A kind of spider silk-like polymer fiber based on column chromatography silica gel and preparation method thereof

A matrix polymer and column chromatography technology, applied in the field of chemical bionics, can solve the problems of weak interaction and low cost, and achieve the effect of weakening the impact, low cost and facilitating collection

Active Publication Date: 2020-06-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the method of the present application, by adding column chromatography silica gel during the spinning process, the spindle structure can be obtained during the fiber preparation process. There is a porous structure inside the column chromatography silica gel, and the pores inside the column chromatography silica gel can be formed during the spinning process. Forming a microfiber network in the middle, to a certain extent, solves the problem of weak interaction between the additive and the fiber matrix, and reduces the influence of the additive on the mechanical properties of the fiber. This method does not require major changes to the existing spinning process and does not require equipment Changing, technically, is simpler and less costly

Method used

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  • A kind of spider silk-like polymer fiber based on column chromatography silica gel and preparation method thereof
  • A kind of spider silk-like polymer fiber based on column chromatography silica gel and preparation method thereof
  • A kind of spider silk-like polymer fiber based on column chromatography silica gel and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] 7 grams of polyvinyl alcohol (PVA 1799, Aladdin, the degree of polymerization is 1700, and the degree of alcoholysis is 99%), 1.05 grams of column chromatography silica gel (purchased from Qingdao Jiyida Silica Reagent Co., Ltd., 200-300 mesh, pore size 20-30 angstroms, porosity 40-60%), dispersed in 43 grams of 1,4-dioxane (DMSO), heated and stirred at 80 degrees Celsius for 2 hours to obtain a uniform spinning dope. At room temperature, the above-mentioned spinning stock solution is extruded into methanol by a peristaltic pump for spinning: the actual extrusion rate is 0.02 milliliters per minute, the spinneret model is 25G (260 microns in diameter), and the spinning rate is 0.1 meters per minute. Minutes, the fibers are in the coagulation bath for at least 5 minutes; after being fully dried and collected, the primary fibers are obtained; heat-stretched to 8 times the original length at 180 degrees Celsius, and the spider silk-like fibers are obtained, and the test res...

Embodiment 2

[0065] 7 grams of polyvinyl alcohol (PVA 1799, Aladdin, the degree of polymerization is 1700, and the degree of alcoholysis is 99%), 1.4 grams of column chromatography silica gel (purchased from Qingdao Jiyida Silica Reagent Co., Ltd., 200-300 mesh, pore size 20-30 angstroms, porosity 40-60%), dispersed in 43 grams of 1,4-dioxane (DMSO), heated and stirred at 80 degrees Celsius for 2 hours to obtain a uniform spinning dope. At room temperature, the above-mentioned spinning stock solution is extruded into methanol by a peristaltic pump for spinning: the actual extrusion rate is 0.02 milliliters per minute, the spinneret model is 25G (260 microns in diameter), and the spinning rate is 0.1 meters per minute. Minutes, the fibers are in the coagulation bath for at least 5 minutes; after being fully dried and collected, the primary fibers are obtained; thermally stretched at 180 degrees Celsius to 8 times the original length, and the spider silk-like fibers are obtained. The diamete...

Embodiment 3

[0067] 7 grams of polyvinyl alcohol (PVA 1799, Aladdin, the degree of polymerization is 1700, and the degree of alcoholysis is 99%), 2.1 grams of column chromatography silica gel (purchased from Qingdao Jiyida Silica Reagent Co., Ltd., 200-300 mesh, pore size 20-30 angstroms, porosity 40-60%), dispersed in 43 grams of 1,4-dioxane (DMSO), heated and stirred at 70 degrees Celsius for 2 hours to obtain a uniform spinning dope. At room temperature, the above-mentioned spinning stock solution is extruded into methanol by a peristaltic pump for spinning: the actual extrusion rate is 0.02 milliliters per minute, the spinneret model is 25G (260 microns in diameter), and the spinning rate is 0.1 meters per minute. Minutes, the fibers are in the coagulation bath for at least 5 minutes; after being fully dried and collected, the primary fibers are obtained; heat-stretched to 8 times the original length at 180 degrees Celsius, and the spider silk-like fibers are obtained, and the test resu...

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Abstract

The invention relates to a spider silk-like polymer fiber based on column chromatography silica gel and a preparation method thereof in the technical field of chemobionics. The spider silk-like polymer fiber comprises the following components by weight: 100 parts of a fiber matrix polymer and 1-44 parts of column chromatography silica gel. The monofilament of the polymer fiber has a spider silk-like microstructure with spindle knot structural units in interval distribution, and the spindle knot structural units have a radial height of 10-300 microns, an axial length of 10-1000 microns, and aninterval of 10-5000 microns. The method provided by the invention has no need for substantial change of the existing spinning technology and has no need for change of equipment, the process is simple,and the cost is low. The spider silk-like polymer fiber obtained by the invention can realize directional movement of water droplets on the fiber surface, has water gathering function, and also has good mechanical properties.

Description

technical field [0001] The invention relates to the technical field of chemical bionics, and furthermore, relates to a spider silk-like polymer fiber based on column chromatography silica gel and a preparation method thereof. Background technique [0002] Water resources are important natural resources for the development of human society. Although the amount of water on the earth is huge, it is very little that can be directly used by people for production and life, accounting for only 0.26% of the total water on the earth. The sustainable use of water resources is the most important issue in the sustainable development and utilization of all natural resources. In today's society, the shortage of fresh water resources is gradually emerging. About 1.5 billion people in more than 80 countries around the world face insufficient fresh water, and 300 million people in 26 countries live in a state of complete water shortage. It is estimated that by 2025, 3 billion people in th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F1/10D01D5/06D01F6/50D01F6/54D01F6/70
CPCD01D5/06D01F1/10D01F6/50D01F6/54D01F6/70
Inventor 乔金樑姜超戚桂村张晓红宋志海赖金梅蔡传伦李秉海王湘蒋海斌张江茹茹越高建明张红彬韩朋
Owner CHINA PETROLEUM & CHEM CORP
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