Laminate and method for manufacturing laminate
A technology of laminates and coatings, applied in chemical instruments and methods, semiconductor/solid-state device manufacturing, coatings, etc., can solve problems such as unresearched, substrate warpage, etc., and achieve high dimensional accuracy.
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Embodiment 1
[0066] Utilize the float method to obtain composition 1 (in terms of mass % SiO 2 : 56.9%, Al 2 o 3 : 8.1%, CaO: 2.3%, SrO: 12.3%, BaO: 20.4%) glass raw material plate (length and width 1000mm, thickness 1.4mm). A circular shape with a radius of 75 mm (diameter: 150 mm) was cut out from the center of the raw material sheet to prepare a disc-shaped glass plate. After chamfering, grinding was performed with a double-side grinder (16B-N / F manufactured by Hamai Seisakusho Co., Ltd.), and the plate thickness (dg) was adjusted to 1.0 mm. The radius of curvature r0 (based on the float method) of the glass sheet was 370 m under self-weight deflection correction.
[0067] Thereafter, a silicon nitride film was formed by reactive sputtering using a silicon target using a sputtering apparatus (SIV-345XYSSS manufactured by ULVAC) on the warped convex side of the glass plate so that the compressive stress of the film became 1 GPa. The thickness (dc) of the coating was 0.5 μm. Table 1 ...
Embodiment 2~ Embodiment 7 and comparative example 1~4
[0069] Except having changed into the conditions described in Table 1, it carried out similarly to Example 1. Table 1 shows the evaluation results.
[0070]
[0071] (quality%)
[0072] Composition 1: SiO 2 : 56.9%, Al 2 o 3 : 8.1%, CaO: 2.3%, SrO: 12.3%, BaO: 20.4%
[0073] Composition 2: SiO 2 : 68.9%, Al 2 o 3 : 5.9%, MgO: 4.1%, CaO: 7.3%, Na 2 O: 14.6%, K 2 O: 0.2%
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