A kind of linear thermosensitive polyurethane and preparation method thereof
A technology of temperature-sensitive polyurethane, which is applied in the field of linear temperature-sensitive polyurethane and its preparation, can solve the problems of complex synthesis method and high production cost, and achieve the effect of simple synthesis method, cost saving and good temperature-sensitive effect
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Embodiment 1
[0022] A kind of linear thermosensitive polyurethane, its preparation method is as follows:
[0023] In a 250mL four-neck flask, add 0.007mol (7g) of polycarbonate diol (PCDL-1000, indicating that the molecular weight is 1000), remove water under vacuum at 130°C for 2 hours at a vacuum of 0.095MPa, add 0.003mol (0.4024 g) Dimethylolpropionic acid (DMPA), 10 mL N-methylpyrrolidone (NMP) and 50 mL acetone. Then raise the temperature to 80°C and under nitrogen protection, add 0.012mol (2.0183g) hexamethylene diisocyanate (HDI), and add the catalyst dibutyltin dilaurate (DBTDL) of 0.0008mol (0.5g), this Under the same conditions, react for 3 hours, then add 0.004mol (0.2405g) of ethylenediamine monomer and 0.0049mol (0.50g) of triethylamine in sequence, and react for 2 hours without changing the reaction conditions to obtain a line with an amino group as the terminal group. Type polyurethane, then add 0.004mol (0.4526g) N-isopropylacrylamide, under the condition of constant react...
Embodiment 2
[0025] A kind of linear thermosensitive polyurethane, its preparation method is as follows:
[0026] In a 250mL four-neck flask, add 0.0063mol (12.6g) of polycarbonate diol (PCDL-2000), at 130°C, vacuum 0.095MPa to remove water for 2 hours, add 0.003mol (0.4024g) of diol Methylpropionic acid (DMPA), 10 mL N-methylpyrrolidone (NMP), and 40 mL acetone. Then raise the temperature to 85°C and under nitrogen protection, add 0.015mol (2.5229g) hexamethylene diisocyanate (HDI), and add the catalyst dibutyltin dilaurate (DBTDL) of 0.0005mol (0.3g), this Under the same conditions, react for 3 hours, then add 0.0042mol (0.2525g) of ethylenediamine monomer and 0.0045mol (0.46g) of triethylamine in sequence, and react for 2 hours without changing the reaction conditions to obtain a line with an amino group as the terminal group. Type polyurethane, then add 0.0042mol (0.4752g) N-isopropylacrylamide, under the condition of constant reaction conditions, react for 12h, finally add 180mL deio...
Embodiment 3
[0028] A kind of linear thermosensitive polyurethane, its preparation method is as follows:
[0029] In a 250mL four-neck flask, add 0.0075mol (3.75g) of polycarbonate diol (PCDL-500), at 130°C, vacuum 0.095MPa to remove water for 2h, add 0.003mol (0.4024g) of diol Methylpropionic acid (DMPA), 10 mL N-methylpyrrolidone (NMP), and 30 mL acetone. Then raise the temperature to 75°C and under nitrogen protection, add 0.012mol (2.0183g) hexamethylene diisocyanate (HDI), and add the catalyst dibutyltin dilaurate (DBTDL) of 0.0005mol (0.3g), this Under the condition of reaction for 3 hours, then add 0.0039mol (0.2345g) of ethylenediamine monomer and 0.0051mol (0.52g) of triethylamine in sequence. Under the condition that the reaction conditions do not change, react for 2 hours to obtain a line with an amino group as the terminal group. Type polyurethane, then add 0.0039mol (0.4413g) N-isopropylacrylamide, under the same reaction conditions, react for 12h, finally add 150mL deionized...
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