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Polythiocarbonate-containing wastewater treatment agent, application thereof and wastewater treatment method

A polythiocarbonate, wastewater treatment agent technology, applied in water/sewage treatment, chemical instruments and methods, water/sewage multi-stage treatment, etc., can solve the problem of high dosage and cost, insufficient research on compound applications, etc. question

Pending Publication Date: 2021-04-20
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, for the research on trimercaptotriazine compounds, most of the literature focuses on the application research of trimercaptotriazine compounds themselves, and the research on their compound application is not enough, which makes the use dosage and cost higher

Method used

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  • Polythiocarbonate-containing wastewater treatment agent, application thereof and wastewater treatment method
  • Polythiocarbonate-containing wastewater treatment agent, application thereof and wastewater treatment method

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preparation example Construction

[0025] The preparation method of the wastewater treatment agent of the present invention is not particularly limited, as long as the above components are mixed. In order to make the compounding effect of different medicaments better, preferably, water may also be added during the mixing process. The amount of water added is not particularly limited, and it is based on the fact that it is more favorable for the mixing of polythiocarbonate, water-soluble chitosan and / or its derivatives, and trimercaptotriazine compound. That is, preferably, the polythiocarbonate-containing wastewater treatment agent may also contain water, preferably, based on the total amount of the wastewater treatment agent, the content of the water is 10-50% by weight.

[0026] The second aspect of the present invention provides the application of the above polythiocarbonate-containing wastewater treatment agent in the treatment of heavy metal-containing wastewater.

[0027] A third aspect of the present in...

Embodiment approach

[0038] According to a specific embodiment of the present invention, step (1) includes adding a wastewater treatment agent into the wastewater containing heavy metals, stirring, and then performing the contacting.

[0039] The present invention has no special limitation on the contacting conditions of the step (2), so as to satisfy the complete reaction between the mixture obtained in the step (1) and the polyacrylamide. Preferably, the contacting conditions in step (2) include: a temperature of 20-40° C. and a time of 5-60 minutes.

[0040] According to a specific embodiment of the present invention, the step (2) includes adding polyacrylamide into the mixture obtained in the contacting step (1), stirring, and then performing the contacting.

[0041] According to a preferred embodiment of the present invention, the weight ratio of the heavy metal-containing wastewater to the wastewater treatment agent in terms of heavy metals is 1:(4-16), more preferably 1:(5-13).

[0042] Acco...

Embodiment 1

[0056] Take by weighing 15g sodium trithiocarbonate, 9g chitosan and 45g trisodium trimercaptotriazine, the ratio of the three is 1:0.6:3, then add 31g water and mix to obtain wastewater treatment agent, the content of water is 31% by weight %.

[0057] (1) Use 15% by weight of sodium hydroxide solution to adjust the pH value of the wastewater to 9, take 1L of wastewater, add 160 mg of the above-mentioned wastewater treatment agent, stir, and then contact for 8 minutes;

[0058] (2) Add polyacrylamide to the mixture obtained in step (1), stir, and then contact for 30 minutes. The concentration of polyacrylamide is 1.5 mg / L, and stand for 30 minutes.

[0059] The supernatant was taken to measure the heavy metal content and turbidity in the water, and the results are listed in Table 2.

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Abstract

The invention relates to the field of wastewater treatment, and discloses a polythiocarbonate-containing wastewater treatment agent, an application thereof and a wastewater treatment method, the heavy metal wastewater treatment agent contains polythiocarbonate, water-soluble chitosan and / or derivatives thereof and a trimercaptotriazine compound; wherein the weight ratio of the polythiocarbonate to the water-soluble chitosan and / or the derivative thereof to the trimercaptotriazine compound is 1: (0.6-3): (0.8-3). The polythiocarbonate, the water-soluble chitosan and / or the derivative thereof and the trimercaptotriazine compound are matched for use, so that the treatment requirement of heavy metal wastewater is met, and a better precipitation separation effect is achieved when the polythiocarbonate, the water-soluble chitosan and / or the derivative thereof and the trimercaptotriazine compound are used in the wastewater treatment process.

Description

technical field [0001] The invention relates to the field of waste water treatment, in particular to a waste water treatment agent containing polythiocarbonate, its application and a waste water treatment method. Background technique [0002] As the first type of pollutants, heavy metals have the characteristics of accumulation and non-biodegradability, which cause great harm to the ecosystem and human health. Due to the rapid development of industry, the pollution of heavy metals to water resources is becoming more and more serious. With the increasingly stringent environmental protection regulations, the removal of heavy metals in water has become an increasingly important issue. [0003] Heavy metal treatment methods mainly include chemical precipitation, ion exchange, reverse osmosis and adsorption. Among them, the adsorption method and the precipitation method are simple to operate and low in cost, and are the most commonly used heavy metal wastewater treatment methods...

Claims

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Application Information

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IPC IPC(8): C02F1/62C02F9/04C02F101/20
Inventor 秦会敏郦和生谢文州楼琼慧
Owner CHINA PETROLEUM & CHEM CORP