Production method for medical balloon
A manufacturing method and medical technology, applied in balloon catheters, catheters, coatings, etc., to achieve the effect of inhibiting delayed-type hypersensitivity
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[0190] Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these Examples. In addition, unless otherwise indicated, the following "parts" are based on weight. In addition, various physical property measurements and evaluation tests were performed as follows.
[0191] Solid content concentration
[0192] A 2-g sample (weight: X2) was accurately weighed in an aluminum pan (weight: X1), and dried in a hot air dryer at 105° C. for 2 hours. Next, after cooling in a desiccator, the weight (weight: X3) of the aluminum pan was measured, and the solid content concentration was calculated according to the following calculation formula.
[0193] Solid content concentration (weight %)={(X3-X1) / X2}×100
[0194] Modification rate
[0195] by using 1 H-NMR measures the carboxy-modified conjugated diene polymer constituting the latex of the carboxy-modified conjugated diene polymer to determine the number of carboxyl groups in the ...
manufacture example 1
[0213] Production of Latex of Carboxyl-modified Synthetic Polyisoprene (A-1)
[0214] Synthetic polyisoprene with a weight average molecular weight of 1,300,000 (trade name "NIPOL IR2200L", manufactured by Nippon Zeon Co., Ltd., homopolymer of isoprene, cis-bonding unit content 98%) and cyclohexane Mix and dissolve by raising the temperature to 60° C. while stirring to prepare a synthetic polyisoprene cyclohexane solution (a) (solid content concentration: 8% by weight) having a viscosity of 12,000 mPa·s as measured by a B-type viscometer.
[0215] On the other hand, 20 parts of sodium abietic acid was added to water, and the temperature was raised to 60° C. to dissolve, thereby preparing an anionic surfactant aqueous solution (b) having a concentration of 1.5% by weight.
[0216] Next, the above cyclohexane solution (a) and the above anionic surfactant aqueous solution (b) were mixed in a weight ratio of 1:1.5 using a mixer (trade name "Multi-line mixer MS26-MMR-5.5L" , man...
manufacture example 2
[0222] Production of Latex of Carboxyl-modified Synthetic Polyisoprene (A-2)
[0223] Except that the amount of methacrylic acid used was changed from 3 parts to 5 parts, the same procedure as in Production Example 1 was carried out to obtain a latex of carboxyl-modified synthetic polyisoprene (A-2) having a solid content concentration of 55%. . The obtained latex of the carboxyl group-modified synthetic polyisoprene (A-2) was measured for the modification rate by the above-mentioned method, and the modification rate was 1 mol%.
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