Phosphorus nitrogen hybridization synergistic intumescent flame retardant and preparation method thereof
An intumescent flame retardant and hybridization technology, which is applied in the field of phosphorus nitrogen hybridized synergistic intumescent flame retardant and its preparation, can solve the problems of damage to the mechanical properties of the matrix polymer and the difficulty of good dispersion of graphene oxide, etc. Large-scale preparation, remarkable combustion effect, and improved combustion effect
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[0024] Example 1
[0025] A synergistic expansion flame retardant, according to mass percentage, includes the following components:
[0026] Cyanuric chloride 12.2%
[0027] Bisphenol A 30.4%
[0028] Diisopropylethylamine 19.4%
[0029] Melamine orthophosphate 16%
[0030] Graphene oxide 22%
[0031] Among them, the diameter of graphene oxide is 0.1 µm, the number of layers is 5, and the thickness is 2 nm.
[0032] A method for preparing the above-mentioned phosphazepine synergistic intumescent flame retardant includes the following steps:
[0033] (1) In the reactor, add cyanuric chloride, bisphenol A and melamine orthophosphate into tetrahydrofuran according to the ratio, stir until completely dissolved, and pour the dispersed graphene oxide THF solution into the above reactor in;
[0034] (2) Add diisopropylethylamine THF solution while stirring, and react for 2.5 hours;
[0035] (3) Remove the solvent and wash with deionized water twice;
[0036] (4) After purification by silica gel colu...
Example Embodiment
[0039] Example 2
[0040] A synergistic intumescent flame retardant, in terms of mass percentage, includes the following components:
[0041] Cyanuric chloride 18.4%
[0042] Bisphenol S 34.3%
[0043] Diisopropylethylamine 20.4%
[0044] Melamine polyphosphate 11.2%
[0045] Graphene oxide 15.7%
[0046] Among them, the diameter of graphene oxide is 3µm, the number of layers is 3, and the thickness is 1.5nm.
[0047] A method for preparing the above-mentioned phosphazepine synergistic intumescent flame retardant includes the following steps:
[0048] (1) In the reactor, add cyanuric chloride, bisphenol S, and melamine polyphosphate into tetrahydrofuran according to the ratio, stir until completely dissolved, and pour the dispersed graphene oxide THF solution into the above reactor in;
[0049] (2) Add diisopropylethylamine THF solution while stirring, and react for 2 hours;
[0050] (3) Remove the solvent and wash with deionized water 3 times;
[0051] (4) After purification by silica gel co...
Example Embodiment
[0054] Example 3
[0055] A synergistic intumescent flame retardant, in terms of mass percentage, includes the following components:
[0056] Cyanuric chloride 12%
[0057] Bisphenol S 15%
[0058] Bisphenolic acid 20%
[0059] Diisopropylethylamine 18%
[0060] Melamine cyanurate 10.5%
[0061] Dimelamine phosphate 8.0%
[0062] Graphene oxide 16.5%
[0063] Among them, the diameter of graphene oxide is 5µm, the number of layers is one, and the thickness is 1nm.
[0064] A method for preparing the above-mentioned phosphazepine synergistic intumescent flame retardant includes the following steps:
[0065] (1) In the reactor, add melamine cyanurate, bisphenolic acid melamine cyanurate and dimelamine phosphate into tetrahydrofuran in accordance with the proportions in the reactor, stir until completely dissolved, and disperse the prepared Pour the graphene oxide THF solution into the above reactor;
[0066] (2) Add diisopropylethylamine THF solution while stirring, and react for 3 hours;
[0067...
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