Preparation method of a photoelectrochemical biosensor for simultaneous detection of dual myocardial markers
A myocardial marker and biosensor technology, which can be used in electrochemical variables of materials, scientific instruments, and material analysis by optical means, etc., can solve problems such as limiting wide application, and achieve the effects of accurate results, high sensitivity and simple operation.
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[0027] The preparation method of the photoelectrochemical biosensor for simultaneously detecting double myocardial markers of the present invention comprises the following steps:
[0028] 1) Deposit nano gold on the surface of ITO electrode to obtain Au / ITO electrode;
[0029] In order to obtain Au / ITO electrodes with better conductivity, under the deposition voltage from 0.7V-1.2V, gold nanoparticles were deposited by cyclic voltammetry on the surface of clean ITO electrodes, and washed with phosphate buffer solution of pH=7.4 Electrode surface, get Au / ITO electrode, the result is as follows figure 1 as shown, figure 1 A- figure 1 F are the SEM images of electrodeposited gold nanoparticles at deposition voltages of 0.7V, 0.8V, 0.9V, 1.0V, 1.1V, and 1.2V, respectively. The inset is a CV (current-voltage curve) graph, in which cyclic voltammetry The parameters are set as follows: the initial potential is -0.2V, the scan rate is 0.1V / S, figure 1 The SEM image in shows the ef...
Embodiment 1
[0039] The preparation method of the photoelectrochemical biosensor for simultaneous detection of double myocardial markers in this embodiment comprises the following steps:
[0040] 1) The deposition voltage is 0.9V, gold nanoparticles are deposited on the surface of a clean ITO electrode, and the electrode surface is washed with a phosphate buffer solution with pH=7.4 to obtain an Au / ITO electrode.
[0041] 2) Dissolve 1.0 mg of CdS nanowires in 1.0 mL of 0.1 mg / mL chitosan solution, the concentration of CdS is 1.0 mg / mL, and 1.0 mg of SnNb 2 o 6 Nanosheets were dissolved in 1.0 mL of 0.1 mg / mL chitosan solution, SnNb 2 o 6 The concentration is 1.0mg / mL, take 20 microliters of the mixed solution of CdS and chitosan and 20 microliters of SnNb 2 o 6 The mixed solution of chitosan and chitosan is added dropwise in two different regions of the Au / ITO electrode obtained in step 1), and dried at 60°C to obtain a region containing both CdS / Au / ITO and SnNb 2 o 6 / Au / ITO modifi...
Embodiment 2
[0044] The preparation method of the photoelectrochemical biosensor for simultaneous detection of double myocardial markers in this embodiment comprises the following steps:
[0045] 1) The deposition voltage is 0.9V, gold nanoparticles are deposited on the surface of a clean ITO electrode, and the electrode surface is washed with a phosphate buffer solution with pH=7.4 to obtain an Au / ITO electrode.
[0046] 2) Dissolve 0.5 mg of CdS nanowires in 1.0 mL of 0.11 mg / mL chitosan solution, the concentration of CdS is 0.5 mg / mL, and 0.5 mg of SnNb 2 o 6 Nanosheets were dissolved in 1.0 mL of 0.11 mg / mL chitosan solution, SnNb 2 o 6 The concentration is 0.5mg / mL, take 20 microliters of the mixed solution of CdS and chitosan and 20 microliters of SnNb 2 o 6 The mixed solution of chitosan and chitosan is added dropwise in two different regions of the Au / ITO electrode obtained in step 1), and dried at 65°C to obtain a region containing both CdS / Au / ITO and SnNb 2 o 6 / Au / ITO modi...
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