Application of alkaline polishing solution in improving surface roughness of barrier layer in CMP

A technology of surface roughness and polishing liquid, applied in polishing compositions containing abrasives, etc., to reduce surface roughness, speed up mass transfer, and achieve the effect of flattening the polishing surface

Inactive Publication Date: 2016-06-08
TIANJIN JINGLING MICROELECTRONIC MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

None of the above-mentioned patent methods mentioned the problem of effectively improving the surface roughness after polishing

Method used

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  • Application of alkaline polishing solution in improving surface roughness of barrier layer in CMP
  • Application of alkaline polishing solution in improving surface roughness of barrier layer in CMP
  • Application of alkaline polishing solution in improving surface roughness of barrier layer in CMP

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Put 1ml of FA / OⅡ chelating agent into 400ml of ultrapure water, then pour 0ml of FA / OⅠsurfactant into the ultrapure water, stir continuously during the process, add a small amount of ultrapure water to make it solution after it is completely mixed The volume reaches 500ml, and then these mixed solutions are poured into 500ml of SiO 2 In the hydrosol, stir continuously during the process until it is completely poured. Then under the process of working pressure: 27.4kpa; polishing head / polishing disc speed: 105 / 100rpm; flow rate: 150mL / min, the graphic sheet is polished for 180s, and the surface roughness of the barrier layer is checked with an atomic force microscope after polishing;

Embodiment 2

[0025] Put 1ml of FA / OⅡ chelating agent into 400ml of ultrapure water, then pour 5ml of FA / OⅠsurfactant into the ultrapure water, stir continuously during the process, add a small amount of ultrapure water to make it solution after it is completely mixed The volume reaches 500ml, and then these mixed solutions are poured into 500ml of SiO 2 In the hydrosol, stir continuously during the process until it is completely poured. Then under the process of working pressure: 27.4kpa; polishing head / polishing disc speed: 105 / 100rpm; flow rate: 150mL / min, the graphic sheet is polished for 180s, and the surface roughness of the barrier layer is checked with an atomic force microscope after polishing;

Embodiment 3

[0027] Put 1ml of FA / OⅡ chelating agent into 400ml of ultrapure water, then pour 10ml of FA / OⅠsurfactant into the ultrapure water, stir continuously during the process, after it is completely mixed, add a small amount of ultrapure water to make it solution The volume reaches 500ml, and then these mixed solutions are poured into 500ml of SiO 2 In the hydrosol, stir continuously during the process until it is completely poured. Then under the process of working pressure: 27.4kpa; polishing head / polishing disc speed: 105 / 100rpm; flow rate: 150mL / min, the graphic sheet is polished for 180s, and the surface roughness of the barrier layer is checked with an atomic force microscope after polishing;

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Abstract

The invention relates to an application of an alkaline polishing solution in improving surface roughness of a barrier layer in CMP. The alkaline polishing solution is mainly composed of an abrasive compound, an FA / O II chelating agent, an FA / O I surfactant and ultrapure water, and is characterized in that the FA / O I surfactant has infiltration capacity which enables the alkaline polishing solution to effectively improve surface roughness of the barrier layer. The invention has beneficial effects as follows: the FA / O I surfactant in the alkaline polishing solution has high infiltration capacity, which helps transport a polishing product by the polishing solution; by wetting action, the FA / O I surfactant molecules rapidly spread out on the surface of a wafer so as to form a uniform and compact protective layer; and the FA / O I surfactant in the polishing solution can accelerate mass transfer of the polishing product, removal rate of convex-concave part on the surface of the barrier layer of the wafer is different, height difference of the convex-concave part is reduced, surface roughness is decreased, and planarization of the polished surface is realized.

Description

technical field [0001] The invention belongs to the field of chemical mechanical polishing, and in particular relates to the application of an alkaline polishing liquid to improve the surface roughness of a barrier layer in CMP. Background technique [0002] In very large scale integration (GLSI) multilayer wiring chemical mechanical planarization (CMP), the surface roughness after polishing is too high, which will cause increased noise, poor consistency of electrical characteristics, and affect device frequency characteristics such as increasing RC delay time, etc. , thus affecting the degree of integration, reliability, excellent product rate and cost reduction. There are many factors that affect the surface roughness, including the polishing process conditions (such as temperature, pressure, flow rate, etc.), the composition of the polishing liquid, the selection of the polishing cloth, and so on. The traditional copper interconnect polishing process is usually divided i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/02
CPCC09G1/02
Inventor 刘玉岭郑环潘国峰
Owner TIANJIN JINGLING MICROELECTRONIC MATERIALS CO LTD
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