The invention provides a crosslinked
polyethylene composition without pits on a
rotational molding surface and a preparation method of the crosslinked
polyethylene composition, and belongs to the technical field of
high polymer materials. The crosslinked
polyethylene composition without pits on the
rotational molding surface is prepared from the following components in parts by weight: 100 parts of polyethylene resin, 0.1 to 2 parts of high-temperature
organic peroxide, 0.5 to 3 parts of crosslinking aid, 0.05 to 0.5 part of
nitroso ether and 0.1 to 1 part of
antioxidant. The
nitroso ether compound is introduced, high-activity nitroxide free radicals generated by the
nitroso ether compound at a high temperature are used for
quenching primary free radicals generated by
decomposition of
peroxide, generation of low-boiling-point byproducts is inhibited, and a rolling part product without pits in the surface of a rolling part can be obtained under the
rotational molding condition of high temperature or rapid temperature rise.