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High temperature corrosion inhibitor for acidification

A high-temperature corrosion inhibitor and corrosion inhibition technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of poor compatibility between corrosion inhibitors and acid liquid systems, increase in cost of corrosion inhibitors, etc., and achieve product performance. Safe and reliable, reducing the risk of flammability, and the effect of good corrosion inhibition performance

Active Publication Date: 2021-11-02
CNPC BOHAI DRILLING ENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Taking methanol as an example of a corrosion inhibitor commonly used as a solvent, the weight fraction of methanol in the corrosion inhibitor accounts for about 50%, which results in poor compatibility between the corrosion inhibitor and the acid system during construction; The more the amount of corrosion inhibitor is added, there is also a risk of flammability in high temperature and hot weather, and the cost of the corrosion inhibitor formulated with methanol will also increase accordingly

Method used

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  • High temperature corrosion inhibitor for acidification
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  • High temperature corrosion inhibitor for acidification

Examples

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Effect test

Embodiment 1

[0024] A preparation method of high-temperature corrosion inhibitor, the steps are as follows:

[0025] 1) Prepare a mixed solution containing aldehyde, ketone and amine condensation polymers: add 70g of formaldehyde and 300g of acetophenone into the reaction flask, then add 2mL of 37.5wt.% hydrochloric acid, and stir at a stirring speed of 0.5~1r / s at a rate of 0.5~ Raise the temperature to 90°C at a rate of 2min / °C, keep it warm for 4h, and then cool down to room temperature and let it stand for 4h to separate the water in the lower layer. Add 200g of polyvinylpolyamine (number average molecular weight: 3000) dropwise to the solution state aldehyde and ketone polycondensate under the stirring speed of 0.5-2min / °C. When it is lowered to room temperature, the obtained product is a mixed solution containing aldehyde, ketone and amine polycondensates; after testing, in the mixed solution containing aldehyde, ketone and amine polycondensates, the molecular weight of aldehyde, ket...

Embodiment 2

[0028] A preparation method of high-temperature corrosion inhibitor, the steps are as follows:

[0029] 1) Prepare a mixed solution containing aldehyde, ketone, and amine condensation polymers: add 32 g of formaldehyde and 120 g of acetophenone into the reaction flask, then add 2 mL of 37.5 wt. Raise the temperature to 80°C at a rate of 2min / °C, keep it warm for 5h, and then lower it to room temperature and let it stand for 4.5h to separate the water in the lower layer, and the product in the upper layer is aldehyde and ketone condensation polymer; At a stirring speed of s, add 450g of polyethylene polyamine (number average molecular weight: 4200) dropwise to the solution aldehyde and ketone polycondensate. After the dropwise addition is completed, the temperature is raised to 80°C at a speed of 0.5~2min / °C, and the temperature is kept for 4h. After cooling down to room temperature, the obtained product is a mixed solution containing aldehyde, ketone and amine polycondensates;...

Embodiment 3

[0032] A preparation method of high-temperature corrosion inhibitor, the steps are as follows:

[0033]1) Preparation of a mixture containing aldehyde, ketone and amine condensation polymers: Add 150g of formaldehyde and 120g of cyclohexanone into the reaction flask, then add 2mL of 37.5wt.% hydrochloric acid, and stir at a stirring speed of 0.5~1r / s at a rate of 0.5~ Raise the temperature to 90°C at a speed of 2min / °C, keep it warm for 4h, and then lower it to room temperature and let it stand for 5h to separate the water in the lower layer. Add 270g of polyvinylpolyamine (number average molecular weight: 3800) dropwise to the solution state aldehyde and ketone polycondensate under the stirring speed of 0.5-2min / °C, heat it up to 70°C at a speed of 0.5-2min / °C, keep it for 5h, and then When it is lowered to room temperature, the obtained product is a mixed solution containing aldehyde, ketone and amine polycondensates; after testing, in the mixed solution containing aldehyde,...

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Abstract

The invention discloses a high-temperature corrosion inhibitor for acidification, which comprises, by mass fraction, 30-40% of a main corrosion inhibitor, 10-17% of an emulsifier, 5.5-9% of a high-temperature synergist, 5-10 % carbon number is C 6 ~C 10 The linear acetylenic diol and the balance of water; the main corrosion inhibitor is a mixture of polyaspartic acid and a mixture of aldehydes, ketones, and amines; the mixture of aldehydes, ketones, and amines is composed of formaldehyde, The mixed solution produced by polycondensation reaction of ketone and polyethylene polyamine, or the mixed solution produced by polycondensation reaction of formaldehyde, cyclohexanone and polyethylene polyamine; the high-temperature synergist is a mixture of metal oxide and alkali metal organic salt; The high-temperature corrosion inhibitor for acidification has a temperature resistance of 160-180 °C, and has good corrosion inhibition performance. It uses water as a solvent instead of methanol as a solvent in traditional corrosion inhibitors, making the high-temperature corrosion inhibitor for acidification more efficient. Green and environmentally friendly, the product performance is safe and reliable, and it is more convenient to transport.

Description

technical field [0001] The invention relates to the field of additives in the acidizing liquid system used in the process of increasing production of oil and gas wells, in particular to a high-temperature corrosion inhibitor for acidizing. Background technique [0002] Acidizing is a commonly used process in the process of oil and gas well stimulation, and acid liquid system is a commonly used liquid system in acidizing. No matter what kind of acid system is used as the well fluid, additives such as corrosion inhibitors must be added to the system to prevent corrosion of tubing and acidizing equipment. [0003] At present, whether the commonly used corrosion inhibitors on the market are high-temperature series corrosion inhibitors or medium-temperature series corrosion inhibitors, alcohols are mostly used as solvents to prepare corrosion inhibitors. Taking methanol as an example of a corrosion inhibitor commonly used as a solvent, the weight fraction of methanol in the corr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/74C08G12/00
CPCC08G12/00C09K8/74
Inventor 刘音李欣苗红海周广龙张伟辉华亮王玉善刘位张国辉贺燕飞
Owner CNPC BOHAI DRILLING ENG
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