A kind of method and device for catalytic conversion of petroleum hydrocarbon raw material to produce olefins and aromatic hydrocarbons

Abstract

The invention relates to a method for producing olefins and aromatics through catalytic conversion of petroleum hydrocarbon raw materials, and belongs to the technical field of catalytic conversion of petroleum hydrocarbons. The method adopts heavy petroleum hydrocarbon raw materials to carry out catalytic conversion in the first reaction regeneration system and the second reaction regeneration system respectively, the raw materials are first catalytically converted in the first catalyst environment of the first reaction regeneration system, and all or part of the generated gas phase products enter the The second reaction regeneration system, under the environment of the second catalyst, performs sub-high temperature reaction and high temperature reaction in sequence to produce ethylene propylene and aromatic hydrocarbons. The present invention sets up a series of three-stage temperature gradients that gradually rise in temperature, that is, the low-temperature zone of the first reactor, the sub-high temperature zone of the second reactor, and the high-temperature zone of the second reactor. The dual reaction system and dual catalyst circulation increase the yield of high-value products ethylene and propylene.

Description

technical field [0001] The invention belongs to the technical field of catalytic conversion of petroleum hydrocarbons, and in particular relates to a method for producing olefins and aromatics by catalytic conversion of petroleum hydrocarbon raw materials. The invention also provides a device for realizing the above method. Background technique [0002] Low-carbon olefins represented by ethylene and propylene are the most basic raw materials in the chemical industry. The existing catalytic conversion technology is to produce low-carbon olefins while producing gasoline and diesel, which is far from meeting the current market demand for organic chemical raw materials. Aromatics is an important organic chemical raw material second only to ethylene and propylene in output and scale. Its derivatives are widely used in the production of chemical fibers, plastics, rubber and other chemical products and fine chemicals. With the continuous development of petrochemical and textile indu...

AI Technical Summary

Problems solved by technology

Although in order to increase the production of low-carbon olefins, 5-8% additives can be added to the regenerator to further convert small molecules, but when the additives are added to the FCC catalyst, due to the dilution of the catalyst, the cracking activity of the catalyst will inevitably decrease.

Usually every 5% additive is added, the cracking conversion rate of heavy oil decreases by 1 percentage point, and the reduction of conversion rate of heavy oil is an important factor that seriously affects the technical economy of FCC. , the improvement of the target product is limited

[0011] 2. Since the second reaction system requires more heat of reaction, coke is generally less, and the heat released by the regeneration of coke itself cannot provide the heat required for the reaction. If the original technology is used to establish an independent second reaction system, it will be restricted by heat balance problems

After the process of first cooling down and then heating up, the investment in equipment and energy consumption is increased, which greatly reduces the economical efficiency of the process technology

[0013] 4. The production of ethylene from petroleum hydrocarbons requires a higher reaction temperature, generally higher than 600°C; the reaction process of catalyzing olefins from catalytic cracking feedstock oil, especially heavy feedstock oil, is a process of gradual cracking and gradual reduction of molecular weight; the smaller the molecule The more difficult it is to activate, the higher the reaction temperature is required, and the high temperature will naturally reheat the cracking reaction, which will affect the selectivity of the target product; how to allocate the reaction temperature and the molecular characteristics of petroleum hydrocarbons, balance the catalytic cracking reaction and thermal cracking reaction, and realize the The limit control of reaction is significant; the desired reaction process is to increase the proportion of catalytic reaction as much as possible in the cracking stage of heavy oil and other macromolecules, limit thermal cracking, and gradually increase the temperature and increase the proportion of thermal cracking reactions in the cracking stage of small molecules; The heat of the reaction process is provided in the inlet area of ​​the reactor, and the reaction is a process of gradually cooling down, especially for the reaction of ethylene production. Due to the high reaction temperature required, the initial stage, that is, the heavy oil cracking stage in the lower part of the reactor, has a higher reaction temperature and heavy components The thermal cracking reaction is carried out directly, reducing the effect of the catalytic cracking reaction

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