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A kind of comprehensive treatment agent for offshore oil field produced fluid and preparation method thereof

A comprehensive treatment agent and technology for offshore oil fields, which are applied in the field of comprehensive treatment agents for produced liquids in offshore oil fields and their preparation, can solve problems such as deterioration of main indicators of production water systems, difficulty in eliminating them, pollution of sewage treatment equipment, etc., and eliminate the phenomenon of crude oil emulsification. , Strong demulsification and dehydration performance, the effect of improving the demulsification effect

Active Publication Date: 2018-06-26
CNOOC TIANJIN CHEM RES & DESIGN INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the application of tertiary oil recovery techniques such as polymer injection and thermal recovery and various production stimulation measures, the physical properties of the produced fluid have changed greatly, and the degree of emulsification has become more serious. The capacity increases, and the mechanical impurities in free water increase. Under such complex emulsification conditions, conventional demulsifiers are no longer suitable, and the oil-water sedimentation separation speed slows down. Under the conventional separation temperature and time conditions, the oil content of sewage and the water content in oil They are all very high, and there is a serious oil-water intermediate transition layer during the separation process. It is difficult to eliminate the emulsion of the crude oil system by conventional demulsifiers, it is difficult to dehydrate the crude oil, the electric dehydration current remains high, and even trips. The electric dehydrator of the crude oil electric dehydrator will be broken down due to the problem of the emulsion; at the same time, the high oily sewage enters the sewage system, the sewage treatment equipment is seriously polluted, and the main indicators of the control of the production water system also deteriorate
The dosage of water purifying agent in the sewage system has increased sharply, generating a large amount of sludge, resulting in serious dirty and clogged filters in the production process, causing serious safety hazards in production

Method used

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  • A kind of comprehensive treatment agent for offshore oil field produced fluid and preparation method thereof
  • A kind of comprehensive treatment agent for offshore oil field produced fluid and preparation method thereof
  • A kind of comprehensive treatment agent for offshore oil field produced fluid and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Preparation of comprehensive treatment agent for offshore oilfield production fluid: In a closed reactor, add 18g of allyl polyether (molecular weight is 3000, wherein EO:PO=0.5:1), and then add 4g of hydrogen-containing silicone oil (hydrogen content 1.58 %), and 1g sodium allyl sulfonate, add catalyst chloroplatinic acid, stir after the reactor repeatedly replaces nitrogen, heat up to 100 ℃ and react for 3 hours, add 8g water-soluble multi-block polyether (molecular weight is 1000, Wherein EO:PO=2:1), heat preservation reaction for 0.5 hours, finally add 1g of acetic acid, 10g of alcohol and 30g of water into the reactor, continue to stir evenly, and finally cool and discharge to obtain the finished product I.

Embodiment 2

[0018] Preparation of comprehensive treatment agent for offshore oilfield production fluid: In a closed reactor, add 18g of allyl polyether (molecular weight is 4000, wherein EO:PO=0.5:1), and then add 4g of hydrogen-containing silicone oil (hydrogen content 1.58 %), and 1g sodium allyl sulfonate, add catalyst chloroplatinic acid, stir after the reactor repeatedly replaces nitrogen, heat up to 100 ℃ and react for 3 hours, add 8g water-soluble multi-block polyether (molecular weight is 1500, Among them, EO:PO=2:1), keep warm for 0.5 hours, and finally add 1g of acetic acid, 10g of alcohol and 30g of water into the reactor, continue to stir evenly, and finally cool and discharge to obtain the finished product II.

Embodiment 3

[0020] Preparation of comprehensive treatment agent for offshore oilfield production fluid: In a closed reactor, after adding 20g of allyl polyether (molecular weight is 3000, wherein EO:PO=0.5:1), add 4g of hydrogen-containing silicone oil (hydrogen content of 1.75 %), and 1g allyl sodium sulfonate, add catalyst chloroplatinic acid, stir after the reactor repeatedly replaces nitrogen, heat up to 105 ℃ and react for 3 hours, add 8g water-soluble multi-block polyether (molecular weight is 1000, Among them, EO:PO=2:1), keep warm for 0.5 hours, and finally add 1g of acetic acid, 10g of alcohol and 30g of water into the reactor, continue to stir evenly, and finally cool and discharge to obtain the finished product III.

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Abstract

The invention discloses an integrated treatment agent for produced liquid of offshore oilfields and its preparation method. The integrated treatment agent is composed of comb-like multi-branched silicon-containing polyether, water-soluble multi-block polyether, synergist, alcohol and water. The ratio of the comb-like multi-branched silicon-containing polyether, the multi-block polyether, the synergist, the alcohol and the water is 10 to 30: 5 to 10: 0.5 to 2: 5 to 10: 30. The integrated treatment agent for the produced liquid of the offshore oilfields has the dual function of the demulsification and the water purification of the crude oil produced liquid, the demulsifier, the anti-demulsifier and the cleaning agent are replaced with one chemical, the produced liquid of the offshore oilfields is effectively treated, and the purpose for qualitative treatment of oil and water is achieved.

Description

technical field [0001] The invention relates to the field of oilfield chemicals, in particular to a comprehensive treatment agent for offshore oilfield production fluid and a preparation method thereof. Background technique [0002] With the continuous exploitation of crude oil and the application of production increase measures such as water injection in oil fields, many oil fields have entered a period of high water cut, and the water cut in Liuhua Oilfield, Wenchang Oilfield, Weizhou Oilfield, etc. located in the South China Sea has reached 90% It has entered the development stage of ultra-high water cut period, and crude oil dehydration has become a key link in the crude oil production process. So far, the methods used for crude oil dehydration at home and abroad can be summarized as: sedimentation separation, chemical demulsification, electric demulsification, and wetting and coalescence. Among them, the use of chemical demulsifiers for demulsification and dehydration i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G77/46C10G33/04
CPCC08G77/46C10G33/04
Inventor 姚光源魏清马浴铭张迪彦王惠章甦王宁
Owner CNOOC TIANJIN CHEM RES & DESIGN INST
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