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A kind of super capacitor electrolyte and super capacitor

A supercapacitor and electrolyte technology, which is applied in the direction of hybrid capacitor electrolyte, etc., can solve the problems of short electrolyte cycle life and large gas production

Active Publication Date: 2022-08-09
SHENZHEN CAPCHEM TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to provide a supercapacitor electrolyte for the short cycle life and large gas production of the electrolyte in the prior art under high temperature and high voltage

Method used

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  • A kind of super capacitor electrolyte and super capacitor
  • A kind of super capacitor electrolyte and super capacitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Using N,N-dimethylpyrrolidine ammonium tetrafluoroborate as the solute and acetonitrile (AN) as the solvent, prepare a 2.0mol / L electrolyte, and then add 0.2% phenylsilane based on the total mass of the electrolyte. The electrolyte consists of are listed in Table 1, and the conductivity of the electrolyte at 25°C was measured, and the results are listed in Table 1. The supercapacitor was fabricated with this electrolyte and its electrochemical performance was tested. The test results of life, capacity and ESR are listed in Table 1, respectively.

Embodiment 2-13

[0040] Except that the solute, solvent, additive and concentration of the electrolyte are different from those of Example 1, the rest are the same. The solute, solvent, additive and concentration composition of the electrolyte of each embodiment are listed in Table 1 and Table 2, and the conductivity of the electrolyte at 25° C. is measured, and the results are listed in Table 1 and Table 2, respectively. The supercapacitors were fabricated with these electrolytes and their electrochemical properties were tested. The test results of life, capacity and ESR are listed in Table 1 and Table 2, respectively.

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Abstract

In order to overcome the problems of short cycle life and large gas production of the electrolyte in the prior art under high temperature and high voltage, the present invention provides a supercapacitor electrolyte, comprising a polar aprotic solvent, an organic electrolyte and an additive, wherein the additive is selected from the group consisting of: From the compound shown in structural formula 1: structural formula 1: wherein, R is an alkane nitrile containing 1-3 carbon atoms or containing structural formula 2: structural formula 2: wherein R 1 ~R 3 Selected from hydrogen, alkyl groups containing 1-3 carbon atoms, alkoxy groups containing 1-3 carbon atoms or aromatic hydrocarbons; R 1 ~R 3 Can be the same or different. At the same time, the present invention also discloses a supercapacitor using the above electrolyte. The supercapacitor containing the supercapacitor electrolyte provided by the invention has long cycle life and small gas production under high temperature and high voltage.

Description

technical field [0001] The invention relates to a super capacitor electrolyte and a super capacitor. Background technique [0002] Supercapacitors, also known as gold capacitors and electrochemical capacitors, use ion adsorption (electric double-layer capacitors) or surface fast redox reactions (pseudocapacitors) to store energy. Supercapacitors are a new type of energy storage device between batteries and traditional electrostatic capacitors. Supercapacitors store hundreds of times more charge than traditional solid-state electrolytic capacitors, can be fully charged and discharged in seconds, have higher power input or output than batteries, and can be reached in less time. At the same time, supercapacitors have the advantages of short charging and discharging time, long storage life, high stability, and wide operating temperature range (-40 °C ~ 70 °C), so they are widely used in the field of consumer electronics, new energy power generation systems, distribution energy...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G11/64H01G11/60H01G11/62
CPCH01G11/64H01G11/60H01G11/62Y02E60/13
Inventor 向晓霞
Owner SHENZHEN CAPCHEM TECH CO LTD