The invention belongs to the technical field of
sodium ion batteries, and particularly relates to a preparation method of a high-entropy
sodium ion positive
electrode material coated with nanoscale oxides, which comprises the following steps: (1) mixing a
metal salt solution, a precipitator solution and a complexing agent solution, controlling the pH value of the reaction solution to be 9-11.5, and carrying out
coprecipitation reaction to obtain a precursor solution; (2) aging, filtering, washing,
drying and demagnetizing the precursor solution to obtain precursor
powder; and (3) uniformly mixing the precursor
powder with
sodium salt and doped salt, calcining, taking out the
molten material in the cooling process, directly
quenching, and cooling to obtain the high-entropy O3 type positive
electrode material, and (4) mixing the high-entropy O3 type positive
electrode material with a nanoscale
oxide, and calcining to obtain the nanoscale
oxide coated high-entropy O3 type positive
electrode material. The invention also provides application of the sodium
ion positive
electrode material. The sodium ion positive
electrode material prepared by the method disclosed by the invention is high in stability and good in circularity in air.