Processing technology of a slow-release long-lasting super-hydrophobic antifouling flashover coating

An anti-pollution flashover coating and processing technology, applied in the coating and other directions, can solve the problems of low elongation, breaking strength and tear strength, easy aging service life, poor corrosion resistance, etc., and achieve salt spray aging resistance. Good performance, excellent stain resistance, and the effect of improving mechanical properties

Active Publication Date: 2019-05-07
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, although the introduction of RTV coatings has alleviated the increasingly serious pollution flashover problem in power systems, the performance of current RTV coatings is still low. First, the coatings have weak adhesion, poor wear resistance, and poor corrosion resistance. Due to poor adhesion, In the process of maintenance, the coating is easy to detach due to the action of external force; secondly, due to the problem of its own structure and composition, its own mechanical properties, such as elongation, breaking strength and tear strength are all low, and it is easy to be damaged during actual use. Peeling, cracking, and falling off occur; thirdly, the surface of the current RTV paint is easy to absorb and accumulate dust. When the loose dirt reaches a certain thickness, the inside of the dirt is easy to form water flow channels and large-area stagnation areas, and finally forms flashover channel, leading to the occurrence of pollution flashover events; in addition, because RTV coatings not only have to withstand the effects of electric field and wind force, but also bear the erosion of temperature changes, rain, snow, frost and sunlight, the performance of RTV coatings gradually decreases with time. Small, easy to age and short service life, requires regular maintenance or even re-spraying, which brings great limitations to its use
[0004] The preparation process of the current RTV coating is complicated, and the resulting coating has the above-mentioned problems. Therefore, a new type of anti-fouling flashover coating with high performance, slow release and long life has been developed in a targeted manner. The anti-pollution work of power grid lines has important practical significance, which can save a lot of construction funds and operation and maintenance costs, and create better social and economic benefits

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] A processing technology of slow-release long-acting super-hydrophobic antifouling flashover coating, comprising the following steps:

[0053] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of methylcyclosiloxane evenly, add 12.5kg of sodium sulfate, heat up to 60°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 1 hour after the dropwise addition, cool to 20°C, add ammonia water, adjust the pH to 6, and obtain hydrogen-terminated fluoropolysiloxane;

[0054] ②Take 80kg of hydrogen-terminated fluoropolysiloxane obtained in step ① and 10kg of methallyl alcohol, stir evenly, add 0.2kg of metal nickel, raise the temperature to 80°C, and react for 1 hour to obtain hydroxypropyl-terminated fluoropolysiloxane Oxygen;

[0055] ③Raise the temperature to 40kg of octamethylcyclotetrasiloxane to 50°C, add 0.1kg of concentrated sulfuric acid and stir evenly, ...

Embodiment 2

[0060] A processing technology of slow-release long-acting super-hydrophobic antifouling flashover coating, comprising the following steps:

[0061] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of methylcyclosiloxane evenly, add 10kg of sodium sulfate, heat up to 70°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 2 hours after the dropwise addition, cool to 30°C, add ammonia water, adjust the pH to 7, and obtain hydrogen-terminated fluoropolysiloxane;

[0062] ②Take 45kg of hydrogen-terminated fluoropolysiloxane and 7.5kg of methallyl alcohol obtained in step ①, stir evenly, add 0.25kg of metal nickel, heat up to 90°C, and react for 2 hours to obtain hydroxypropyl-terminated fluoropolysiloxane Silicone;

[0063] ③Raise the temperature to 42.5kg octamethylcyclotetrasiloxane to 60°C, add 0.25kg concentrated sulfuric acid to it and stir evenly, then add...

Embodiment 3

[0068] A processing technology of slow-release long-acting super-hydrophobic antifouling flashover coating, comprising the following steps:

[0069] ①Stir 45kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 120kg of methylcyclosiloxane evenly, add 8kg of sodium sulfate, heat up to 62°C after stirring evenly, and then add Add 3kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 1.5 hours after the dropwise addition, cool to 22°C, add ammonia water, adjust the pH to 6.5, and obtain hydrogen-terminated fluoropolysiloxane;

[0070] ②Take 41kg of hydrogen-terminated fluoropolysiloxane obtained in step ① and 7kg of methallyl alcohol, stir evenly, add 0.15kg of metal nickel, heat up to 84°C, and react for 1.5 hours to obtain hydroxypropyl-terminated fluoropolysiloxane Oxygen;

[0071] ③Raise the temperature to 41kg of octamethylcyclotetrasiloxane to 52°C, add 0.15kg of concentrated sulfuric acid to it and stir evenly, the...

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PUM

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Abstract

The invention discloses a processing technology of a slow-release long-acting super hydrophobic anti-pollution flashover coating. The processing technology comprises the following steps: first, preparing hydroxypropyl-terminated fluorinated polysiloxane, hydroxyl-terminated polysiloxane and hydrophobic fumed silica; second, adding the hydroxypropyl-terminated fluorinated polysiloxane and hydroxyl-terminated polysiloxane together with 107 silicone rubber, nano zinc oxide, oil amino oleate, mica powder and aluminum hydroxide into a mixer, stirring uniformly, and grinding for 3-4 times on a three-roller machine to obtain a uniform sizing material; third, adding the uniform sizing material into a kneading machine, adding the hydrophobic fumed silica, heating to 145-150 DEG C, kneading for 1-2 hours and cooling to 20-30 DEG C; and after that, adding a ketoxime crosslinking agent, dimethylamino propylamine, a silane coupling agent and an organic solvent, and stirring uniformly to obtain slow-release long-acting super hydrophobic anti-pollution flashover coating. In the coating prepared by the preparation method disclosed by the invention, the aims of slow release and pollution prevention can be achieved through the combination of the hydroxypropyl-terminated fluorinated polysiloxane and hydroxyl-terminated polysiloxane, and the hydrophobicity transfer of the coating can be remarkably improved.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a processing technology of slow-release long-acting super-hydrophobic antifouling flashover coatings. Background technique [0002] Pollution flashover accidents involve a wide range of areas, and the power outage lasts for a long time, which seriously threatens the operation safety of power transmission and transformation equipment. Especially in winter, there are thousands of pollution flashover trips in the national power grid, sometimes almost causing the provincial power grid to be disconnected. The anti-fouling flashover measures are nothing more than four main measures: taking measures to adjust creepage, cleaning insulators, using synthetic insulators, and coating RTV paint (room temperature vulcanized silicone rubber). Comprehensive investigation and comparison of the above anti-fouling flashover measures, it can be seen that coating RTV paint is the most economical and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/06C09D183/08C09D183/05C09D7/61C09D7/62C09D7/65C08G77/385C08G77/12
CPCC08G77/12C08G77/385C08K2201/011C08L2205/02C08L2205/03C09D7/61C09D7/62C09D7/65C09D183/06C08L83/08C08L83/04C08K13/06C08K9/04C08K3/36C08K2003/2296C08K3/34C08K2003/2227
Inventor 冯海清冯迎春袁森王震杨靖波卢志鹏黄锐孙兆国惠杰白临李守金
Owner STATE GRID CORP OF CHINA
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