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A kind of high strength and toughness high entropy alloy and preparation method thereof

A high-entropy alloy, high-strength technology, applied in the field of alloy materials, can solve problems such as the inability to meet the needs of working conditions, and achieve the effect of easy molding and low price

Active Publication Date: 2020-07-24
NAT INST CORP OF ADDITIVE MFG XIAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] With the rapid development of high-tech industries such as aerospace and advanced motor vehicles, and the continuous update of material preparation technology, people have put forward higher requirements for material performance. Traditional materials can no longer meet the needs of complex working conditions in active service.

Method used

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  • A kind of high strength and toughness high entropy alloy and preparation method thereof
  • A kind of high strength and toughness high entropy alloy and preparation method thereof
  • A kind of high strength and toughness high entropy alloy and preparation method thereof

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preparation example Construction

[0024] A method for preparing high-strength and tough high-entropy alloys, comprising the following steps:

[0025] Step 1), get the following raw materials by mass fraction: Ni: 33%-39%, Cr: 16-24%, W: 7-15%, Fe: 25-35%, Ti: 1%-7%, and the rest are Impurities: the above raw materials are mixed to prepare spherical alloy powder, the purity of spherical alloy powder is ≥99.9%, and the particle size is 15-53 μm;

[0026] Specifically, the elemental powders of Ni, Cr, W, Fe, and Ti elements with a purity of ≥99.9% are uniformly mixed according to the ratio of element content, and ball milled to prepare spherical alloy powder; Ni, Cr, W, and Ti with a purity of ≥99.9% The Fe and Ti blocks are smelted according to the ratio of element content to prepare rods, and then the rods are prepared into spherical alloy powders with gas atomization or rotating electrode method;

[0027] Step 2), the alloy powder prepared in step 1) is placed in a drying oven for drying and deoxidation, wher...

Embodiment 1

[0034] Step 1), take the following materials according to the mass fraction: Ni: 33, Cr: 20, W: 14, Fe: 28, Ti: 5, prepare the above materials and prepare them into spherical alloy powder, the purity of which is ≥99.9%, and the particle size Both are 15μm;

[0035] Step 2), the alloy powder prepared in step 1) is placed in a drying oven for drying and deoxidation, wherein the vacuum degree is 1×10 -2 Pa, the temperature is 60°C, the time is 7h, then naturally cool to room temperature, and store in vacuum packaging;

[0036] Step 3), put the alloy powder prepared in step 2) in the powder cylinder of the 3D printer, vacuumize the cavity to 98ppm, protect the cavity with Ar gas, wherein the oxygen content of the cavity is 760ppm, the pressure of the molding chamber is 17mba, and the working Pressure 3.8bar, blowing speed 950r / min;

[0037] Step 4), set the power of the 3D printer to 250W, the scanning speed to 1500mm / s, the rotation angle to 30°, the scanning distance to 80μm, ...

Embodiment 2

[0040] The following materials are taken according to the mass fraction: Ni: 33, Cr: 20, W: 14, Fe: 28, Ti: 5, the above materials are prepared and prepared into spherical alloy powder, the purity of which is ≥99.9%, and the particle size is 20 μm;

[0041] Step 2), the alloy powder prepared in step 1) is placed in a drying oven for drying and deoxidation, wherein the vacuum degree is 1×10 -2 Pa, the temperature is 70°C, the time is 6h, then naturally cool to room temperature, and store in vacuum packaging;

[0042] Step 3), put the alloy powder prepared in step 2) in the powder cylinder of the 3D printer, vacuumize the cavity to 100ppm, protect the cavity with He gas, wherein the oxygen content in the cavity is 755ppm, the pressure of the molding chamber is 17mba, and the working Pressure 3.9bar, blowing speed 1020r / min;

[0043] Step 4), set the power of the 3D printer to 250W, the scanning speed to 1500mm / s, the rotation angle to 30°, the scanning distance to 80μm, the amo...

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Abstract

The invention discloses a high-strength, toughness, and high-entropy alloy and a preparation method thereof. The raw materials are mixed according to the mass fraction or more, and after being dried and deoxidized, the high-strength, toughness, and high-entropy alloy is formed by using an SLM process, and a new non-isotropic alloy is obtained. The atomic ratio high-strength and high-toughness multi-principal high-entropy alloy is different from the existing high-entropy alloys. The use of 3D printing technology has realized a new method of preparing alloys that cannot be replaced by conventional methods. In particular, this method is easier to form complex structures and can meet the needs of complex components in aviation, aerospace and other fields. The obtained high strength and toughness high entropy alloy has a density of 8.5‑8.9g / cm 3 , the tensile strength is 800‑830 MPa, and the elongation after fracture is 21‑23%. The selected alloying elements are cheap and there are no more expensive elements.

Description

technical field [0001] The invention belongs to the technical field of alloy materials, and in particular relates to a high-strength and tough high-entropy alloy and a preparation method thereof. Background technique [0002] With the rapid development of high-tech industries such as aerospace and advanced motor vehicles, and the continuous update of material preparation technology, people have put forward higher requirements for material performance. Traditional materials can no longer meet the needs of complex working conditions in active service. To this end, researchers continue to explore and break through the chemical composition range of alloys, looking for new metal structural materials with excellent performance. High-entropy alloy is a new type of alloy material, and the alloy contains five or more main elements. The alloy has no obvious distinction between solute and solvent, and is considered a super solid solution alloy. The solid solution strengthening effect ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C30/00C22C1/04B22F3/105B33Y10/00B33Y70/00
CPCC22C1/04C22C30/00B33Y10/00B33Y70/00B22F10/00B22F10/36B22F10/34B22F10/366B22F10/28B22F10/38B22F10/32Y02P10/25
Inventor 陈祯杨喜岗张树哲魏培卢秉恒张丽娟邹亚桐
Owner NAT INST CORP OF ADDITIVE MFG XIAN