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Crude Oil, Sludge, and Emulsion Treatment Methods

A sludge and mixture technology, applied in sludge treatment, water/sludge/sewage treatment, dehydration/drying/thickened sludge treatment, etc., can solve the problems of time-consuming, hydrocarbon loss, highly polluted oil and bound water, etc. problem, to achieve the effect of improving commercial value and preventing accumulation

Inactive Publication Date: 2017-06-06
NAGAARJUNA SHUBHO GREEN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0023] However, even bioremediation techniques have certain limitations
First, the bioremediation process results in the loss of all valuable hydrocarbons, which is highly undesirable
Second, the bioremediation process is expensive and consumes a lot of time in the waste disposal process
First, air flotation is only feasible at oil concentrations up to 200ppm, it cannot go beyond said ppm level
Second, these techniques utilize surfactants, whose highly polluting oil and bound water qualities

Method used

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  • Crude Oil, Sludge, and Emulsion Treatment Methods
  • Crude Oil, Sludge, and Emulsion Treatment Methods
  • Crude Oil, Sludge, and Emulsion Treatment Methods

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0125] Table 1.1 - Description of laboratory oils

[0126] SI number illustrate furnace oil diesel fuel 1 Water weight percent in hydrocarbon per BTX 0.21 0.01 2 Calorific value of oil (kcal / kg) 10,173 11,002 3 Weight percent of ash in oil 0.23 0.00

[0127] Table 1.2 - Preparation of Furnace Oil Sludge

[0128]

[0129]

[0130] Table 1.3 - Preparation of Diesel Sludge

[0131]

[0132] Preparation of sludge / emulsion for subsequent removal of bound and free water

[0133] A predetermined amount of internal sludge is prepared with viscous / non-viscous hydrocarbon water, for understanding the sludge, and also for subsequent removal of all bound water therefrom. Therefore, if present, weighed water, hydrocarbons and sodium lauryl sulfate as an emulsifier were mixed and stirred using a high-speed shear mixer at 10,000 rpm for 1 minute and performed 5 times while ensuring that the temperature of the mixed material was insulated...

Embodiment 2

[0136] Pretreatment of incoming sludge / emulsion using a centrifuge

[0137] The purpose was to determine the degree of bound water present in the incoming sludge, thereby separating it into sludge with bound water and waste oil by centrifuge. Furthermore, the aim was to establish the recovery of value-added marketable hydrocarbons with a batch centrifuge alone; it was possible to remove a part of the water present and also reduce the amount of sludge, which required further treatment. Therefore, the sludge prepared in-house and the lagoon sludge procured from India's Oil and Natural Gas Corporation (ONGC) were treated in a batch centrifuge at 4,500 and 21,853 RCF with different residence times to separate and weigh the fractions after that, The centrifuged material is then mass balanced. In addition, the moisture content of these fractions was evaluated by the BTX method, followed by the ash content by heating in a muffle furnace, followed by evaluation of the calorific value...

Embodiment 3

[0168] Effect of using xylene as solvent on sludge with bound water

[0169] The effect of releasing bound water from sludge over time was studied by reducing the viscosity of the sludge by adding different amounts of low-viscosity solvents, such as xylene, at room temperature and elevated temperature. In addition, it was discovered how water is simply captured by hydrocarbons. Therefore, about 58 wt.% and 200 wt.% of xylene were added to viscous furnace oil sludge, which did not contain internally produced sodium lauryl sulfate, but had 50 wt.% bound water. Alternatively, about 58 wt.% and 200 wt.% xylenes were added to viscous furnace oil sludge with 20.47 wt.% bound water and 3.74 wt.% sodium lauryl sulfate, the sludge was Extracted from sludge with 47.5 wt.% water and 2.51 wt.% sodium lauryl sulfate inside by centrifugation at 21,893 RCF for 10 minutes. Additionally, 58wt.% and 200wt.% of xylene were added to viscous ONGC sludge with 42.21wt.% bound water and 8.61wt.% as...

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Abstract

The present invention discloses a process for treating petroleum / coarse sludge for the removal of bound and unbound water, thereby facilitating the recovery of free product hydrocarbons in the range of about 96wt% - 100wt% non-volatiles and at least low turbidity Unbound water at 20NTU. The method of treating the sludge facilitates the recovery of almost about 100% of the solvent and the total bound water in the range of about 99 wt %−100 wt %. This method of treating sludge helps to recover free water in the range of about 94 wt %-99 wt %. This method of treating sludge also facilitates the recovery of solvents that are reused in the process. The present invention further discloses a method of treating waste oil containing water, solids, salts and limited hydrocarbons in an amount less than 10,000 ppm for recovering useful water therefrom in an efficient and economically viable manner. The method for treating waste oil can reduce its turbidity in the range of 90wt%-99wt%.

Description

technical field [0001] The present invention relates to the treatment method of petroleum / coarse sludge, emulsion and waste oil. More specifically, the present invention relates to a method for removing bound and unbound water from petroleum / coarse sludge, emulsions and waste oils containing hydrocarbons, bound water, unbound water, dissolved and undissolved solids, to Turning it into salable fluids of varying purity, in particular, is not a method limited to the oil industry. Background technique [0002] Petroleum crude oil comes out of an oil well always with water, dissolved and undissolved solids and a portion of sulfur compounds with bound and unbound water. The petrocrude is then processed at the Group Collection Center (hereinafter referred to as GCC) of the oil company, where, first, the petrocrude is desulfurized and then unbound water and undissolved solids are removed. However, GCC cannot remove bound water and dissolved solids, except in the case of demulsifie...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/04C02F11/14C10G31/10
CPCC10G31/08C10G33/06C10G53/02C10G1/002C10G1/045C02F1/04C02F11/127C02F11/14C10G31/00C10G31/10C10G33/04
Inventor 德鲁瓦·乔蒂·达斯古普塔
Owner NAGAARJUNA SHUBHO GREEN TECH