High-temperature-resistant salt-resistant water loss reducer and preparation method and application thereof

A fluid loss agent, high temperature resistant technology, applied in the field of oil and gas cementing, can solve the problems of accelerated hydrolysis of alkaline cement slurry, excessive retardation of cement slurry, and poor high temperature resistance, so as to protect oil and gas layers and reduce pores. The effect of size, strong adaptability

Inactive Publication Date: 2018-12-04
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyvinyl alcohol has poor high temperature resistance, and the general applicable temperature is below 95°C
The cellulose-based fluid loss reducer will thicken the cement slurry under the condition of meeting the control of fluid loss, resulting in difficulty in construction
However, under high temperature and high pressure conditions, the amide group in the molecule of the AMPS type fluid loss reducer will accelerate the hydrolysis in the alkaline cement slurry, increase the carboxyl group in the adsorption group in the molecular structure, and cause excessive retardation of the cement slurry The phenomenon
Under high temperature conditions, the hydrolysis of the AMPS type fluid loss reducer and the desorption of the groups will directly cause the water loss of the high temperature oil well cement slurry to exceed the standard requirements, and the high temperature resistance is poor.

Method used

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  • High-temperature-resistant salt-resistant water loss reducer and preparation method and application thereof
  • High-temperature-resistant salt-resistant water loss reducer and preparation method and application thereof
  • High-temperature-resistant salt-resistant water loss reducer and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Weigh 40 parts by weight of 2-acrylamido-2-methylpropanesulfonic acid (AMPS), 30 parts by weight of N,N'-dimethylacrylamide (DMAA), 1 part by weight of acrylic acid (AA), 1 part by weight Parts of 3-allyloxy-2-hydroxy-1-propanesulfonic acid (AHPS), 1 part by weight of acrylonitrile (AN), dissolved in 100 parts by weight of deionized water. The pH value was adjusted to 7 by adding a 40% sodium hydroxide solution. Add the solution into the reactor, put the reactor in a constant temperature water bath at 60°C for 1 to 1.5 hours; feed nitrogen into the reactor to remove oxygen, and when the temperature of the aqueous solution in the reactor reaches 60°C, add 0.1 parts by weight Potassium persulfate and 0.1 parts by weight of sodium bisulfite initiate the reaction, the reaction lasts for 3 hours, and naturally cool to room temperature to make a pentapolymer solution, which is the anti-high temperature and anti-salt fluid loss reducing agent of the present invention, code-nam...

Embodiment 2

[0034] Except that the difference from Example 1 is: the amount of 2-acrylamido-2-methylpropanesulfonic acid (AMPS) is changed to 80 parts by weight, and the amount of N,N-dimethylacrylamide (DMAA) Change to 70 parts by weight, change the consumption of acrylic acid (AA) into 20 parts by weight, change the consumption of 3-allyloxy-2-hydroxyl-1-propanesulfonic acid (AHPS) into 30 parts by weight, change the consumption of acrylonitrile The consumption of (AN) is changed into 20 parts by weight. Example 2 Compared with Example 1, other operating methods are the same, and an oil well cement fluid loss reducer (pentapolymer) is prepared, code-named Sample 2.

Embodiment 3

[0036] Except that the difference is that the amount of acrylic acid (AA) is changed to 20 parts by weight, compared with Example 1 in Example 3, the weight ratios and operating methods of other components are the same, and the oil well cement fluid loss reducer is prepared. (pentapolymer), the code name is sample 3.

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Abstract

The invention relates to a high-temperature-resistant salt-resistant water loss reducer and a preparation method thereof in the field of oil-gas well cementation. The high-temperature-resistant salt-resistant water loss reducer includes 100 parts by weight of water, 40-80 parts by weight of 2-acrylamido-2-methyl propanesulfonic acid, 30-70 parts by weight of N,N-dimethyl acrylamide, 1-30 parts byweight of 3-allyloxy-2-hydroxy-1-propanesulfonic acid, 1-20 parts by weight of acrylic acid, and 1-20 parts by weight of acrylonitrile. The high-temperature-resistant salt-resistant water loss reducercan be cooperatively used with other oil well cement additives under a condition of the temperature of up to 180 DEG C, has a wide range of temperature application and good salt resistance effect, does not affect the performance of cement slurry in saturated or semi-saturated brine, can be cooperatively used together with matched dispersants, medium-temperature retarders and high temperature retarders and the like to prepare low water loss cement slurry meeting different well cementing requirements, and is suitable for API oil well cement at all levels.

Description

technical field [0001] The invention relates to an additive in the field of oil and gas well cementing, and more specifically, to a high-temperature, salt-resistant, and fluid-loss-reducing agent as well as a preparation method and application thereof. Background technique [0002] During the drilling process of oil and gas, every well needs to be cemented. In the cementing project, it is necessary to run the casing into the specified well depth, and then pump cement slurry into the annular space between the casing and the wellbore to balance the formation pressure, isolate the oil, gas and water layers, and support the casing. During the contact between the cement slurry and the formation and the solidification of the cement slurry, the water in the cement slurry will seep into the formation. If the water loss of the cement slurry is too large, the volume of the water phase will continue to decrease, and in severe cases, the cement slurry will not be able to be pumped. , a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/58C08F220/54C08F220/06C08F220/48C08F216/14C09K8/035C09K8/487
CPCC08F220/54C08F220/58C08F220/585C09K8/035C09K8/487C08F220/06C08F220/48C08F216/1475
Inventor 刘飞刘学鹏方春飞周仕明张林海杨红歧
Owner CHINA PETROLEUM & CHEM CORP
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