A method for remediation of surface water contaminated sediment and control of nutrient release
A bottom mud and surface technology, applied in water/sludge/sewage treatment, sludge treatment, sludge treatment, etc., can solve the problem that the fixing capacity of zirconium-modified zeolite is not very high, and achieve long effective duration and good repair , The effect of reducing the gas supply
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Embodiment 1
[0036] Example 1 Preparation of zirconium calcium modified zeolite (1)
[0037] Herein, the natural zeolite refers to an aluminosilicate crystal mineral with a skeleton structure existing in nature.
[0038] (a) Preparation of calcium-modified zeolite: use calcium chloride to prepare Ca with a concentration of 1mol / L 2+ Solution, weigh a certain quality of natural zeolite and place it in a container, then pipette Ca according to the liquid-solid ratio of 10mL / g 2+ The solution was fully mixed with the natural zeolite; the container was placed in a shaker and reacted for 24 hours under the reaction conditions of 150rpm and 25°C. After the reaction, the solid-liquid separation was carried out to obtain a solid material, and then the solid material was washed repeatedly until the AgNO 3 The solution does not detect Cl in the cleaning solution - , and dry to obtain calcium-modified zeolite;
[0039] (b) the calcium-modified zeolite and zirconium oxychloride octahydrate prepared...
Embodiment 2
[0040] Example 2 Preparation of Zirconium Calcium Modified Zeolite (2)
[0041] (a) Preparation of calcium-modified zeolite: adopting calcium chloride to prepare Ca with a concentration of 0.2mol / L 2+ Solution, weigh a certain quality of natural zeolite and place it in a container, then pipette Ca according to the liquid-solid ratio of 1mL / g 2+The solution was fully mixed with the natural zeolite; the container was placed in a shaker and reacted for 96 hours under the reaction conditions of 150rpm and 25°C. After the reaction, the solid-liquid separation was carried out to obtain a solid material, and then the solid material was washed repeatedly until the AgNO 3 The solution does not detect Cl in the cleaning solution - , and dry to obtain calcium-modified zeolite;
[0042] (b) the calcium-modified zeolite and zirconium oxychloride octahydrate prepared by step (a) are added together in the container, so that the mass ratio of calcium-modified zeolite and zirconium oxychlori...
Embodiment 3
[0043] Example 3 Preparation of Zirconium Calcium Modified Zeolite (3)
[0044] (a) Preparation of calcium-modified zeolite: use calcium chloride to prepare Ca with a concentration of 2.0mol / L 2+ Solution, weigh a certain quality of natural zeolite and place it in a container, then pipette Ca according to the liquid-solid ratio of 1000mL / g 2+ The solution was fully mixed with the natural zeolite; the container was placed in a shaker and reacted for 0.5h under the reaction conditions of 150rpm and 25°C. After the reaction, the solid-liquid separation was carried out to obtain a solid material, and then the solid material was washed repeatedly until the AgNO 3 The solution does not detect Cl in the cleaning solution - , and dry to obtain calcium-modified zeolite;
[0045] (b) the calcium-modified zeolite and zirconium oxychloride octahydrate prepared by step (a) are added together in the container, so that the mass ratio of calcium-modified zeolite and zirconium oxychloride oc...
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