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Method for preparing transition metal carbide powder through electric field and/or ultrasonic field reinforcement

A transition metal and ultrasonic field technology, applied in the electrolysis process, electrolysis components, etc., can solve the problems of high oxygen content in the product, the reduction of transition metal low-valent oxides and solid solutions, and the difficulty of oxygen removal, so as to achieve high product quality , Strengthen the carbonization kinetic process, and the effect of simple equipment

Active Publication Date: 2019-06-14
NORTHEASTERN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method uses oxides as raw materials, and the reduction and oxygen removal of transition metal subvalent oxi

Method used

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  • Method for preparing transition metal carbide powder through electric field and/or ultrasonic field reinforcement
  • Method for preparing transition metal carbide powder through electric field and/or ultrasonic field reinforcement
  • Method for preparing transition metal carbide powder through electric field and/or ultrasonic field reinforcement

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0086] A method for preparing transition metal carbide powder by electric field strengthening, comprising the following steps:

[0087] Step 1. Preparation of high melting point transition metal-carbon sintered sheet

[0088] (1) Mix metal Nb and amorphous carbon powder according to a molar ratio of 1:1, add polyvinyl alcohol ethanol saturated solution accounting for 2wt% of the total mass percentage of metal Nb and amorphous carbon powder, and mix uniformly to obtain a mixture;

[0089] The metal Nb powder has a particle size of 1 μm, and the amorphous carbon powder has a particle size of 0.2 μm.

[0090] (2) Weighing 2 g of the mixture and molding it under 10 MPa pressure to obtain a cylindrical sheet, the diameter of the cylindrical sheet is 15 cm, and the thickness is 2-3 mm;

[0091] (3) Put the cylindrical sheet in a resistance furnace, and sinter it at 1000° C. for 3 hours under an Ar atmosphere to obtain a high melting point transition metal-carbon sintered sheet.

...

Embodiment 2

[0101] A method for preparing transition metal carbide powder by ultrasonic field strengthening, the same as in Example 1, the difference is:

[0102] (1) In step 3, the high melting point transition metal-carbon sintered piece is connected to the stainless steel wire, the high melting point transition metal-carbon sintered piece is immersed in the molten salt system after pre-electrolysis, and the high melting point transition metal-carbon sintered A 20kHZ ultrasonic field was applied to the stainless steel wire of the sheet through an ultrasonic generator, and the carbonization reaction time was 8h. Compared with Comparative Example 1, ultrasonic vibration can accelerate the diffusion of carbon into the interior of niobium, and eliminate the influence of the natural oxide layer formed on the surface on the kinetics of the carbonization process. At the same time, it can refine the carbide product and obtain carbide powder with a particle size of less than 100nm.

[0103] Other...

Embodiment 3

[0106] A method of electro-ultrasonic coupling field strengthening for preparing transition metal carbide powder, the same as in Example 1, the difference lies in:

[0107] (1) While applying the electric field in step 3, use the KMD-K1 ultrasonic generator to apply an ultrasonic field with a frequency of 20kHZ on the stainless steel wire, and the carbonization reaction time is 4h;

[0108] Other implementations are the same.

[0109] The flow chart of the method for preparing NbC by electro-ultrasonic coupled field assisted carbonization is shown in Figure 4 .

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Abstract

The invention provides a method for preparing transition metal carbide powder through electric field and/or ultrasonic field reinforcement and belongs to the field of smelting of transition metal ceramic powder. The method comprises the following steps: mixing transition metal powder with a high smelting point with carbon powder according to a ratio, then adding an adhesive, mixing, pressing and roasting to obtain a sintered sheet; dewatering fused salt, then carrying out pre-electrolysis, immersing the sintered sheet into the dewatered fused salt, applying electric field and/or ultrasonic field reinforcement for carrying out carbonation reaction, washing and drying to obtain the transition metal carbide powder. The method is capable of preparing the carbide powder by taking transition metal as a raw material and using a fused salt medium environment by means of an electric field and/or ultrasonic field reinforcement method; the problems of incomplete oxygen removal in oxides and low quality of the product can be effectively solved; high-efficiency and high-quality preparation of the transition metal carbide powder under a relatively low temperature can be achieved; the used equipment is simple to operate.

Description

technical field [0001] The invention belongs to the field of transition metal ceramic powder smelting, and in particular relates to a method for preparing transition metal carbide powder strengthened by an electric field and / or an ultrasonic field. Background technique [0002] Transition metal carbide powder formed by transition metals such as tantalum, niobium, titanium, etc. is a non-oxide ceramic powder, which is used for alloy reinforcement phase, catalyst, optical material, aviation material, etc. due to its good physical and chemical properties. field. Among them, as the reinforcement phase of the alloy, that is, the reinforcement phase of the matrix material, is the most important application of transition metal carbide powder. The preparation methods of transition metal carbide powder include carbothermal reduction method, direct contact carbonization method, high temperature self-propagating synthesis method, flame synthesis method, plasma sintering method, molten...

Claims

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Application Information

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IPC IPC(8): C25B1/00
Inventor 宋秋实张政谢宏伟宁志强尹华意
Owner NORTHEASTERN UNIV
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