Adhesive composition including at least two types of dyes, adhesive sheet, and display device including same
A bonding composition and bonding sheet technology, applied in the direction of azo dyes, organic dyes, polymer adhesive additives, etc., can solve the problems of reducing the durability of the device, reducing the visibility of the device, and being unable to effectively block light
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preparation example 1
[0231] Preparation Example 1: Preparation of the first light-absorbing dye
[0232] A dye having the following chemical formula was used as the first light-absorbing dye.
preparation example 1-1
[0234]
[0235] Dimethylformamide (DMF, 20ml) was injected into a 250ml three-neck round bottom flask, and Chemical Formula A1 (10.0g, 0.0247mol) and Chemical Formula B1 (10.7g, 0.0789mol) were put into it. Add potassium carbonate (K 2 CO 3 , 3.4g) and the temperature was raised to 120° C., and reflux was carried out for 3 hours. Ethyl acetate (EA, ethyl acetate, 100 ml) and water were added to the reaction mixture for washing. The solvent was removed to obtain the target compound (chemical formula C1, 15.7 g, yield: 90.13%).
[0236] MALDI-TOF: m / z=705.71 (C 36 h 39 N 3 o 12 =705.25)
preparation example 1-2
[0238]
[0239] Dimethylformamide (DMF, 20ml) was injected into a 250ml three-necked round bottom flask, and Chemical Formula A1 (10.0g, 0.0247mol) and Chemical Formula B2 (15.5g, 0.1037mol) were put into it. Add potassium carbonate (K 2 CO 3 , 3.4g) and the temperature was raised to 120° C., and reflux was carried out for 6 hours. Ethyl acetate (EA, ethyl acetate, 100 ml) and water were added to the reaction mixture for washing. The solvent was removed to obtain the target compound (chemical formula C2, 18.3 g, yield: 86.00%).
[0240] MALDI-TOF: m / z=861.93 (C 45 h 55 N 3 o 14 =861.37)
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