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A slow-release long-lasting super-hydrophobic anti-fouling flashover coating

An anti-pollution flashover coating and super-hydrophobic technology, applied in the coating field, can solve the problems of low elongation, breaking strength and tear strength, easy aging service life, weak coating adhesion, etc., and achieve salt spray aging resistance. Good, excellent stain resistance, and the effect of enhancing self-cleaning ability

Active Publication Date: 2019-05-07
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, although the introduction of RTV coatings has alleviated the increasingly serious pollution flashover problem in power systems, the performance of current RTV coatings is still low. First, the coatings have weak adhesion, poor wear resistance, and poor corrosion resistance. Due to poor adhesion, In the process of maintenance, the coating is easy to detach due to the action of external force; secondly, due to the problem of its own structure and composition, its own mechanical properties, such as elongation, breaking strength and tear strength are all low, and it is easy to be damaged during actual use. Peeling, cracking, and falling off occur; thirdly, the surface of the current RTV paint is easy to absorb and accumulate dust. When the loose dirt reaches a certain thickness, the inside of the dirt is easy to form water flow channels and large-area stagnation areas, and finally forms flashover channel, leading to the occurrence of pollution flashover events; in addition, because RTV coatings not only have to withstand the effects of electric field and wind force, but also bear the erosion of temperature changes, rain, snow, frost and sunlight, the performance of RTV coatings gradually decreases with time. Small, easy to age and short service life, requires regular maintenance or even re-spraying, which brings great limitations to its use

Method used

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  • A slow-release long-lasting super-hydrophobic anti-fouling flashover coating
  • A slow-release long-lasting super-hydrophobic anti-fouling flashover coating

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preparation example Construction

[0048] The preparation method of slow-release type long-acting super-hydrophobic antifouling flashover coating of the present invention, comprises the following steps:

[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and methylcyclosiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add dropwise Concentrated hydrochloric acid with a concentration of 37%, react for 1-2 hours after the dropwise addition, cool to 20-30°C, add ammonia water, adjust the pH to 6-7, and obtain hydrogen-terminated fluorine-containing polysiloxane; among them, trifluoropropyl The mass ratio of methylcyclotrisiloxane, tetramethyldisiloxane, methylcyclosiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~1:0.2~0.5;

[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 hours to obtain hydroxypropyl-...

Embodiment 1

[0057] A slow-release long-acting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluoropolysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, and hydrophobic gas-phase white 20kg of carbon black, 3kg of nano-zinc oxide, 2kg of oleyl amino oleate, 4kg of mica powder, 1kg of ketoxime type crosslinking agent, 5kg of dimethylaminopropylamine, 1kg of silane coupling agent, 3kg of aluminum hydroxide and 165kg of organic solvent;

[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of methylcyclosiloxane evenly, add 12.5kg of sodium sulfate, heat up to 60°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 1 hour after the dropwise...

Embodiment 2

[0064] A slow-release long-acting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45kg of hydroxypropyl-terminated fluoropolysiloxane, 30kg of hydrogen-terminated polysiloxane, 65kg of 107 silicone rubber, and hydrophobic gas-phase white 30kg of carbon black, 5kg of nano zinc oxide, 4kg of oleyl amino oleate, 6kg of mica powder, 3kg of ketoxime type crosslinking agent, 10kg of dimethylaminopropylamine, 2kg of silane coupling agent, 6kg of aluminum hydroxide and 175kg of organic solvent;

[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of methylcyclosiloxane evenly, add 10kg of sodium sulfate, heat up to 70°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 2 hours after the dropwise ...

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Abstract

The invention discloses a slow-release type long-acting super-hydrophobic pollution flashover prevention coating. The coating is prepared from the following raw materials in parts by weight: 35-45 parts of terminal hydroxypropyl fluorine-containing polysiloxane, 20-30 parts of terminal hydrogen polysiloxane, 55-65 parts of 107 silicon rubber, 20-30 parts of hydrophobic fumed silica, 3-5 parts of nano zinc oxide, 2-4 parts of oil amino oleate, 4-6 parts of mica powder, 1-3 parts of ketoxime type crosslinking agents, 5-10 parts of dimethyl aminopropyl amine, 1-2 parts of silane coupling agents, 3-6 parts of aluminum hydroxide and 165-175 parts of organic solvents. The slow-release type long-acting super-hydrophobic pollution flashover prevention coating is high in mechanical performance, long in service life which can reach 15 years, high in flame retardancy which can reach FV-0 grade, high in salt fog resistance, high in aging resistance and excellent in stain resistance, and still can exert the effectiveness in weather with haze pollution; the expectant pollution flashover prevention effect can be achieved; the occurrence of pollution flashover accidents is avoided.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a slow-release long-acting super-hydrophobic antifouling flashover coating. Background technique [0002] Pollution flashover accidents involve a wide range of areas, and the power outage lasts for a long time, which seriously threatens the operation safety of power transmission and transformation equipment. Especially in winter, there are thousands of pollution flashover trips in the national power grid, sometimes almost causing the provincial power grid to be disconnected. The anti-fouling flashover measures are nothing more than four main measures: taking measures to adjust creepage, cleaning insulators, using synthetic insulators, and coating RTV paint (room temperature vulcanized silicone rubber). Comprehensive investigation and comparison of the above anti-fouling flashover measures, it can be seen that coating RTV paint is the most economical and effective measure. Espec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/06C09D183/08C09D183/05C09D5/16C09D5/18C09D7/61C08G77/38C08G77/12
CPCC08G77/12C08G77/38C08K2201/011C08L2201/02C08L2201/08C08L2205/02C08L2205/03C09D5/1675C09D5/18C09D7/61C09D7/62C09D7/63C09D183/06C08L83/08C08L83/04C08K13/06C08K9/04C08K3/34C08K2003/2227C08K3/36C08K2003/2296
Inventor 冯迎春杜远王洪川乔耀华韩正新孟海磊袁森冯海清卢志鹏黄锐孙兆国
Owner STATE GRID CORP OF CHINA
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