Lithium ion power battery charging method capable of controlling battery degradation based on temperatures
A charging method and power battery technology, applied in the direction of secondary battery charging/discharging, secondary battery repair/maintenance, etc., can solve the problems of not considering the influence of temperature on battery charging characteristics, affecting battery life, accelerating side reactions, etc. Achieve the effect of improving service life, reducing battery attenuation, and controlling attenuation
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[0035] The embodiment uses the battery q of 50Ah battery, starting temperature T and V 临界 The relationship between them is (Table 1):
[0036] q (unit is %)
[0037] V within Table 1 above 临界 Values are V at the temperature in brackets 临界 , where V at -20°C 临界 Specifies the theoretical charging upper limit voltage for the battery, V at -15 and 10°C 临界 It is the lithium analysis voltage; when the battery is charged to 4.2V with a standard current constant current at -20°C, q=9.7%. At this time, the charging capacity is low, and the battery has not reached the lithium analysis voltage. From the table above, the T of the battery 1 -20°C, T 2 is 0°C.
Embodiment 1
[0041] Example 1: T=-15°C, T 1 2
[0042] Measure the initial temperature of the battery at -15°C, V 临界 is 4.07V. The battery is charged with a constant voltage pulse from -15°C. As the charge progresses, the battery temperature rises to Tc>T 2 When the temperature is set at 2°C (>0°C), stop the constant voltage pulse charging; at this time, charge with a constant current of 1 / 3C to 4.107V (2°C), then switch to a constant voltage of 4.107V to charge until the current is about 1 / 3C 30C or constant pressure time 1h. Among them, the pulse charging adopts a 4-step pulse process, and the pulse voltages are 4.07V (-15°C), 4.08V (-10°C), 4.09V (-5°C), and 4.10V (0°C), and the pulse voltages are respectively in brackets V at internal temperature 临界 . The temperature intervals were 5°C (heated to 0°C) and 2°C (heated to the target 2°C), the single pulse time was 0.2s, and the rest time after a single pulse was 0.2s.
[0043] The constant voltage pulse charging parameters are sho...
Embodiment 2
[0049] Example 2: T=10°C, T>T 2
[0050] Battery test temperature 10°C, V 临界 is 4.13V. The charging method of the battery at 10°C adopts 1C constant current charging to 4.13V (V 临界 ) and then switch to constant voltage (4.13V) to charge until the current drops to 0.1C or the constant voltage time is 1h.
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