Method for recovering arsenic from black copper sludge
A black copper slime and arsenic recovery technology, which is applied in the treatment of black copper slime and the cleaning treatment of arsenic-containing black copper slime, can solve the problems of potential safety hazards, arsenic dispersion, high cost, etc., and achieve the goal of reducing production costs and avoiding arsenic The effect of accumulation, efficient separation and extraction
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[0026] Example 1
[0027] Take 100kg of black copper mud (specific components are Cu: 30.07%, As: 28.17%, Sb: 2.56%, Bi: 1.49%; the phase of black copper mud is mainly Cu 2 As and Cu 3 As) Carry out alkaline pressure oxidation leaching. The leaching process is controlled by sodium hydroxide 1.5mol / L, oxygen pressure 1.0MPa, temperature 120℃, liquid-solid ratio 5:1, reaction time 1.5h, stirring speed 500rpm, after the reaction is over, Liquid-solid separation is carried out while it is hot, and the leaching residue is a copper-enriched slag, the leaching rate of arsenic is 98.78%, and the copper is not leached. Add an appropriate amount of lime (Ca / As molar ratio = 1.5) to the leaching solution, and carry out causticizing at a temperature of 80°C, a time of 1 h and a stirring speed of 300 rpm. After the causticizing is completed, liquid-solid separation is carried out while hot, and the solid phase is arsenic acid Calcium and lye are returned to the pressurized oxidation leaching ...
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[0028] Example 2
[0029] Take 100kg of black copper mud (specific components are Cu: 30.07%, As: 28.17%, Sb: 2.56%, Bi: 1.49%; the phase of black copper mud is mainly Cu 2 As and Cu 3 As) Carry out atmospheric alkaline oxidation leaching, add appropriate amount of hydrogen peroxide in the leaching process, control sodium hydroxide 2mol / L, temperature 80℃, liquid-solid ratio 7:1, reaction time 2h, stirring speed 400rpm, after the reaction, proceed while hot Liquid-solid separation, the leaching residue is a copper-enriched slag, the leaching rate of arsenic is 94.15%, and the copper is not leached. Add an appropriate amount of lime (Ca / As molar ratio = 1.5) to the leaching solution, and carry out causticizing at a temperature of 80°C, a time of 1 h and a stirring speed of 300 rpm. After the causticizing is completed, liquid-solid separation is carried out while hot, and the solid phase is arsenic acid Calcium and lye are returned to the pressurized oxidation leaching process, and...
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