Isoflavones contained in tobacco and its preparation method and application
A kind of compound, technology of isoflavone, application in antioxidant and anti-HIV-1, isoflavone compound and preparation field thereof
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Embodiment 1
[0027] -Preparation of the compound
[0028] The tobacco sample was collected in Yuxi, Yunnan, and the variety was Yunyan-85. Sample 2.2kg of tobacco sample and crush it to 30 meshes, extract 3 times with 70% acetone ultrasonically, combine the extracts, filter, concentrate the extracts under reduced pressure to 1 / 6 of the original volume of the extracts, filter the precipitate after standing The filtrate was extracted with ethyl acetate three times, the ethyl acetate extracts were combined and concentrated into an extract to obtain 42.8 g of extract.
[0029] The extract is dissolved with appropriate amount of chloroform and mixed with 80g crude silica gel (80-100 mesh), 1.5kg silica gel (160-200 mesh) is packed in a column for silica gel column chromatography, the volume ratio of chloroform:acetone (1:0→0: 1) Gradient elution, TLC monitoring and merging the same parts to obtain 8 parts (pure chloroform, chloroform-acetone 20:1, chloroform-acetone 9:1, chloroform-acetone 8:2, chl...
Embodiment 2
[0031] -Preparation of the compound
[0032] The tobacco sample was collected in Yuxi, Yunnan, and the variety was Yunyan-85. Sample 2.2kg of tobacco sample and crush it to 30 mesh, extract 3 times with 70% acetone ultrasonically, combine the extracts, filter, concentrate the extracts under reduced pressure to 1 / 4 of the original volume of the extracts, filter the precipitate after standing The filtrate was extracted 3 times with ethyl acetate, and the ethyl acetate extracts were combined and concentrated into an extract to obtain 42.7 g of extract.
[0033] The extract is dissolved with appropriate amount of chloroform and mixed with 80g crude silica gel (80-100 mesh), 1.5kg silica gel (160-200 mesh) is packed in a column for silica gel column chromatography, the volume ratio of chloroform:acetone (1:0→0: 1) Gradient elution, TLC monitoring and merging the same parts to obtain 8 parts (pure chloroform, chloroform-acetone 20:1, chloroform-acetone 9:1, chloroform-acetone 8:2, chlor...
Embodiment 3
[0035] -Preparation of the compound
[0036] The tobacco sample was collected in Yuxi, Yunnan, and the variety was Yunyan-85. Sample 2.2kg of tobacco sample and crush it to 30 meshes, extract 3 times with 70% acetone ultrasonically, combine the extracts, filter, concentrate the extracts under reduced pressure to 1 / 5 of the original volume of the extracts, filter the precipitate after standing The filtrate was extracted 3 times with ethyl acetate, and the ethyl acetate extracts were combined and concentrated into an extract to obtain 42.9 g of extract.
[0037] The extract is dissolved with appropriate amount of chloroform and mixed with 80g crude silica gel (80-100 mesh), 1.5kg silica gel (160-200 mesh) is packed in a column for silica gel column chromatography, the volume ratio of chloroform:acetone (1:0→0: 1) Gradient elution, TLC monitoring and merging the same parts to obtain 8 parts (pure chloroform, chloroform-acetone 20:1, chloroform-acetone 9:1, chloroform-acetone 8:2, chl...
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