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Ammoniacal-odor-free foaming agent masterbatch special for low-density polyethylene (LDPE) high foaming process, and preparation method of ammoniacal-odor-free foaming agent masterbatch

A foaming agent and high-foaming technology, which is applied in the field of ammonia-free foaming agent masterbatch and its preparation for LDPE high-foaming process, which can solve the problem of stimulating ammonia smell

Active Publication Date: 2019-03-01
JIANGSU SOPO CHEM +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Foaming masterbatch is a common product form. Compared with powder foaming agent, although this product form solves the above-mentioned flying technical problems, it still has an obvious irritating ammonia smell.

Method used

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  • Ammoniacal-odor-free foaming agent masterbatch special for low-density polyethylene (LDPE) high foaming process, and preparation method of ammoniacal-odor-free foaming agent masterbatch
  • Ammoniacal-odor-free foaming agent masterbatch special for low-density polyethylene (LDPE) high foaming process, and preparation method of ammoniacal-odor-free foaming agent masterbatch

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A non-ammonia-smell foaming agent master batch for LDPE high foaming, which is composed of 75 parts of azodicarbonamide, 5 parts of ammonia removal agent, 0.5 part of dispersant and 19.5 parts of carrier resin in parts by weight. Wherein the ammonia removal agent is citric acid, which is used to remove the by-product ammonia and eliminate the pungent smell in the foamed product. The dispersant is white oil, which is used to help and improve the uniform dispersion effect of the effective components of azodicarbonamide and ammonia removal agent in the carrier resin. The carrier resin is ethylene-vinyl acetate, which is used to pre-mix azodicarbonamide and ammonia removal agent to form a high concentration and easy dispersion.

[0020] The preparation method is: add the proportioned azodicarbonamide, citric acid, white oil, and ethylene-vinyl acetate resin into the internal mixer, and make the internal mixing The temperature of the material in the machine reaches 90°C, an...

Embodiment 2

[0025] A non-ammonia-smell foaming agent master batch for LDPE high foaming, which is composed of 60 parts of azodicarbonamide, 10 parts of ammonia removal agent, 2 parts of dispersant and 28 parts of carrier resin in parts by weight. Among them, the ammonia removal agent is calcium chloride, which is used to remove the by-product ammonia and eliminate the pungent smell in the foamed product. The dispersant is stearic acid, which is used to help and improve the uniform dispersion effect of the effective components of the azodicarbonamide and the ammonia removal agent in the carrier resin. The carrier resin is ethylene-vinyl acetate, which is used to pre-mix azodicarbonamide and ammonia removal agent to form a high concentration and easy dispersion.

[0026] The preparation method is: add the proportioned azodicarbonamide, calcium chloride, stearic acid, and ethylene-vinyl acetate resin into the internal mixer, so that the temperature of the material in the internal mixer reach...

Embodiment 3

[0029] A non-ammonia-smell foaming agent master batch for LDPE high foaming, which is composed of 60 parts of azodicarbonamide, 10 parts of ammonia removal agent, 5 parts of dispersant and 25 parts of carrier resin in parts by weight. Among them, the ammonia removal agent is aluminum tripolyphosphate, which is used to remove the by-product ammonia and eliminate the pungent smell in the foamed product. The dispersant is polyethylene wax (PE wax), which is used to help and improve the uniform dispersion effect of the effective components of azodicarbonamide and ammonia removal agent on the carrier resin. The carrier resin is polyolefin elastomer, which is used to pre-mix azodicarbonamide and ammonia removal agent to form a high concentration and easy dispersion.

[0030] The preparation method is: add the proportioned azodicarbonamide, aluminum tripolyphosphate, PE wax, and polyolefin elastomer into the internal mixer, so that the temperature of the material in the internal mixe...

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Abstract

The invention discloses ammoniacal-odor-free foaming agent masterbatch special for a low-density polyethylene (LDPE) high foaming process, and a preparation method of the ammoniacal-odor-free foamingagent masterbatch. The ammoniacal-odor-free foaming agent masterbatch is prepared from a foaming agent, a deammoniation agent, a dispersing agent and carrier resin, and is concretely prepared from thefollowing components in parts by weight: 25-75 parts of azodicarbonamide, 5-40 parts of the deammoniation agent, 0.5-5 parts of the dispersing agent and 19.5-30 parts of the carrier resin. The preparation method comprises the steps of banburying and mixing the carrier resin, the azodicarbonamide, the deammoniation agent and the dispersing agent in an internal mixer until the mixing temperature is90-140 DEG C, extruding the obtained agglomerated mixture through a mould of an extruder, pelletizing with a rotary blade, and cooling.

Description

technical field [0001] The invention relates to a foaming agent masterbatch, in particular to a non-ammonia-smell foaming agent masterbatch for LDPE high foaming process and a preparation method thereof. Background technique [0002] Azodicarbonamide foaming agent is a yellow solid powder. Because of its large gas production capacity and high cost performance, it is the most commonly used foaming agent in the production of LDPE high foaming process. However, due to the generation of ammonia gas as a by-product during the decomposition process of ordinary azodicarbonamide foaming agents, LDPE high-foaming products all have an unpleasant pungent smell. [0003] LDPE high-foaming products are widely used. The cushion lining inside the luggage, the filling and fixing of precision instruments and high-end gift boxes are all made of this material. With the enhancement of consumers' awareness of environmental protection, high-end applications are limited because of the pungent sme...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08L91/00C08K5/092C08K3/16C08K3/32C08J9/10C08J3/22
CPCC08J3/226C08J9/0023C08J9/0061C08J9/0066C08J9/103C08J2203/04C08J2323/06C08J2423/06C08J2423/08C08J2491/00C08K5/092C08K2003/162C08K2003/327
Inventor 胡宗贵董建平朱桂生邵守言张之文黄永明唐丽
Owner JIANGSU SOPO CHEM
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