The invention relates to a heatproof antifouling superhigh voltage insulation material and a preparation method thereof. The material contains the components, by weight, 100 portions of low density polyethylene, 15-20 portions of fluorine silicon resin, 20-30 portions of polytetrafluoroethylene, 5-15 portions of a room temperature vulcanized silicone rubber, 1-5 portions of nano montmorillonite, 0.1-1 portion of sodium dodecyl sulfate, 10-30 portions of distilled water, 5-15 portions of a mixture of nano boron nitride, nano magnesium oxide and nano zinc oxide, 0.8-6 portions of a compatible agent, 1-5 portions of a flame retardant, 0.5-2.5 portions of an antioxidant, and 0.5-5 portions of a crosslinking agent. The heatproof antifouling superhigh voltage insulation material prepared by the invention can effectively restrain space charge accumulation in the cable insulation material, and has the advantages of good mechanical, electrical, thermal and physical properties.