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A kind of fire-resistant environmental protection curtain wall and preparation method thereof

An environmental protection and curtain wall technology, applied in the field of building materials, can solve problems such as hindering popularization and application, poor mechanical strength and flame retardant performance of starch-based foam materials, and achieve the effects of low price, reduced heat release rate, and reduced CO generation.

Active Publication Date: 2022-04-29
WUXI HENGSHANG DECORATION ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The curtain wall is the outer wall enclosure of the building, not load-bearing. It is a light wall with decorative effect commonly used in modern large and high-rise buildings. It is composed of a panel and a supporting structure system. It can have a certain displacement capacity relative to the main structure or itself. A building envelope or decorative structure that has a certain deformation capacity and does not bear the role of the main structure (the external wall frame support system is also a kind of curtain wall system). In order to respond to the call for energy saving, most of the current building curtain wall materials choose good thermal insulation performance Polystyrene or polyurethane foam materials, but polystyrene or polyurethane foam materials as plastics, large-scale use will inevitably bring environmental risks, there are also related studies on the use of starch-based foam materials as thermal insulation building materials, such as SU Qiong; The research progress of the preparation method and application of [J]. Food Industry Science and Technology, 2013, 34 (20): 381-385, but starch-based foaming materials generally have poor mechanical strength and flame retardancy, which hinders its Further promotion and application

Method used

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  • A kind of fire-resistant environmental protection curtain wall and preparation method thereof
  • A kind of fire-resistant environmental protection curtain wall and preparation method thereof
  • A kind of fire-resistant environmental protection curtain wall and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A fire-resistant and environmentally friendly curtain wall is prepared from raw materials with the following weights:

[0026] 55g of hydroxypropyl starch, 20g of expanded perlite, 10g of halloysite nanotube composite flame retardant, 1g of ammonium polyphosphate, 6g of polyvinyl alcohol, 0.75g of N,N-dihydroxyethyl formamide, 0.25g of sorbitol, Citric acid 0.25g, sodium bicarbonate 0.25g, talcum powder 0.25g, microcrystalline paraffin 0.25g, water 140g.

[0027] Wherein, the preparation method of halloysite nanotube composite flame retardant is as follows:

[0028] Mix 9mL vinyltrimethoxysilane, 200mL methanol, and 12mL hydrochloric acid evenly, seal it, stir at room temperature for 20 days, then filter, wash the solid with methanol, dissolve it in 50mL tetrahydrofuran, add 20g halloysite nanotubes, and slowly drop Methanol, make POSS grow on halloysite nanotubes, let it stand for 1h after dropping, filter and dry the solid to obtain the intermediate, take 20g of the ...

Embodiment 2

[0032] A fire-resistant and environmentally friendly curtain wall is prepared from raw materials with the following weights:

[0033] 60g of hydroxypropyl starch, 20g of expanded perlite, 12g of halloysite nanotube composite flame retardant, 1g of ammonium polyphosphate, 5g of polyvinyl alcohol, 0.75g of N,N-dihydroxyethyl formamide, 0.25g of sorbitol, Citric acid 0.25g, sodium bicarbonate 0.25g, talcum powder 0.25g, microcrystalline paraffin 0.25g, water 120g.

[0034] Wherein, the preparation method of halloysite nanotube composite flame retardant is as follows:

[0035] Mix 9mL vinyltrimethoxysilane, 200mL methanol, and 12mL hydrochloric acid evenly, seal it, stir at room temperature for 25 days, then filter, wash the solid with methanol, dissolve it in 50mL tetrahydrofuran, add 20g halloysite nanotubes, and slowly drop Methanol, make POSS grow on the halloysite nanotubes, let it stand for 1h after dropping, and obtain the intermediate, take 20g of the intermediate, 100mL ...

Embodiment 3

[0039] A fire-resistant and environmentally friendly curtain wall is prepared from raw materials with the following weights:

[0040] 50g of hydroxypropyl starch, 30g of expanded perlite, 10g of halloysite nanotube composite flame retardant, 2g of ammonium polyphosphate, 5g of polyvinyl alcohol, 0.75g of N,N-dihydroxyethyl formamide, 0.25g of sorbitol, Citric acid 0.25g, sodium bicarbonate 0.25g, talcum powder 0.25g, microcrystalline paraffin 0.25g, water 120g.

[0041] Wherein, the preparation method of halloysite nanotube composite flame retardant is as follows:

[0042]Mix 9mL vinyltrimethoxysilane, 200mL methanol, and 12mL hydrochloric acid evenly, seal it, stir at room temperature for 25 days, then filter, wash the solid with methanol, dissolve it in 50mL tetrahydrofuran, add 20g halloysite nanotubes, and slowly drop Crystallize methanol, grow POSS on halloysite nanotubes, let it stand for 1 hour after dropping to obtain the intermediate, take 20g of the intermediate, 10...

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Abstract

The invention relates to the field of building materials, in particular to a fire-resistant and environmentally friendly curtain wall and a preparation method thereof, which is prepared from the following raw materials in parts by weight: 50-60 parts of hydroxypropyl starch, 20-30 parts of filler, halloysite nano 10-15 parts of pipe composite flame retardant, 1-2 parts of ammonium polyphosphate, 5-8 parts of polyvinyl alcohol, 1-2 parts of plasticizer, 0.5-1 part of foaming component, 120-150 parts of water, all The halloysite nanotube composite flame retardant is obtained by POSS modification of halloysite nanotubes and deposition of nano inorganic flame retardant particles on its surface. Advantages, broad application prospects.

Description

technical field [0001] The invention relates to the field of building materials, in particular to a fire-resistant and environment-friendly curtain wall and a preparation method thereof. Background technique [0002] The curtain wall is the outer wall enclosure of the building, not load-bearing. It is a light wall with decorative effect commonly used in modern large and high-rise buildings. It is composed of a panel and a supporting structure system. It can have a certain displacement capacity relative to the main structure or itself. A building envelope or decorative structure that has a certain deformation capacity and does not bear the role of the main structure (the external wall frame support system is also a kind of curtain wall system). In order to respond to the call for energy saving, most of the current building curtain wall materials choose good thermal insulation performance Polystyrene or polyurethane foam materials, but polystyrene or polyurethane foam material...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L3/08C08L29/04C08K13/06C08K9/06C08K7/00C08K3/32C08K3/38C08K3/34C08K5/053C08K5/20C08J9/08
CPCC08J9/08C08J9/0061C08J9/0023C08J9/0066C08J9/0038C08J9/0095C08J9/009C08J9/0028C08J2203/02C08J2303/08C08J2429/04
Inventor 朱燕明马晓明刘备
Owner WUXI HENGSHANG DECORATION ENG CO LTD
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