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Titanate coupling agent modified pollution-flashover-preventing fluorocarbon paint and preparation method thereof

A technology of titanate coupling agent and fluorocarbon coating, applied in the direction of coating, etc., to achieve the effect of high anti-pollution flashover performance, good hot water performance and excellent weather resistance

Inactive Publication Date: 2013-08-14
ELECTRIC POWER RES INST OF GUANGDONG POWER GRID +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing fluorocarbon coatings need to be applied to anti-fouling flashover, and the mechanical properties and electrical insulation properties need to be strengthened.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Example 1 Antifouling flash fluorocarbon coating

[0039] GK 570 (FEVE resin) 60 kg

[0040] HDI trimer N3390 (curing agent) 7 kg

[0041] Titanate coupling agent TM JTBT 5 kg

[0042] Modified rutile TiO 2 (Pigment) 3.6 kg

[0043] Vapor SiO 2 (filler) 6 kg

[0044] Nanoscale PTFE wax powder (filler) 18 kg

[0045] Polyether modified silicone defoamer (auxiliary) 0.3 kg

[0046] Surfactant FC-4430 (auxiliary) 0.3 kg

[0047] Silicone modified polysiloxane emulsion (auxiliary) 3 kg

[0048] Butyl acetate:MIBK=2:1 (solvent) 63 kg

[0049] Dibutyltin dilaurate (drying agent) 0.06 kg

[0050] The preparation method of the coating of embodiment 1 is:

[0051] (1) Stir 60 kg of FEVE resin, part of butyl acetate and methyl isobutyl ketone as a mixed solvent, and add 6 kg of gas-phase SiO 2 , stirred until the silica was dissolved in the solution, and ground in a basket mill for 90 min;

[0052] (2) Add 18 kg of nano-sized polytetrafluoroethylene wax powder to ...

Embodiment 2

[0056] Example 2 Antifouling flash fluorocarbon coating

[0057] GK 570 (FEVE resin) 100 kg

[0058] HDI biuret (curing agent) 12 kg

[0059] Titanate coupling agent TM JTBT 10 kg

[0060] Modified rutile TiO 2 (pigment) 7 kg

[0061] Vapor SiO 2 (filler) 8 kg

[0062] Nanoscale polytetrafluoroethylene wax powder (filler) 30 kg

[0063] Nano aluminum hydroxide particles 6 kg

[0064] Fluorosilicone modified defoamer (auxiliary) 1.0 kg

[0065] Surfactant FC-4430 (auxiliary) 2.4 kg

[0066] Silica fume 2.5 kg

[0067] Butyl acetate: MIBK=1.5:1 (solvent) 110kg

[0068] Dibutyltin dilaurate (drying agent) 0.08 kg

[0069] The preparation method of the coating of embodiment 2 is:

[0070] (1) Mix 100 kg of FEVE resin, part of butyl acetate and methyl isobutyl ketone as a solvent, and stir evenly;

[0071] (2) 8kg gas phase SiO 2 , 30 kg of nano-sized polytetrafluoroethylene wax powder and 6 kg of aluminum hydroxide particles were put into the high mixer, preheate...

Embodiment 3

[0075] Example 3 Antifouling flash fluorocarbon resin coating

[0076] GK 570 (FEVE resin) 50 kg

[0077] HDI biuret (curing agent) 6 kg

[0078] Titanate coupling agent TM JTPT 8 kg

[0079] Inorganic composite pigment cadmium red 10 kg

[0080] Vapor SiO 2 (filler) 5 kg

[0081] Nanoscale PTFE wax powder (filler) 15 kg

[0082] Fluorosilicone modified defoamer (auxiliary) 0.5 kg

[0083] Surfactant FC-4430 (auxiliary) 0.3 kg

[0084] Silicone modified polysiloxane emulsion (auxiliary) 0.2 kg

[0085] Butyl acetate: MIBK=1.5:1 (solvent) 35kg

[0086] Dibutyltin dilaurate (drying agent) 0.01 kg

[0087] The preparation method of the coating of embodiment 3 is:

[0088] (1) Put 5kg gas phase SiO 2 15kg of nano-sized polytetrafluoroethylene wax powder and 8kg of titanate coupling agent TM JTPT are mixed together with part of the mixed solvent, stirred evenly, and ultrasonically dispersed for 1 hour;

[0089] (2) Add 50kg of resin and the remaining solvent to step (...

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PUM

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Abstract

The invention discloses titanate coupling agent modified pollution-flashover-preventing fluorocarbon paint which comprises the following components in parts by weight: 30-50 parts of fluorocarbon resin, 10-30 parts of filler, 1-10 parts of pigment, 3.5-10 parts of curing agent, 2-10 parts of coupling agent, 0.03-3 parts of assistant, 35-45 parts of solvent and 0.001-0.1 part of drying agent. The invention also discloses a preparation method of the fluorocarbon resin paint. The static contact angle theta of the fluorocarbon resin paint can be up to 118 degrees; and the fluorocarbon resin paint has favorable hydrophobicity and hydrophobic migration performance and high pollution flashover preventing performance, thus ensuring that the physical / chemical properties and electric properties of a prepared coating can meet pollution flashover preventing conditions. The invention is used for insulator pollution flashover prevention, and solves the problem of insulator pollution flashover of a high-voltage transmission line.

Description

technical field [0001] The invention relates to an antifouling flashover fluorocarbon coating, in particular to an antifouling flashover fluorocarbon coating modified by a titanate coupling agent. The invention also relates to a preparation method of the antifouling flash fluorocarbon coating. Background technique [0002] Anti-pollution flashover coating is an important means to prevent pollution flashover of external insulation of power equipment. In recent years, with the increase of industrial emissions and the aggravation of environmental pollution, pollution flashover of power transmission and transformation equipment has become more and more frequent. After the creepage distance of transmission line insulator strings has been generally adjusted, the problem of anti-pollution flashover of substation equipment has become more prominent. The use of anti-pollution flashover coatings in substations has also increased day by day, and has become an important means of anti-p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D127/12C09D7/12C09D7/14C09D5/25C09D7/80
Inventor 李丽朱志平周永言周艺黎晓淀黄静唐念
Owner ELECTRIC POWER RES INST OF GUANGDONG POWER GRID
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