dispersed lactam
A technology of lactam and solid dispersion, which is applied in the field of lactam and can solve problems such as solubility limitations
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[0066] The lactams - 4-(4-bromophenyl)-5-hydroxy-5-methyl-1H-pyrrol-2-one and 4-(4-chlorophenyl)-5-methylene were prepared according to - Pyrrol-2-one - solid dispersion in PEG (1.5k, 10k or 20k molecular weight) or polyvinylpyrrolidone (PVP, 40k molecular weight):
[0067] Lactam and polymer (PVP or PEG) were combined in the desired ratio, suspended in acetonitrile and heated to cause dissolution. Thereafter, the solution was cooled to room temperature, and the solvent was removed in vacuo to provide the desired solid dispersion. The material was dried under vacuum for an extended period of time to ensure removal of all residual solvent, and ground to provide a fine powder.
[0068] The inventors have shown that a solid dispersion of a lactam in PVP confers enhanced water solubility to the lactam. As can be seen from the photographs below, both PVP alone and a solid dispersion of 1% lactam in PVP dissolved rapidly in water to provide a clear solution. Lactam in an amount e...
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