Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A method of preparing furan-2,5-dicarboxylic acid from furoic acid

A technology of furandicarboxylic acid and furan formic acid, which is applied in the direction of organic chemistry, can solve the problems of low total yield, high cost, and difficulty in large-scale industrial application, and achieve the goal of less by-products, short process, and promotion of sustainable development Effect

Active Publication Date: 2017-04-05
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
View PDF3 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology describes methods for producing various types of compounds called furanoate or 5-furaldehydes (FFA). These molecules are important building blocks found naturally throughout plants like citrus peels. They have potential applications in different industries including medicine, chemistry, electronics, energy storage devices, etc., where they may help improve their performance characteristics over existing products.

Problems solved by technology

This patented technical problem addressed by this patents relates to finding an efficient way for producing various types of polymer materials that contain both these structurally diverse components - called hydrogen bonds or pyrrolobenzene rings.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A method of preparing furan-2,5-dicarboxylic acid from furoic acid
  • A method of preparing furan-2,5-dicarboxylic acid from furoic acid
  • A method of preparing furan-2,5-dicarboxylic acid from furoic acid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] Take 11.2g of furoic acid monomer and put it into a 100ml reactor, add 20.4g of acetic anhydride, and react with 0.02mol concentrated sulfuric acid at 160°C for 2 hours. Base-5-furancarboxylic acid, yield 86%, liquid phase mass spectrometry (LC-MS) records molecular weight 154.0, 1 H-NMR (400MHz, deuterated chloroform CDCl3) test obtained, CH on the furan ring, 1H, δ (7.44); CH on the furan ring, 1H, δ (7.47); CH 3 , 3H, δ(2.59). Elemental analysis C7H6O4 calculated value C: 54.55, H: 3.92, O: 41.52; measured value C: 54.61, H: 4.10, O: 41.55.

[0061] In a 250ml reactor, dissolve 3.08g of 2-acetyl-5-furancarboxylic acid in 20ml of water, add 35.5g of iodine and 200ml of water dropwise at 20°C, then add NaOH aqueous solution (concentration is 2mol / L) dropwise to adjust the pH 7, the precipitate was removed by filtration, the pH value of the reaction solution was adjusted to 1 with hydrochloric acid (concentration: 0.5 mol / L), the precipitated solid was filtered and dr...

Embodiment 2

[0064] Take 11.2g of furoic acid monomer and put it into a 250ml reactor, add 102.6g of chloroacetic anhydride, and react with 0.025mol of concentrated nitric acid at 200°C for 0.5h. After the reaction is completed, cool down to room temperature, distill off chloroacetic anhydride under reduced pressure, and sublimate to obtain white crystals 2-Chloroacetyl-5-furancarboxylic acid, yield 93%, liquid phase mass spectrometry (LC-MS) measured molecular weight 188.6, 1 H-NMR (400MHz, CDCl 3 ) test, CH on the furan ring, 1H, δ (7.44); CH on the furan ring, 1H, δ (7.47); CH 2 , 2H, δ (4.83).

[0065] In a 250ml reactor, dissolve 3.77g of 2-chloroacetyl-5-furancarboxylic acid in 100ml of water, slowly feed 0.2mol of chlorine gas at 40°C, and at the same time add KOH aqueous solution (concentration: 1mol / L) dropwise, and then add chlorine gas Finish adjusting pH with KOH solution (concentration is 1mol / L) to be 7, filter to remove precipitate, use sulfuric acid (concentration is 0.5m...

Embodiment 3

[0068] Take 5.6g of furoic acid monomer and put it into a 250ml reactor, add 57.8g of trifluoroacetic anhydride, and react with 0.005mol concentrated hydrochloric acid at 160°C for 6h. Crystalline 2-trifluoroacetyl-5-furancarboxylic acid, yield 88%, molecular weight 207.0 as measured by liquid chromatography mass spectrometry (LC-MS), 1 H-NMR (400MHz, CDCl 3 ) test, CH on the furan ring, 1H, δ (7.74); CH on the furan ring, 1H, δ (7.97).

[0069] In a 250ml reactor, 4.14g of 2-trifluoroacetyl-5-furancarboxylic acid was dissolved in 20ml of water, 10.0g of bromine and 50ml of water were added at 60°C, and then LiOH aqueous solution (concentration was 2mol / L) was added dropwise, Adjust the pH to 7, remove the precipitate by filtration, adjust the pH of the reaction solution to 1 with phosphoric acid (concentration: 1 mol / L), filter the precipitated solid and dry it to obtain 2,5-furandicarboxylic acid with a yield of 70%.

[0070] through 1 H-NMR (400MHz, DMSO) test, CH on the...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Molecular weightaaaaaaaaaa
Molecular weightaaaaaaaaaa
Molecular weightaaaaaaaaaa
Login to View More

Abstract

A method of preparing furan-2,5-dicarboxylic acid is provided. Furoic acid is adopted as a raw material and is subjected to acylation to obtain 2-acyl-5-furancarboxylic acid, and then the furan-2,5-dicarboxylic acid is prepared into the furan-2,5-dicarboxylic acid with a high yield. The method has characteristics of simplicity, a high efficiency, short procedures and few side products. The furan-2,5-dicarboxylic acid prepared by the method is high in purity, and can meet requirements on raw materials of high-performance polyester, epoxy resin, polyamide, polyurethane, and other types of engineering plastic, requirements on chemical raw materials and requirements on medicine intermediate raw materials.

Description

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com