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A kind of frost-resistant and wear-resistant cement concrete and its preparation method

A technology of cement concrete and hydrogel, which is applied in the field of frost-resistant and wear-resistant cement concrete and its preparation, which can solve the problems of poor freeze-thaw resistance and poor wear resistance of cement concrete, so as to improve the damage resistance and frost resistance. Resistance and wear resistance, and the effect of promoting the hydration process

Active Publication Date: 2019-04-26
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In view of the deficiencies in the prior art, the object of the present invention is to provide a pH-sensitive hydrogel for improving the frost resistance and wear resistance of concrete, so as to solve the problem of poor freeze-thaw resistance and resistance to freezing and thawing of cement concrete in the prior art. Problems such as poor abrasiveness

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  • A kind of frost-resistant and wear-resistant cement concrete and its preparation method
  • A kind of frost-resistant and wear-resistant cement concrete and its preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0030] This embodiment provides a cement concrete, which is composed of the following raw materials in terms of mass percentage: 0.2% of cellulose ether, 1% of pH sensitive hydrogel, 17% of cement, 74% of aggregate, and 7.8% of water. %; of which fine aggregate is 25% and coarse aggregate is 49%.

[0031] Among them: the critical transition pH of the pH-sensitive hydrogel involved is 4 and 10, that is, when pH<4, the gel is in a shrinking state; when 4≤pH≤10, the gel is in a swelling state; The glue is in a contracted state.

[0032] The fineness modulus of the fine aggregate is 2.8, the mud content is 2.5%, and the apparent density is 2650kg / m 3 , bulk density is 1420kg / m 3 .

[0033] The particle size distribution of coarse aggregate is 10-31.5mm, the crushing index is 7.5%, and the apparent density is 2690kg / m 3 , the mud content is 0.5%. The total volume occupied by the aggregate in the concrete is very high. In most cases, it is difficult to reach the critical water ...

Embodiment 2

[0042] This embodiment provides a kind of frost-resistant and wear-resistant cement concrete, which is composed of the following raw materials in terms of mass percentage: 0.2% of cellulose ether, 1% of pH-sensitive hydrogel, 17% of cement, and 74% of aggregate , water is 7.8%.

[0043] In this example, the requirements for raw materials and the preparation method of antifreeze and wear-resistant cement concrete are the same as those in Example 1, except that the pH-sensitive hydrogel is prepared by dissolving 0.514g of CMC in 12.87g of deionized water, Then add 1.854g NaOH, 4.634g acrylic acid, 0.128g potassium persulfate (initiator), 0.74mL N,N'-methylenebisacrylamide solution with a mass concentration of 1g / L while stirring at 60°C (Cross-linking agent), cover the beaker with a film, and react for 1.5 hours to obtain a light red viscous liquid and obtain a pH-sensitive hydrogel.

[0044] The mass loss rate test method, relative dynamic elastic modulus test method, mechanic...

Embodiment 3

[0046] This embodiment provides a kind of freeze-thaw resistant cement concrete, which is composed of the following raw materials in terms of mass percentage: 0.3% of cellulose ether, 0.5% of pH sensitive hydrogel, 17.4% of cement, and 74% of aggregate, Water is 7.8%.

[0047] In this example, the requirements for raw materials and the preparation method of antifreeze and wear-resistant cement concrete are the same as those in Example 1. The difference is that during the preparation of the pH-sensitive hydrogel: 0.257g of CMC was dissolved in 6.435g of 0.929g NaOH, 2.319g acrylic acid, 0.06g potassium persulfate (initiator), 0.386mL N,N'-methylenebis Acrylamide solution (cross-linking agent) was covered with a beaker, and after 1.5 hours of reaction, a light red viscous liquid was obtained, and a pH-sensitive hydrogel was obtained.

[0048] The mass loss rate test method, relative dynamic elastic modulus test method, mechanical property test method, and wear resistance test m...

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Abstract

The invention provides anti-freezing and wear-resisting cement concrete and a preparation method of the anti-freezing and wear-resisting cement concrete. The cement concrete is prepared from the following raw materials: cement, aggregate, water, cellulose ether and pH (Potential of Hydrogen) sensitive hydrogel. The pH sensitive hydrogel is doped into the concrete and the mass loss of the concrete is obviously reduced under the condition that mechanical properties of the concrete are not influenced, and the anti-damage strength of the concrete is improved. The pH sensitive hydrogel is doped into the concrete and volume shrinkage of the pH sensitive hydrogel in a cement system occurs in a high-pH environment leads to water release, and a thin film net-shaped structure is formed; expansion of crack tips is reduced so that the wear-resisting performance of the concrete is improved. The pH sensitive hydrogel releases the water to promote a hydration process of cement grains in the concrete, the compactness of the concrete is increased and the content of free water and the mobility ratio are reduced, so that the anti-freezing property of the concrete is improved.

Description

technical field [0001] The invention belongs to the field of road engineering materials, and relates to cement concrete materials, in particular to a frost-resistant and wear-resistant cement concrete and a preparation method thereof. Background technique [0002] The freezing damage of concrete is that the moisture in the concrete pores is frozen, undergoes a phase change, and generates expansion pressure, and the remaining moisture migrates to nearby pores and capillaries. During the process of water movement, expansion pressure and liquid pressure are generated, and finally It causes the concrete structure to expand, crack, erode and collapse, resulting in structural failure. Our country has a vast territory, and the phenomenon of concrete freeze-thaw damage is common in the northern region of our country, and the freeze-thaw damage of concrete engineering has caused huge losses to our national property and economy. In addition to being damaged by freeze-thaw cycles in c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/04C04B111/34
CPCC04B28/04C04B2111/343C04B2201/50C04B22/002C04B24/383C04B2103/0068C04B14/00
Inventor 王振军吴佳育白敏王佩仵江涛郭豪彦
Owner CHANGAN UNIV