Phenolic resin black function master batch and preparation method thereof

A technology of phenolic resin and functional masterbatch, which is applied in the field of phenolic resin black functional masterbatch and its preparation, can solve the problems of affecting the curing speed of phenolic resin, limitation of dispersion and utilization of carbon black, unsightly appearance of products, etc., so as to improve the dyeing ability , The heat distortion temperature is increased, and the softness is good.

Active Publication Date: 2015-12-16
延安金瓯科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This traditional process has a certain effect on reducing the dyeing cost of phenolic molding compounds; but it has certain limitations on the dispersion and utilization of carbon black
The main disadvantages are as follows: (1) The dosage is relatively large; (2) The dispersion is uneven; (3) The appearance of the product is not beautiful; (4) The product

Method used

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  • Phenolic resin black function master batch and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A phenolic resin black functional masterbatch of type F081-A was prepared. It is prepared from the following raw materials in parts by weight: 0.1 part of nano-calcium carbonate, 0.3 part of nano-montmorillonite, 6 parts of pigment carbon black, 0.1 part of dispersant, 0.1 part of lubricant, 0.01 part of defoamer, and 0.2 part of emulsifier part, 0.2 part of coupling agent.

[0034] The preparation method of the phenolic resin black functional masterbatch of model F081-A, carry out as follows:

[0035] Step 1: Pre-dispersion

[0036] Put nano-calcium carbonate and nano-montmorillonite in a high-speed mixer; add dispersant, lubricant, and stir at high speed for 1-3 minutes; then add coupling agent and continue stirring for 1-2 minutes; then add pigment carbon black , continue to stir for 5 to 8 minutes, and keep the temperature at 25°C to 45°C.

[0037] Step 2: Ball Mill Dispersion or Ultrasonic Dispersion

[0038] Put the material obtained in step 1 into a ball mill...

Embodiment 2

[0042]A phenolic resin black functional masterbatch of type F082-A was prepared. It is prepared from the following raw materials in parts by weight: 0.1 part of nano-montmorillonite, 0.4 part of nano-silica, 8 parts of pigment carbon black, 0.1 part of dispersant, 0.15 part of lubricant, 0.01 part of defoamer, emulsifier 0.1 part, 0.2 part of coupling agent.

[0043] The preparation method of the phenolic resin black functional masterbatch of model F082-A, carry out as follows:

[0044] Step 1: Pre-dispersion

[0045] Put nano-montmorillonite and nano-silica in a high-speed mixer; add dispersant, lubricant, and stir at high speed for 1-3 minutes; then add coupling agent and continue stirring for 1-2 minutes; then add pigment carbon black, continue stirring for 5-8 minutes, and keep the temperature at 25°C-45°C.

[0046] Step 2: Ball Mill Dispersion or Ultrasonic Dispersion

[0047] Put the material obtained in step 1 into a ball mill or ultrasonic dispersion equipment for ...

Embodiment 1-1F081

[0051] Embodiment 1-1F081 model phenolic resin black functional masterbatch

[0052] The specific steps of preparation are as follows: In a 500mL three-necked flask equipped with a stirrer, a condenser, and a thermometer, first add 200g of molten phenol, and then add 148g of formaldehyde according to the molar ratio of phenol to formaldehyde of 1:0.74, start stirring, and heat to make the reaction The temperature of the system is controlled to react at 100°C-104°C. When the liquid is observed to reflux, 2g-10g of catalyst is added according to the condition of 1%-5% of the phenol mass. The catalyst is inorganic acid or organic acid, i.e. hydrochloric acid, sulfuric acid or oxalic acid, continue to react for 1h-2h, when the liquid is observed to be turbid, add 4g-10g of composite functional black dye F081-A emulsion according to the proportion, and reflux for 1.5h-2h , start dehydration under reduced pressure, and when the resin reaches a certain viscosity (10-15Pa·s), the poly...

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Abstract

The invention provides a phenolic resin black function master batch and a preparation method thereof. The phenolic resin black function master batch is prepared from the following raw materials by weight: 200 parts of phenyl hydroxide, 148 to 152 parts of formaldehyde, 2 to 10 parts of a catalyst, and 4 parts of a composite functional black coloring agent. The preparation method comprises the following steps: first, adding molten phenyl hydroxide into a three-mouth beaker equipped with a stirrer, a condenser and a thermometer, adding formaldehyde according to the weight ratio, and carrying out stirring and heating to ensure that the temperature of the reaction system is 100 to 104 DEG C; adding the catalyst according to the weight ratio for a 1 to 2 hours' reaction when the liquid flows back; adding the composite functional black coloring agent according to the weight ratio when the liquid becomes turbid, carrying out a backflow reaction for 1.5 to 2 hours, dehydrating under decompression, carrying out a polycondensation synthesis reaction when the viscosity of resin reaches up to a certain value, discharging fast after the polycondensation synthesis reaction is finished, and carrying out cooling and smashing for treatment. The master batch is good in dyeing property and flowability, can be added with an optional quantity, and can be used for improving toughness effect and rising heat distortion temperature, so that the comprehensive performance is improved remarkably.

Description

technical field [0001] The invention relates to a phenolic resin black functional masterbatch and a preparation method thereof, in particular to a phenolic resin black functional masterbatch using nano-material modified pigment carbon black as a dyeing agent and a preparation method thereof. Background technique [0002] Phenolic resin is a polymer material that is polymerized with phenol and formaldehyde as raw materials under the condition of acidic catalyst (or basic catalyst). Its production process is stable and easy to operate, the price of raw materials is low, and it has many advantages such as good heat resistance, electrical insulation, corrosion resistance, low smoke generation, and product dimensional stability. Therefore, phenolic molding compound (commonly known as bakelite powder) with phenolic resin as the main raw material is widely used in many fields such as household appliances, household cooking utensils, aerospace, and automobile industry. Among the ma...

Claims

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Application Information

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IPC IPC(8): C08L61/10C08K13/06C08K9/06C08K3/34C08K3/26C08K3/22C08K3/04C08G8/10
Inventor 范忠庆姚建明黄振贻陈锦胜林月红林海陈启好姚岩松
Owner 延安金瓯科技发展有限公司
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