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Preparation method of cerium-based sulfate catalyst for SCR (selective catalytic reduction) reaction

A catalyst and sulfate technology, which is applied in the field of preparation of cerium-based SCR catalysts to achieve good application prospects and good catalytic activity.

Active Publication Date: 2017-05-10
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, there are no literature and patent reports on the use of such sulfate catalysts in SCR reactions

Method used

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  • Preparation method of cerium-based sulfate catalyst for SCR (selective catalytic reduction) reaction
  • Preparation method of cerium-based sulfate catalyst for SCR (selective catalytic reduction) reaction
  • Preparation method of cerium-based sulfate catalyst for SCR (selective catalytic reduction) reaction

Examples

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Effect test

Embodiment 1

[0026] Accurately weigh 1.93g of Ce(SO 4 ) 2 , adding 9g of titanium dioxide, grinding and mixing at room temperature to obtain a mixture. The above mixture was added into a crucible with a lid, kept in a muffle furnace at 200°C for 2h, and then heated to 580°C for 3h to obtain 1# catalyst.

Embodiment 2

[0028] Accurately weigh 1.93g of Ce(SO 4 ) 2 , adding 18g of titanyl sulfate powder, grinding and mixing at room temperature to obtain a mixture. The above mixture was added into a crucible with a lid, kept in a muffle furnace at 200°C for 2h, and then heated to 400°C for 3h to obtain 2# catalyst.

Embodiment 3

[0030] Accurately weigh Ce with a mass of 3.16g 2 (C 2 o 4 ) 3 , adding 18g of titanyl sulfate powder, grinding and mixing at room temperature to obtain a mixture. The above mixture was added into a crucible with a lid, kept in a muffle furnace at 200°C for 2h, and then heated to 400°C for 3h to obtain 3# sample.

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Abstract

A preparation method of a cerium-based sulfate catalyst for SCR (selective catalytic reduction) reaction belongs to the technical field of preparation of a rare earth based SCR catalyst. The preparation method comprises the following steps: (1) weighing raw materials, mixing and ball-milling, wherein the Ce / Ti molar ratio is between 0.02 and 0.5; and (2) transferring the mixture to a muffle furnace, roasting at the temperature of 200 to 250 DEG C, preserving the temperature for 2 to 4 hours, and performing roasting at the temperature of 400 to 650 DEG C for 2 to 6 hours. The preparation method has the characteristics that the raw materials are cheap and easily available, the preparation process is simple, the preparation condition is easy to control, the preparation process is low in discharge and the like; and the obtained catalyst has high catalytic activity.

Description

technical field [0001] The invention relates to a preparation method of a cerium-based SCR catalyst, and belongs to the technical field of preparation of rare earth-based SCR catalysts. Background technique [0002] Since the beginning of the 21st century, with the acceleration of urbanization, environmental problems have gradually become prominent, especially the continuous smog in recent years has aroused people's widespread concern and concern. The main cause of smog is atmospheric pollution. The concentration of PM2.5 seriously exceeds the standard, while nitrogen oxides (NO x ) is one of the precursors of PM2.5. Severe polluted weather has seriously interfered with people's normal life and work, and will also have adverse effects on human health. NO x It is one of the main pollutants in the atmosphere, and its main sources include automobile exhaust and emissions from industrial boilers (kilns). NO x Emission reduction is an important and challenging task at present...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/10B01D53/90B01D53/56
CPCB01D53/8628B01D53/90B01D2255/2065B01D2255/20707B01J23/10Y02P20/30
Inventor 何洪宋丽云苏垚超邱文革朱红太孙向丽
Owner BEIJING UNIV OF TECH
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