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A method for stabilizing protease in laundry detergent

A technology of protease and laundry detergent, which is applied in the field of stable protease, can solve the problems of reducing enzyme activity and taking half an hour to release, and achieves the effect of high embedding rate, improved stability and good stability

Active Publication Date: 2020-07-03
JIANGNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These methods can make the protease have certain stability in the laundry liquid, but it is still not ideal: for example, the protease immobilized on the surface of the carrier is still inferior to the surfactant in the aqueous solution in the concentrated solution, and can only be used for adding enzymes. In laundry detergent; in addition, embedded or surface-immobilized protease systems such as alginate usually reduce the enzyme activity and take half an hour to release half of the enzyme activity, which is far longer than the usual household washing time

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] To prepare vesicles embedded with alkaline protease 2709 (909.1 mg protein / g, Xingtai Spectrum Biotechnology Co., Ltd.), the specific steps are as follows:

[0044] 1) Dissolve 5.76g of conjugated linoleic acid in 100mL of sodium dihydrogen phosphate-disodium hydrogen phosphate buffer solution (pH 8.6, 0.01mol / L) containing 0.25mmol / L calcium citrate at room temperature, conjugated linoleic acid The acid concentration is 200mmol·L -1 After mixing uniformly, add alkaline protease 2709 solution, the addition of protease is 500mg albumen / g conjugated linoleic acid (550mg protease preparation / g conjugated linoleic acid), after mixing uniformly, in 25 0 Under C, use a shaker to avoid light and oscillate for 4 hours (the shaker speed is 50rpm) to obtain a solution for embedding protease-conjugated linoleic acid vesicles, and the embedding rate is 91.2%;

[0045] 2) Put 100mL of the above solution in a 250mL stoppered cylindrical glass reactor (height-to-diameter ratio: 2:1) ...

Embodiment 2

[0052] Preparation of vesicles embedded with S. marcescens alkaline protease (930.2mg protein / g, from S. marcescens), the specific steps are as follows:

[0053] 1) Dissolve conjugated linoleic acid and calcium citrate in 0.01mol / L borax buffer (pH9.18) at room temperature and mix well. The concentration of conjugated linoleic acid is 240mmol / L, and the concentration of calcium salt is 0.15mmol / L; add viscose Saybolt alkaline protease, the amount of protease added is 560mg protein / g conjugated linoleic acid, after mixing evenly, shake it with a shaking table at 20°C for 7h, the shaking speed of the shaking table is 40rpm, Self-assembled to obtain a vesicle solution embedding protease-conjugated linoleic acid, with an embedding rate of 92.3%;

[0054] (2) Put the self-assembled protease-conjugated linoleic acid vesicle solution obtained in step (1) in the reactor, and add QTX in an amount of 0.06% of the mass of the conjugated linoleic acid in the dark, and add it to the reacto...

Embodiment 3

[0058] To prepare vesicles embedded with dispase 1398 (905.7 mg protein / g, Xingtai Spect Biotechnology Co., Ltd.), the specific steps are as follows:

[0059] (1) Dissolve conjugated linoleic acid and calcium citrate tetrahydrate in 0.01mol / L pH 8 disodium hydrogen phosphate-citric acid buffer at room temperature, the concentration of conjugated linoleic acid is 300 mmol / L, The concentration of calcium salt is 0.25 mmol / L; add neutral protease 1398 solution, the amount of protease added is 580 mg protein / g conjugated linoleic acid, mix well and shake with a shaking table at 25 °C for 5 hours, the shaking table The speed was 50 rpm, and the vesicle solution embedding protease-conjugated linoleic acid was obtained by self-assembly, and the embedding rate was 94.5%;

[0060] (2) Put the self-assembled protease-conjugated linoleic acid vesicle solution obtained in step (1) in the reactor, and add QTX in an amount of 0.08% of the mass of the conjugated linoleic acid in the dark, an...

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Abstract

The invention provides a method for immobilizing protease in a laundry detergent, and belongs to the technical field of daily chemicals. The method comprises the following steps: firstly, self-assembling conjugated linoleic acid and protease of certain pH values and relatively low calcium ion concentration into vesicae for wrapping the protease, and performing partial cross-linking on the conjugated linoleic acid on the surfaces of the vesicae. Therefore, a protease vesicae can be directly used in a laundry detergent formula after being concentrated, can resist enzyme activity of surfactants in the laundry detergent, can maintain enzyme activity in a detergent, and can be disintegrated in an environment of relatively high calcium ion concentration such as washing water to release the protease. The method provided by the invention is applicable to both neutral and alkali protease, and obtained protease vesicae wrapped bodies are also high in stability in laundry detergents; the conjugated linoleic acid self is also a surfactant with a decontamination function, is good in compatibility with surfactants in laundry detergents, and is relatively good in wrapping and release effect compared with those of macromolecule polysaccharide wall materials such as pectin and sodium alginate.

Description

technical field [0001] The invention belongs to the technical field of daily chemicals, and in particular relates to a method for stabilizing protease in laundry detergent. Background technique [0002] Laundry liquid is rich in anionic surfactants, amphoteric surfactants and nonionic surfactants, among which anionic surfactants are the main decontamination ingredients. In order to improve the washing performance of laundry detergent, especially in order to effectively remove protein-containing stains such as blood stains, it is necessary to add protease to the laundry detergent formulation. However, protease is easily affected by the external environment such as light, heat and pH, especially in the environment of a large amount of water and a large amount of surfactant in the anionic surfactant aqueous solution in the laundry detergent, and cannot be as relatively strong as in the washing powder. It exists relatively stably in the embedding body, but it is easy to react w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C12N9/96C12N9/50
CPCC12N9/50C12N9/96
Inventor 方云夏咏梅魏贝闫引星
Owner JIANGNAN UNIV