A preparation method and product of flame-retardant micro-foamed polyphenylene ether composite material
The technology of composite material and flame retardant material is applied in the field of preparation of flame retardant micro-foamed polyphenylene ether composite material, which can solve the problems of complex formula, complex preparation process steps and high cost, and achieves simple preparation method, good repeatability, high cost and high cost. low cost effect
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Embodiment 1
[0035] Get 70 parts by weight of polyphenylene ether (PPO, Bluestar Chemical Company, LXR040), 18 parts by weight of high-impact polystyrene (HIPS, BASF Chemical Company, 466F), 9 parts by weight of resorcinol bis(diphenyl Phosphate (RDP) and 3 parts by weight of aluminum hypophosphite (AP) were put into an internal mixer and mixed uniformly for 8 minutes at 260°C. Afterwards, the mixture was hot-pressed in a flat vulcanizing machine at 260°C for 10 minutes, cold-pressed for 5 minutes, and then taken out. The thickness of the polymer obtained by pressing was 1mm, and a flame-retardant material was obtained, which was recorded as PPO / HIPS-1, and its flame-retardant performance was listed as in Table 1 below.
[0036] The flame retardant material prepared in this example was placed in an autoclave for gas saturation. The saturated gas was carbon dioxide, the saturation pressure was 4 MPa, the saturation temperature was room temperature, and the saturation time was 12 hours. Aft...
Embodiment 2
[0039] Get the polyphenylene oxide (PPO) of 60 weight parts, the high-impact polystyrene (HIPS) of 28 weight parts, 9 weight parts resorcinol bis (diphenyl phosphate) (RDP), 3 weight parts hypophosphorous acid Aluminum (AP) was placed in an internal mixer and mixed uniformly for 8 minutes at a temperature of 260°C. Afterwards, the mixture was hot-pressed in a flat vulcanizing machine at 260°C for 10 minutes, cold-pressed for 5 minutes, and then taken out. The thickness of the polymer obtained by pressing was 1mm, and a flame-retardant material was obtained, which was recorded as PPO / HIPS-2, and its flame-retardant performance was listed as in Table 1 below.
[0040] The flame retardant material described in this example was placed in an autoclave for gas saturation. The saturated gas was carbon dioxide, the saturation pressure was 4 MPa, the saturation temperature was room temperature, and the saturation time was 12 hours. After the saturation equilibrium was reached, the sam...
Embodiment 3
[0044] Get the polyphenylene oxide (PPO) of 50 weight parts, the high-impact polystyrene (HIPS) of 38 weight parts, 9 weight parts resorcinol bis (diphenyl phosphate) (RDP), 3 weight parts hypophosphorous acid Aluminum (AP) was placed in an internal mixer and mixed uniformly for 8 minutes at a temperature of 260°C. Afterwards, the mixture was hot-pressed in a flat vulcanizer at 260°C for 10 minutes, cold-pressed for 5 minutes, and then taken out. The thickness of the polymer obtained by pressing was 1mm, and a flame-retardant material was obtained, which was recorded as PPO / HIPS-3, and its flame-retardant performance was listed as in Table 1 below.
[0045] The flame retardant material described in this example was placed in an autoclave for gas saturation. The saturated gas was carbon dioxide, the saturation pressure was 4 MPa, the saturation temperature was room temperature, and the saturation time was 12 hours. After the saturation equilibrium was reached, the sample was t...
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