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Preparation method of hydrophobic oleophobic BC superfine dry powder extinguishing agent base material carbonate

A hydrophobic and oleophobic, ultra-fine dry powder technology, which is used in the preparation of alkali metal carbonate shapes, fire protection equipment, etc. The effect of strong adhesion and excellent hydrophobic and oleophobic properties

Active Publication Date: 2018-07-24
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology uses an alkoxysilylated compound called Flourosilane (FSI) or Silanesulfonamide for better wetting properties onto nanoparticles such as calcium oxaluminate particles. These modifications improve their ability to bind tightly together during use without losing effectiveness over time due to weak interactions like Van der Waals forces. Additionally, this modification makes these materials more stable against decomposition caused by heat exposure compared to previous methods. Overall, this new method provides improved performance and safety benefits while maintaining superior physical/chemical properties of traditional flame retardants.

Problems solved by technology

Technological Problem: Current methods use expensive chemicals such as chlorofluoro compounds or peroxybromides (PFO) to create fire extinction gases like CFB, while producing nonionic liquid fire exchanging particles called CEAHZ™ by adding certain types of molecules onto their surfaces. However, existing techniques either require long periods before they start working properly, may result in loss of effective properties during storage over time, or produce unwanted side effects when exposed to humid environments.

Method used

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  • Preparation method of hydrophobic oleophobic BC superfine dry powder extinguishing agent base material carbonate
  • Preparation method of hydrophobic oleophobic BC superfine dry powder extinguishing agent base material carbonate
  • Preparation method of hydrophobic oleophobic BC superfine dry powder extinguishing agent base material carbonate

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Experimental program
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Effect test

Embodiment 1

[0030] Embodiment 1: the preparation of hydrophobic and oleophobic superfine sodium bicarbonate powder

[0031] (1) Use a supersonic jet mill to crush sodium bicarbonate into an ultrafine powder with a particle size of 90% ≤ 5 μm;

[0032] (2) Add the ultrafine powder to the methanol solution of γ-aminopropyltriethoxysilane (KH550) at room temperature for impregnation treatment, stir at 1000rpm for 1h, and the weight percentage of each substance is the ultrafine powder The amount of methanol is 10%, the amount of methanol is 89%, and the amount of KH550 is 1%;

[0033] (3) Suction filter after the reaction, wash, dry at 100°C, cool, pulverize, and pass through a 400-mesh standard sampling sieve;

[0034] (4) Add the treated ultrafine powder into the acetone solution of tridecafluorooctyltriethoxysilane for impregnation treatment, stir at 1000rpm for 10h, and the weight percentage of each substance is the amount of ultrafine powder The amount of acetone is 10%, the amount of ...

Embodiment 2

[0040] Embodiment 2: the preparation of hydrophobic and oleophobic superfine potassium bicarbonate powder

[0041] (1) Use a supersonic jet mill to crush potassium bicarbonate into ultrafine powder with 90% particle size ≤ 5 μm;

[0042] (2) Add the ultrafine powder into the acetone solution of γ-glycidyl etheroxypropyltrimethoxysilane (KH560) at room temperature for impregnation treatment, stir at 1000rpm for 2h, and the weight percentage of each substance is ultrafine The amount of powder is 10%, the amount of acetone is 67%, and the amount of KH560 is 3%;

[0043] (3) After the reaction, filter with suction, wash, dry at 110°C, cool, pulverize, and pass through a 400-mesh standard sampling sieve;

[0044] (4) Add the treated ultrafine powder into the n-hexane solution of heptadecafluorodecyltrimethoxysilane for impregnation treatment, stir at 1000rpm for 12h, and the weight percentage of each substance is the amount of ultrafine powder The amount of n-hexane is 5%, the am...

Embodiment 3

[0050] Embodiment 3: the preparation of hydrophobic and oleophobic superfine sodium bicarbonate powder

[0051] (1) Use a supersonic jet mill to crush sodium bicarbonate into an ultrafine powder with a particle size of 90% ≤ 5 μm;

[0052] (2) Add the ultrafine powder into the n-hexane solution of γ-aminopropyltriethoxysilane (KH550) at room temperature for impregnation treatment, stir at 1000rpm for 2h, and the weight percentage of each substance is ultrafine powder The amount of solid is 30%, the amount of n-hexane is 67%, and the amount of KH550 is 3%.

[0053] (3) After the reaction, filter with suction, wash, dry at 115°C, cool, pulverize, and pass through a 400-mesh standard sampling sieve;

[0054] (4) Add the treated ultrafine powder to the ethanol solution of perfluorodecyltriethoxysilane for impregnation treatment, stir at 1000rpm for 12h, and the weight percentage of each substance is the amount of ultrafine powder: 1%, the amount of ethanol is 98.9%, and the amou...

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PUM

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Abstract

The invention discloses a preparation method of a hydrophobic oleophobic BC superfine dry powder extinguishing agent base material carbonate. The preparation method comprises the steps: (1) smashing carbonate into superfine powder with the 90% particle size smaller than or equal to 5mu m; (2) adding the superfine powder into a silane coupling agent organic solution under a normal temperature to perform dipping treatment; (3) after reaction finishes, performing suction filtering, washing, drying under a high temperature, cooling, smashing and sieving; (4) adding the treated dry superfine powderinto a fluorosilane organic solution to perform dipping treatment; (5) after reaction finishes, performing suction filtering, washing, drying under a high temperature, cooling, smashing and sieving to obtain hydrophobic oleophobic superfine carbonate powder. The superfine powder prepared by the invention not only has excellent hydrophobic oleophobic performance, but also has high stability; whenthe superfine powder is applied to preparing the superfine dry powder extinguishing agent, oil fire can be quickly extinguished; the superfine powder has the characteristics of high fire extinguishingeffectiveness and reburning resistance.

Description

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Claims

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Application Information

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Owner UNIV OF SCI & TECH OF CHINA
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