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Catalyst for the production of acrylic acid from glycerol

A catalyst, acrylic technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, organic chemistry, etc., can solve the problems of low acrylic acid yield, large investment, and high cost of ionic liquid catalysts

Active Publication Date: 2021-06-18
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] A large amount of glycerin dehydration to prepare acrolein has been reported, such as patent CN101070276A reported acidic molecular sieve as catalyst, 200-500 ℃, pressure 0.001-3.0MPa, liquid space velocity 0.1-100h -1 , the yield of acrylic acid can reach 70-80%, but the molecular sieve catalyst has the problem of poor high-temperature hydrothermal properties: patents CN102936189A, CN102942462A, using pyridine, imidazole and quaternary ammonium salt ionic liquid as catalysts, at a reaction temperature of 250-350 °C, the molar ratio of ionic liquid to glycerol is 0.1:100-1.5:100, acrolein is prepared from glycerin liquid phase dehydration, the conversion rate of glycerol is 100%, and the yield of product acrolein is 30.5-68.2%, but the ion The cost of liquid catalyst is high, and the production efficiency is not as high as that of fixed bed reactor.
Patent CN 105498845 A uses a supercritical CO 2 The CsPW / Zr-MCM-41 catalyst prepared in the environment, using this catalyst, the conversion rate of glycerin can reach 65.2-100%, and the selectivity of acrolein can reach 56.8-85.4%. However, supercritical conditions require high equipment and large investment
[0006] But the catalyst acrylic acid yield of prior art is on the low side

Method used

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  • Catalyst for the production of acrylic acid from glycerol
  • Catalyst for the production of acrylic acid from glycerol
  • Catalyst for the production of acrylic acid from glycerol

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0075] Take 400ml of commercially available SiO 2 Carrier powder, 20g graphite, 40g deionized water, mixed evenly, pelletized, dried at 120°C, calcined at 500°C for 2 hours, prepared Raschig ring carrier particles.

[0076] 3.5g platinum tetrachloride (PtCl 4 ) was dissolved in 100g of water to obtain a platinum tetrachloride aqueous solution. Take 200ml of carrier particles, pour the platinum tetrachloride aqueous solution into it, stir thoroughly, dry at 120°C, and roast at 500°C for 2 hours to obtain a catalyst. The catalytic activity is shown in Table 1 .

Embodiment 2

[0078] Take 400ml of commercially available TiO 2 Carrier powder, 20g graphite, 40g deionized water, mixed evenly, pelletized, dried at 120°C, calcined at 500°C for 2 hours, prepared Raschig ring carrier particles.

[0079] 5.2g hydrated ruthenium trichloride (RuCl 3 ·3H 2 O) dissolved in 100g of water to obtain an aqueous solution of ruthenium trichloride, take 200ml of carrier particles, pour the aqueous solution of ruthenium trichloride into it, fully stir, dry at 120°C, and roast at 500°C for 2 hours to obtain a catalyst. The catalytic activity is shown in the table 1.

Embodiment 3

[0081] Take 400ml of commercially available niobium pentoxide carrier powder, 20g of graphite, and 40g of deionized water, mix them uniformly, punch into tablets, dry at 120°C, and roast at 500°C for 2 hours to prepare Raschig ring carrier particles.

[0082] 3.6g iridium trichloride hydrate (IrCl 3 ·3H 2 O) Dissolve in 100g of water to obtain iridium trichloride aqueous solution, take 200ml of carrier particles, pour iridium trichloride aqueous solution into it, fully stir, dry at 120°C, and roast at 500°C for 2 hours to obtain a catalyst. The catalytic activity is shown in the table 1.

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Abstract

The present invention relates to a catalyst for producing acrylic acid from glycerin, a preparation method of the catalyst, and an application in synthesizing acrylic acid from glycerol. and an active component, the active component includes at least one technical solution selected from Pt, Re and Rh, which better solves the technical problem and can be used in the industrial production of glycerin to synthesize acrylic acid.

Description

technical field [0001] The invention relates to a catalyst for producing acrylic acid from glycerin, its application in preparing acrylic acid from glycerin, and a preparation method of the catalyst. Background technique [0002] Acrylic acid (CH 2 =CH-COOH) is the simplest unsaturated carboxylic acid, which is an important organic synthesis raw material and synthetic resin monomer. Acrylic acid is mainly used to synthesize advanced water-absorbent resins and water treatment agents, etc., and a part of acrylic acid is used for esterification to manufacture acrylates such as methyl acrylate, ethyl acrylate, n-butyl acrylate and 2-ethylhexyl acrylate, while Acrylate polymers are mainly used in adhesives, coatings, textiles, plastics, leather, paper and other fields. [0003] Acrylic acid and its series of products have developed rapidly in recent years. In 2015, the world's total output of acrylic acid and its esters reached 7.7 million t / a, an increase of about 27% compared...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/42B01J23/46B01J23/648B01J27/195C07C51/235C07C57/055
CPCB01J23/002B01J23/42B01J23/462B01J23/6484B01J27/195C07C45/52C07C51/235C07C57/04C07C47/22
Inventor 徐文杰杨斌王伟华奚美珍
Owner CHINA PETROLEUM & CHEM CORP
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