few reports on the application of the regeneration treatment of industrial organic wastewater

Method used

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  • A method for regenerating and treating organic wastewater using an enzyme-like magnetic catalyst
  • A method for regenerating and treating organic wastewater using an enzyme-like magnetic catalyst

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Embodiment 1

[0027] The invention discloses a method for regenerating and treating organic wastewater by adopting an enzyme-like magnetic catalyst. The organic wastewater to be regenerated in this example is taken from the effluent after the secondary biochemical treatment of wastewater from a coking plant of an iron and steel complex: the COD value is 150-300 mg / L, the chroma is 300-400 times, and the pH value is 6.5-8.2.

[0028] The method for regenerating the organic wastewater in this embodiment is as follows: figure 1 Shown:

[0029] Step 1: Add inorganic acid to the organic wastewater entering the cyclone mixer 1 to adjust the pH to 3.5-6, and the acidified organic wastewater after pH adjustment enters the catalytic degradation reactor 2.

[0030] Step 2, adding the imitative enzyme-type magnetic catalyst into the catalytic degradation reactor 2 equipped with acidified organic wastewater, and then adding H 2 o 2 , an enzyme-like magnetic catalyst: H 2 o 2 The mass ratio is 1:1....

Embodiment 2

[0037] The invention discloses a method for regenerating and treating organic wastewater by adopting an enzyme-like magnetic catalyst. The organic wastewater to be regenerated in this embodiment is taken from the effluent of an independent coking plant after secondary biochemical treatment, with a COD value of 250-450 mg / L, a chroma of 400-600 times, and a pH value of 6.2-8.5.

[0038] The method for regenerating the organic wastewater in this embodiment is as follows: figure 1 Shown:

[0039] Step 1: Add inorganic acid to the organic wastewater entering the cyclone mixer 1 to adjust the pH to 3.5-6, and the acidified organic wastewater after pH adjustment enters the catalytic degradation reactor 2.

[0040] Step 2, adding the imitative enzyme-type magnetic catalyst into the catalytic degradation reactor 2 equipped with acidified organic wastewater, and then adding H 2 o2 , an enzyme-like magnetic catalyst: H 2 o 2 The mass ratio is 1:1.5~2.0. Then, under the condition of...

Embodiment 3

[0047] The invention discloses a method for regenerating and treating organic wastewater by adopting an enzyme-like magnetic catalyst. The organic wastewater for regeneration treatment in this example is taken from the effluent after secondary biochemical treatment of wastewater from a new coal chemical coking plant: the COD value is 400-600 mg / L, the chroma is 500-700 times, and the pH value is 5.8-8.0.

[0048] The method for regenerating the organic wastewater in this embodiment is as follows: figure 1 Shown:

[0049] Step 1: Add inorganic acid to the organic wastewater entering the cyclone mixer 1 to adjust the pH to 3.5-6, and the acidified organic wastewater after pH adjustment enters the catalytic degradation reactor 2.

[0050] Step 2, adding the imitative enzyme-type magnetic catalyst into the catalytic degradation reactor 2 equipped with acidified organic wastewater, and then adding H 2 o 2 , an enzyme-like magnetic catalyst: H 2 o 2 The mass ratio is 1:2.0~2.5....

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Abstract

The invention relates to a regenerating method of organic waste water by adoption of an enzyme-mimic magnetic catalyst. According to the technical scheme, the method includes adding an inorganic acid into the organic waste water fed into a vortex mixer (1), adjusting pH to 3.5-6, feeding the acidified organic waste water after pH adjustment into a catalytic degradation reactor (2), adding the enzyme-mimic magnetic catalyst into the catalytic degradation reactor (2) containing the acidified organic waste water, adding H2O2 with the mass ratio of the enzyme-mimic magnetic catalyst to the H2O2 being 1:1-4.5, stirring at 20-30 DEG C with air blowing by an air blower (3) for 60-120 min to obtain suspension, allowing the suspension to flow automatically into a catalyst separation column (4), allowing the suspension to stand for 10-30 min under the action of a magnetic field, returning the enzyme-mimic magnetic catalyst in the lower layer to the catalytic degradation reactor (2) through a return pipe (5) to be reutilized, and using the supernatant liquid as industrial reclaimed water. The method has characteristics of simple process, high operationality, low investment, low operation cost, low running cost, and wide COD ranges of treated water.

Description

technical field [0001] The invention belongs to the technical field of organic wastewater treatment. In particular, it relates to a method for regenerating and treating organic wastewater by adopting an enzyme-like magnetic catalyst. Background technique [0002] The composition of industrial organic wastewater is complex, especially the organic components in coking wastewater are more complex, containing a large amount of aromatic hydrocarbons, polycyclic aromatic hydrocarbons and heterocyclic aromatic hydrocarbons, etc., its COD value is generally above 2000mg / L, and the color is darker, which is relatively Refractory industrial organic wastewater. The effluent treated by the traditional biochemical process still contains a relatively high concentration of refractory biodegradable organic matter. It is difficult for COD and chroma to meet the standards of industrial recycled water. Direct discharge will cause serious pollution and poisoning of the environment and ecology....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/04
Inventor 王光华李文兵王登富陈坤万栋胡琴梁玉河鲁露露
Owner WUHAN UNIV OF SCI & TECH
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